The effect of the novel HO2+NO-HNO3 reaction channel at South Pole, Antarctica

Antarctic Science

Volumn 24, Issue 4, 2012, Pages 417-425

  Boxe, C S ^a   Hamer, P D ^a   Ford, W ^b   Hoffmann, M ^b   Shallcross, D E ^c  

^a CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

^b CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

^c UNIVERSITY OF BRISTOL   (United Kingdom)

Author keywords

Boundary layer; Ice photochemistry; Nitric acid; NOx; Ozone; Polar chemistry

Indexed keywords

EID: 84896751966     PISSN: 09541020     EISSN: 13652079     Source Type: Journal    
DOI: 10.1017/S0954102012000144     Document Type: Article

References (39)

1. ATKINSON, R., BAULCH, D.L., COX, R.A., CROWLEY, J.N., HAMPSON, R.F., HYNES, R.G., JENKIN, M.E., ROSSI, M.J. & TROE, J. 2004. Evaluated kinetic and photochemical data for atmospheric chemistry: Volume I - gas phase reactions of Ox, HOx, NOx and SOx species. Atmospheric Chemistry and Physics, 4, 1461-1738.
2. BOCK, J. & JACOBI, H.W. 2010. Development of a mechanism for nitrate photochemistry in snow. Journal of Physical Chemistry A, 114, 1790-1796.
3. BOXE, C.S. 2005. Nitrate photochemistry and interrelated chemical phenomena in ice: Influence of the quasi-liquid layer (QLL). PhD thesis, California Institute of Technology, 225 pp. [Unpublished.]
4. BOXE, C.S. & SAIZ-LOPEZ, A. 2008. Multiphase modeling of nitrate photochemistry in the quasi-liquid layer (QLL): Implications for NOx release from the Arctic and coastal Antarctic snowpack. Atmospheric Chemistry and Physics, 8, 4855-4864.
5. BOXE, C.S. & SAIZ-LOPEZ, A. 2009. Influence of thin liquid films on polar chemistry: Implications for Earth and planetary science. Polar Science, 3, 73-81.
6. BOXE, C.S., COLUSSI, A.J., HOFFMANN, M.R., TAN, D., MASTROMARINO, J., CASE, A.T., SANDHOLM, S.T. & DAVIS, D.D. 2003. Multiscale ice fluidity in NOx photodesorption from frozen nitrate solutions. Journal of Physical Chemistry A, 107, 11 409-11 413.
7. 21NO reaction as a function of pressure and temperature in the ranges of 72-600 torr and 223-323 K. Journal of Physical Chemistry A, 111, 9047-9053.
8. 21NO reaction: Effects of temperature and water vapor. Journal of Physical Chemistry A, 109, 6509-6520.
9. 21NO reaction on tropospheric HNO3, NOx, HOx and ozone. Atmospheric Chemistry and Physics, 8, 1-8.
10. CARVER, G.D., BROWN, P.D. & WILD, O. 1997. The ASAD atmospheric chemistry integration package and chemical reaction database. Computer Physics Communications, 105, 197-215.
11. CHEN, G. et al. 2001. An investigation of South Pole HOx chemistry: Comparison of model results with ISCAT observations. Geophysical Research Letters, 28, 3633-3636.
12. CHEN, G. et al. 2004. A reassessment of HOx South Pole chemistry based on observations recording during ISCAT 2000. Atmospheric Environment, 38, 5451-5461.
13. 2 production from Antarctic snow? Laboratory investigation assessing the wavelength and temperature dependence. Journal of Geophysical Research, 10.1029/2002JD002602.
14. CRAWFORD, J.H. et al. 2001. Evidence for the photochemical production of ozone at the South Pole surface. Geophysical Research Letters, 28, 3641-3644.
15. DAVIS, D., CHEN, G., BUHR, M., CRAWFORD, J., LENSCHOW, D., LEFER, B., SHETTER, R., EISELE, F., MAULDIN, L. & HOGAN, A. 2004. South Pole NOx chemistry: An assessment of factors controlling variability and absolute levels. Atmospheric Environment, 38, 5375-5388.
16. DAVIS, D. et al. 2001. Unexpected high levels of NO observed at South Pole. Geophysical Research Letters, 28, 3625-3628.
17. DAVIS, D. et al. 2008. A reassessment of Antarctic plateau reactive nitrogen based on ANTCI 2003 airborne and ground based measurements. Atmospheric Environment, 42, 2831-2848.
