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Volumn 16, Issue 2, 2014, Pages 436-439

PhICl2 and wet DMF: An efficient system for regioselective chloroformyloxylation/a-chlorination of alkenes/a,β-unsaturated compounds

Author keywords

[No Author keywords available]

Indexed keywords

ALKENE; CHLORINATED HYDROCARBON; ESTER;

EID: 84896779980     PISSN: 15237060     EISSN: 15237052     Source Type: Journal    
DOI: 10.1021/ol403321n     Document Type: Article
Times cited : (46)

References (49)
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    • For selected reviews, see: (a) McDonald, R. I.; Liu, G.; Stahl, S. S. Chem. Rev. 2011, 111, 2981
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    • McDonald, R.1    Liu, G.2    Stahl, S.3
  • 5
    • 33746332654 scopus 로고    scopus 로고
    • For selected examples
    • For selected examples, see: (e) Reiser, O. Angew. Chem., Int. Ed. 2006, 45, 2838
    • (2006) Angew. Chem., Int. Ed. , vol.45 , pp. 2838
    • Reiser, O.1
  • 20
  • 43
    • 49149125488 scopus 로고    scopus 로고
    • For selected examples
    • For selected examples, see: (a) Jutand, A. Chem. Rev. 2008, 108, 2300
    • (2008) Chem. Rev. , vol.108 , pp. 2300
    • Jutand, A.1
  • 47
    • 84865856326 scopus 로고    scopus 로고
    • For reviews on DMF as a multipurpose reagent
    • For reviews on DMF as a multipurpose reagent, see: (a) Ding, S.; Jiao, N. Angew. Chem., Int. Ed. 2012, 51, 9226
    • (2012) Angew. Chem., Int. Ed. , vol.51 , pp. 9226
    • Ding, S.1    Jiao, N.2
  • 49
    • 85081811741 scopus 로고    scopus 로고
    • For an alternative mechanistic pathway, see the Supporting Information for details. Intermediate D has been detected by both crude 1H NMR and LCMS analysis when PhICl2 was combined with DMF in the absence of an alkene
    • For an alternative mechanistic pathway, see the Supporting Information for details. Intermediate D has been detected by both crude 1H NMR and LCMS analysis when PhICl2 was combined with DMF in the absence of an alkene.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.