Hidden negative differential resistance in the oxidation of formic acid on platinum

Electrochimica Acta

Volumn 129, Issue , 2014, Pages 142-151

  Gojuki, Takeshi ^a   Numata, Yukimasa ^a   Mukouyama, Yoshiharu ^a   Okamoto, Hiroshi ^a  

^a TOKYO DENKI UNIVERSITY   (Japan)

Author keywords

Formic acid oxidation; HNDR; NDR; Potential oscillation; SEIRAS

Indexed keywords

LIGHT ABSORPTION; NEGATIVE RESISTANCE; OXIDATION;

FORMIC ACID OXIDATION; HNDR; NDR; POTENTIAL OSCILLATIONS; SEIRAS;

FORMIC ACID;

EID: 84896470079     PISSN: 00134686     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.electacta.2014.02.102     Document Type: Article

References (64)

1. A. Capon, and R. Parsons The oxidation of formic acid at noble metal electrodes I. review of previous work J. Electroanal. Chem. 44 1973 1 7
2. A. Capon, and R. Parsons The oxidation of formic acid at noble metal electrodes II. a comparison of the behaviour of pure electrodes J. Electroanal. Chem. 44 1973 239 254
3. A. Capon, and R. Parsons The oxidation of formic acid at noble metal electrodes Part III. intermediates and mechanism on platinum electrodes J. Electroanal. Chem. 45 1973 205 231
4. B. Beden, A. Bewick, and C. Lamy A study by electrochemically modulated infrared reflectance spectroscopy of the electrosorption of formic acid at a platinum electrode J. Electroanal. Chem. 148 1983 147 160 (Pubitemid 14470458)
5. 3OH and HCOOH J. Electroanal. Chem. 213 1986 149 157
6. 3OH and HCOOH J. Electroanal. Chem. 218 1987 155 172
7. C. Rice, S. Ha, R.I. Masel, and A. Wieckowski Catalysis for direct formic acid fuel cells J. Power Sources 115 2003 229 235 (Pubitemid 41177327)
8. Y. Zhu, S.Y. Ha, and R.I. Masel High power density direct formic acid fuel cells J. Power Sources 130 2004 8 14 (Pubitemid 41325885)
9. E. Müller, and G. Hindemith Zur elektrolytischen oxydation der ameisensäure Z. Elektrochem. 33 1927 561 568
10. M.T.M. Koper The theory of electrochemical instabilities Electrochim. Acta 37 1992 1771 1778
11. M.T.M. Koper, and J.H. Sluyters On the mathematical unification of a class of electrochemical oscillators and their design procedures J. Electroansl. Chem. 352 1993 51 64
12. M.T.M. Koper, and J.H. Sluyters Instabilities and oscillations in simple models of electrocatalytic surface reactions J. Electroanal. Chem. 371 1994 149 159
13. P. Strasser, M. Lübke, F. Raspel, M. Eiswirth, and G. Ertl Oscillatory instabilities during formic acid oxidation on Pt(100), Pt(110) and Pt(111) under potentiostatic control. I. experimental J. Chem. Phys. 107 1997 979 990 (Pubitemid 127557493)
14. H. Okamoto Mechanistic studies of the potential oscillation and induction period in the oxidation of formic acid on platinum Electrochim. Acta 37 1992 37 42
15. M. Kikuchi, S. Miyahara, Y. Mukouyama, and H. Okamoto Potential oscillation generated by formic acid oxidation in the presence of dissolved oxygen J. Phys. Chem. C 112 2008 7186 7192 (Pubitemid 351704649)
16. H. Okamoto, M. Kikuchi, and Y. Mukouyama Effect of chloride ions on potential oscillation generated by formic acid oxidation J. Electroanal. Chem. 622 2008 1 9
17. H. Okamoto, Y. Numata, T. Gojuki, and Y. Mukouyama Different behavior of adsorbed bridge-bonded formate from that of current in the oxidation of formic acid on platinum Electrochim. Acta 116 2014 263 270
18. N.A. Anastasijevic, H. Baltruschat, and J. Heitbaum DEMS as a tool for the investigation of dynamic processes: galvanostatic formic acid oxidation on a Pt electrode J. Electroanal. Chem. 272 1989 89 100
19. G. Samjeské, A. Miki, S. Ye, A. Yamakata, Y. Mukouyama, H. Okamoto, and M. Osawa Potential oscillations in galvanostatic electrooxidation of formic acid on platinum: a time-resolved surface-enhanced infrared study J. Phys. Chem. B 109 2005 23509 23516 (Pubitemid 43084735)
