Elimination of phenol and aromatic compounds by zero valent iron and EDTA at low temperature and atmospheric pressure

Chemosphere

Volumn 68, Issue 2, 2007, Pages 338-344

  Sanchez, Irama ^a   Stüber, Frank ^a   Font, Josep ^a   Fortuny, Agustí ^b   Fabregat, Azael ^a   Bengoa, Christophe ^a  

^a UNIVERSITAT ROVIRA I VIRGILI   (Spain)

^b UNIVERSITAT POLITÈCNICA DE CATALUNYA   (Spain)

Author keywords

Chelated catalysts; Mild conditions; Refractory compounds; Wastewater

Indexed keywords

ATMOSPHERIC PRESSURE; CONCENTRATION (PROCESS); DEGRADATION; DERIVATIVES; PHENOLS; REACTION KINETICS;

CHELATED CATALYSTS; KINETIC ANALYSIS; REFRACTORY COMPOUNDS;

WASTEWATER TREATMENT;

2 CHLOROPHENOL; 4 NITROPHENOL; ANILINE; AROMATIC COMPOUND; EDETIC ACID; IRON; ORTHO CRESOL; PHENOL;

ATMOSPHERIC PRESSURE; CONCENTRATION (PROCESS); DEGRADATION; DERIVATIVES; PHENOLS; REACTION KINETICS; WASTEWATER TREATMENT;

AROMATIC HYDROCARBON; ATMOSPHERIC PRESSURE; CATALYSIS; CHLOROPHENOL; DEPURATION; EDTA; IRON; LOW TEMPERATURE; ORGANIC NITROGEN COMPOUND; OXIDATION; PHENOL; WASTEWATER; WATER TREATMENT;

AIR; ARTICLE; ATMOSPHERIC PRESSURE; BIOREACTOR; CATALYST; CHEMICAL REACTION; CONCENTRATION (PARAMETERS); DEGRADATION KINETICS; ELIMINATION REACTION; EXPERIMENTAL STUDY; KINETICS; LOW TEMPERATURE; OXIDATION KINETICS; WASTE WATER MANAGEMENT;

EID: 34047241294     PISSN: 00456535     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.chemosphere.2006.12.059     Document Type: Article

References (24)

1. Agrawal A., and Tratnyek P.G. Reduction of nitro aromatic compounds by zero-valent iron metal. Environ. Sci. Technol. 30 (1996) 153-160
2. Bianchi D., Bertoli M., Tassinari R., Ricci M., and Vignola R. Ligand effect on the iron-catalysed biphasic oxidation of aromatic hydrocarbons by hydrogen peroxide. J. Mol. Catal. A: Chem. 204-205 (2003) 419-424
3. Bigda R.J. Consider Fenton's chemistry for wastewater treatment. Chem. Eng. Prog. 91 (1995) 62-66
4. Bucher J.R., Tien M., and Aust S.D. The requirement for ferric in the initiation of lipid peroxidation by chelated ferrous iron. Biochem. Biophys. Res. Commun. 111 (1983) 777-784
5. De A.K., Chaudhuri B., and Bhattacharjee S. A kinetic study of the oxidation of phenol, o-chlorophenol and catechol by hydrogen peroxide between 298 K and 333 K: the effect of pH, temperature and ratio of oxidant to substrate. J. Chem. Technol. Biotechnol. 74 (1999) 162-168
6. Devlin H.R., and Harris I.J. Mechanism of the oxidation of aqueous phenol with dissolved oxygen. Ind. Eng. Chem. Fundam. 23 (1984) 387-392
7. Eftaxias, A., 2003. PhD Thesis, Universitat Rovira i Virgili, Tarragona, Spain.
8. Farrell J., Kason M., Melitas N., and Li T. Investigation of the long-term performance of zero-valent iron for reductive dechlorination of trichloroethylene. Environ. Sci. Technol. 34 (2000) 514-521
9. Fortuny A., Bengoa C., Font J., Castells F., and Fabregat A. Water pollution abatement by catalytic wet air oxidation in a trickle bed reactor. Catal. Today 53 (1999) 107-114
10. Guo J., and Al-Dahhan M. Catalytic wet air oxidation of phenol in concurrent downflow and upflow packed-bed reactors over pillared clay catalyst. Chem. Eng. Sci. 60 (2005) 735-746
11. Joo S.H., Feitz A.J., and Waite T.D. Oxidative degradation of the carbothioate herbicide, molinate, using nanoscale zero-valent iron. Environ. Sci. Technol. 38 (2004) 2242-2247
12. Levec J. Wet oxidation processes for treating industrial wastewaters. Chem. Biochem. Eng. Q. 11 (1997) 47-58
13. Liou R.-M., Chen S.-H., Hung M.-Y., Hsu C.-S., and Lai J.-Y. Fe(III) supported on resin as effective catalyst for the heterogeneous oxidation of phenol in aqueous solution. Chemosphere 59 (2005) 117-125
14. Miller D.M., Buettner G.R., and Aust S.D. Transition metals as catalysts of autoxidation reactions. Free Radical Biol. Med. 8 (1990) 95-108
15. Noradoun C.E., and Cheng I.F. EDTA degradation induced by oxygen activation in a zerovalent iron/air/water system. Environ. Sci. Technol. 39 (2005) 7158-7163
16. Noradoun C., Engelmann M.D., McLaughlin M., Hutchenson R., Breen K., Paszczynski A., and Cheng I.F. Destruction of chlorinated phenols by dioxygen activation under aqueous room temperature and pressure conditions. Ind. Eng. Chem. Res. 42 (2003) 5024-5030
17. Noradoun C.E., Mekmaysy C.S., Hutchenson R.M., and Cheng I.F. Detoxification of malathion a chemical warfare agent analog using oxygen activation at room temperature and pressure. Green Chem. 7 (2005) 426-430
18. Saran M., Michel C., Stettmaier K., and Bors W. Arguments against the significance of the Fenton reaction contributing to signal pathways under in vivo conditions. Free Radical Res. Commun. 33 (2000) 567-579
19. Sayles G.D., You G., Wang M., and Kupferle M.J. DDT, DDD and DDE dechlorination by zero-valent iron. Environ. Sci. Technol. 31 (1997) 3448-3454
20. Stoyanova M., Christoskova S., and Georgieva M. Mixed Ni-Mn-oxide systems as catalysts for complete oxidation Part II. Kinetic study of liquid-phase oxidation of phenol. Appl. Catal. A 249 (2003) 295-302
21. Stüber F., Font J., Eftaxias A., Paradowska M., Suarez M.E., Fortuny A., and Bengoa C. Chemical wet oxidation for the abatement of refractory non-biodegradable organic wastewater pollutants. Process Saf. Environ. Prot. 83 (2005) 371-380
22. Stüber F., Font J., Fortuny A., Bengoa C., Eftaxias A., and Fabregat A. Carbon materials and catalytic wet air oxidation of organic pollutants in wastewater. Top. Catal. 33 (2005) 3-50
23. Suarez-Ojeda M.E., Stüber F., Fortuny A., Fabregat A., Carrera J., and Font J. Catalytic wet air oxidation of substituted phenols using activated carbon as catalyst. Appl. Catal. B 58 (2005) 105-114
24. Welch K.D., Davis T.Z., and Aust S.D. Iron autoxidation and free radical generation, effects of buffers, ligands, and chelators. Arch. Biochem. Biophys. 397 (2002) 360-369