18. DIBB, J.E., HUEY, L.G., SLUSHER, D.L. & TANNER, D.J. 2004. Soluble reactive nitrogen oxides at South Pole during ISCAT 2000. Atmospheric Environment, 38, 5399-5409.
19. FREY, M.M., STEWART, R.W., MCCONNELL, J.R. & BALES, R.C. 2005. Atmospheric hydroperoxides in West Antarctica: Links to stratospheric ozone and atmospheric oxidation capacity. Journal of Geophysical Research, 10.1029/2005JD006110.
20. GRANNAS, A. et al. 2007. An overview of snow photochemistry: Evidence, mechanisms, and impacts. Atmospheric Chemistry and Physics, 7, 4329-4373.
21. HAMER, P.D., SHALLCROSS, D.E. & FREY, M.M. 2007. Modelling the impact of oxygenated VOC and meteorology upon the boundary layer photochemistry at the South Pole. Atmospheric Science Letters, 8, 14-20.
22. 2 on photochemistry in the South Pole boundary layer. Environmental Chemistry, 5, 268-273.
23. 2 at the South Pole during ISCAT 2000. Atmospheric Environment, 38, 5411-5421.
24. HUTTERLI, M.A., MCCONNELL, J.R., CHEN, G., BALES, R.C., DAVIS, D.D. & LENSCHOW, D.H. 2004. Formaldehyde and hydrogen peroxide in air, snow and interstitial air at South Pole. Atmospheric Environment, 38, 5439-5450.
25. JACOBI, H.-W. & HILKER, B. 2007. A mechanism for the photochemical transformation of nitrate in snow. Journal of Photochemistry and Photobiology A Chemistry, 185, 371-382.
26. JENKIN, M.E., SAUNDERS, S.M. & PHILLING, M.J. 1997. The tropospheric degradation of volatile organic compounds: A protocol for mechanism development. Atmospheric Environment, 31, 81-104.
27. JONES, A.E. & WOLFF, E.W. 2003. An analysis of the oxidation potential of the South Pole boundary layer and the influence of stratospheric ozone depletion. Journal of Geophysical Research, 10.1029/2003JD003379.
28. 2 production in Antarctic snow. Geophysical Research Letters, 27, 345-348.
29. JONES, A.E. et al. 2001. Measurements of NOx emissions from the Antarctic snowpack. Geophysical Research Letters, 28, 1499-1502.
30. LEFER, B.L., HALL, S.R., CINQUINI, L. & SHETTER, R.E. 2001. Photolysis frequency measurements at the South Pole during ISCAT-98. Geophysical Research Letters, 28, 3637-3640.
31. MARTIN, R.V., SAUVAGE, B., FOLKINS, I., SIORIS, C.E., BOONE, C.,BERNATH, P. & ZIEMKE, J. 2007. Spaced-based constraints on the production of nitric oxide by lightning. Journal of Geophysical Research, 10.1029/ 2006JD007831.
32. 2 filter badge and tube. Tokai Journal of Experimental and Clinical Medicine, 27, 35-42.
33. 4, and MSA at the South Pole during ISCAT 2000. Atmospheric Environment, 38, 5423-5437.
34. ONCLEY, S.P., BUHR, M., LENSCHOW, D.H., DAVIS, D. & SEMMER, S.R. 2004. Observations of summertime NO fluxes and boundary-layer height at the South Pole during ISCAT 2000 using scalar similarity. Atmospheric Environment, 38, 5389-5398.
35. SANDER, S.P. et al. 2006. Chemical kinetics and photochemical data for use in atmospheric studies. Evaluation no. 15. JPL Publication 06-02. Pasadena, CA: NASA. http: //jpldataeval.jpl.nasa.gov/pdf/JPL-15-AllInOne.pdf.
36. WANG, Y.H., CHOI, Y., ZENG, T.,DAVIS, D., BUHR, M.,HUEY, L.G. & NEFF, W. 2008. Assessing the photochemical impact of snow NOx emissions over Antarctica during ANTCI 2003. Atmospheric Environment, 42, 2849-2863.
37. WAYNE, R.P. 2000. Chemistry of atmospheres. Oxford: Oxford University Press, 806 pp.
38. WOLFF, E.W., JONES, A.E., MARTIN, T.J. & GRENFELL, T.C. 2002. Modelling photochemical NOx production and nitrate loss in the upper snowpack of Antarctica. Geophysical Research Letters, 10.1029/ 2002GL015823.
39. YABUSHITA, A., KAWANAKA, N., KAWASAKI, M., HAMER, P.D. & SHALLCROSS, D.E. 2007. Release of oxygen atoms and nitric oxide molecules from the ultraviolet photodissociation of nitrate adsorbed on water ice films at 100 K. Journal of Physical Chemistry A, 111, 8629-8634.