20. G. Inzelt, and V. Kertész Experimental evidence for the periodical changes of the amount of chemisorbed species accompanying the potential oscillations produced in the course of galvanostatic oxidation of formic acid on platinum Electrochim. Acta 38 1993 2385 2386
21. G.G. Láng, M. Seo, and K.E. Heusler Simultaneous oscillations of surface energy, superficial mass and electrode potential in the course of galvanostatic oxidation of formic acid J. Solid State Electrochem. 9 2005 347 353 (Pubitemid 40878585)
22. M. Tian, and B.E. Conway Electrocatalysis in oscillatory kinetics of anodic oxidation of formic acid: at Pt; nanogravimetry and voltammetry studies on the role of reactive surface oxide J. Electroanal. Chem. 616 2008 45 56
23. V. Kertész, G. Inzelt, C. Barbero, R. Kötz, and O. Haas Probe beam deflection studies of electrochemical oscillations during galvanostatic oxidation of formic acid at a platinum electrode J. Electroanal. Chem. 392 1995 91 95
24. G.G. Láng, K. Ueno, M. Újvári, and M. Seo Simultaneous oscillations of surface stress and potential in the course of galvanostatic oxidation of formic acid, J. Phys. Chem. B 104 2000 2785 2789
25. C.Le. Naour, Ph Moisy, J.M. Léger, C. Petrier, and C. Madic Effect of power ultrasound on the electrochemical platinum | HCOOH interface J. Electroanal. Chem. 501 2001 215 221 (Pubitemid 32287766)
26. F. Raspel, R.J. Nichols, and D.M. Kolb Current oscillations during formic acid oxidation on Pt(100) J. Electroanal. Chem. 286 1990 279 283 (Pubitemid 20711052)
27. N. Markovic, and P.N. Ross Jr. Oscillatory behavior in the electrochemical oxidation of formic acid on Pt(100) J. Phys. Chem. 97 1993 9771 9778
28. F. Raspel, and M. Eiswirth Current oscillations in the electrochemical oxidation of formic acid at Pt single crystal surfaces J. Phys. Chem. 98 1994 7613 7618
29. M.T.M. Koper Oscillations and complex dynamical bifurcations in electrochemical systems I. Prigogine, S.A. Rice, Advances in Chemical Physics 92 1996 Wiley New York 161 298 (Pubitemid 126068111)
30. K. Krischer Principles of temporal and spatial pattern formation in electrochemical systems B.E. Conway, J.O.-M. Bockris, R.E. White, Modern Aspects of Electrochemistry, No. 32 1999 Kluwer Acadmic/Plenum Publishers New York 1 142
31. K. Krischer Nonlinear dynamics in electrochemical systems R.C. Alkire, D.M. Kolb, Advances in Electrochemical Science and Engineering 8 2003 WILEY-VCH Weinheim 89 208
32. M. Orlik Self-organization in Electrochemical systems I, II 2012 Springer-Verlag Berlin
33. ad + Pt(111) electrodes J. Electroanal. Chem. 376 1994 151 160
34. H. Okamoto, N. Tanaka, and M. Naito Modelling temporal kinetic oscillations for electrochemical oxidation of formic acid on Pt Chem. Phys. Lett 248 1996 289 295 (Pubitemid 126165019)
35. T. Iwasita, X.H. Xia, H.-D. Liess, and W. Vielstich Electrocatalysis of organic oxidations: influence of water adsorption on the rate of reaction J. Phys. Chem. B 101 1997 7542 7547 (Pubitemid 127581200)
36. G.-Q. Lu, A. Crown, and A. Wieckowski Formic acid decomposition on polycrystalline platinum and palladized platinum electrodes J. Phys. Chem. B 103 1999 9700 9711 (Pubitemid 129614003)
37. G. Samjeské, and M. Osawa Current oscillations during formic acid oxidation on a Pt electrode: insight into the mechanism by time-resolved IR spectroscopy Angew. Chem. Int. Ed. 44 2005 5694 5697
38. M. Naito, N. Tanaka, and H. Okamoto General relationship between complex impedance and linear stability in electrochemical systems J. Chem. Phys. 111 1999 9908 9917 (Pubitemid 129590228)
39. A. Miki, S. Ye, M. Osawa, and Surface-enhanced IR absorption on platinum nanoparticles: an application to real-time monitoring of electrocatalytic reactions, Chem. Commun. 150 2002 0 1501
40. T. Biegler, D.A.J. Rand, and R. Woods Limiting oxygen coverage on platinized platinum; relevance to determination of real platinum area by hydrogen adsorption J. Electroanal. Chem. 29 1971 269 277
41. G. Samjeské, A. Miki, S. Ye, and M. Osawa Mechanistic study of electrocatalytic oxidation of formic acid at platinum in acidic solution by time-resolved surface-enhanced infrared absorption spectroscopy J. Phys. Chem. B 110 2006 16559 16566 (Pubitemid 44373383)
42. G. Samjeské, A.K. Komatsu, and M. Osawa Dynamics of CO oxidation on a polycrystalline platinum electrode: A time-resolved infrared study J. Phys. Chem. C 113 2009 10222 10228
43. M. Heinen, Y.X. Chen, Z. Jusys, and R.J. Behm In situ ATR-FTIRS coupled with on-line DEMS under controlled mass transport conditions-A novel tool for electrocatalytic reaction studies Electrochim. Acta 52 2007 5634 5643 (Pubitemid 46602211)
44. L.-W.H. Leung, A. Wieckowski, and M.J. Weaver In situ infrared spectroscopy of well-defined single-crystal electrodes: adsorption and electrooxidation of CO on Pt(111) J. Phys. Chem. 92 1988 6985 6990
45. Y.X. Chen, S. Ye, M. Heinen, Z. Jusys, M. Osawa, and R.J. Behm Application of in-situ attenuated total reflection-Fourier transform infrared spectroscopy for the understanding of complex reaction mechanism and kinetics: formic acid oxidation on a Pt film electrode at elevated temperatures J. Phys. Chem. B 110 2006 9534 9544 (Pubitemid 43952976)
46. Y.-X. Chen, M. Heinen, Z. Jusys, and R.J. Behm Bridge-bonded formate: active intermediate or spectator species in formic acid oxidation on a Pt film electrode? Langmuir 22 2006 10399 10408 (Pubitemid 46051718)
47. D.K. Lambert Vibrational Stark effect of adsorbates at electrochemical surfaces Electrochim. Acta 41 1996 623 630 (Pubitemid 126350853)
48. P.S. Bagus, C.J. Nelin, W. Müller, M.R. Philpott, and H. Seki Field-induced vibrational frequency shifts of CO and CN chemisorbed on Cu(100) Phys. Rev. Lett. 58 1987 559 562
49. S. Holloway, and J.K. Nørskov Changes in the vibrational frequencies of adsorbed molecules due to an applied electric field J. Electroanal. Chem. 161 1984 193 198
50. H. Kita, T. Katagiri, and K. Kunimatsu Electrochemical oxidation of HCOONa on Pt in acidic solutions J. Electroanal. Chem. 220 1987 125 138 (Pubitemid 17587240)
51. H. Okamoto, W. Kon, and Y. Mukouyama Five current peaks in voltammograms for oxidations of formic acid, formaldehyde, and methanol on platinum, J. Phys. Chem. B 109 2005 15659 15666
52. T. Iwasita, X. Xia, E. Herrero, and H.-D. Liess Early stages during the oxidation of HCOOH on single-crystal Pt electrodes as characterized by infrared spectroscopy Langmuir 12 1996 4260 4265 (Pubitemid 126567922)
53. M. Osawa, K. Komatsu, G. Samjeské, T. Uchida, T. Ikeshoji, A. Cuesta, and C. Gutiérrez Role of bridge-bonded formate in the electrocatalytic oxidation of formic acid on platinum Angew. Chem. Int. Ed. 50 2011 1159 1163
54. 4 Reexamination of its mechanism through combined cyclic-voltammetry, electrochemical quartz-crystal nanobalance, and Auger electron spectroscopy measurements, Electrochim. Acta 49 2004 1451 1459
55. M. Alsabet, M. Grden, and G. Jerkiewicz Comprehensive study of the growth of thin oxide layers on Pt electrodes under well-defined temperature, potential, and time conditions, J. Electroanal. Chem. 589 2006 120 127
56. G. Jerkiewicz, M. Alsabet, M. Grden, H. Varela, and G. Tremiliosi-Filho Erratum to: Comprehensive study of the growth of thin oxide layers on Pt electrodes under well-defined temperature, potential, and time conditions [Journal of Electroanalytical Chemistry, 589 (2006) 120-127] J. Electroanal. Chem. 625 2009 172 174
57. H. Imai, K. Izumi, M. Matsumoto, Y. Kubo, K. Kato, and Y. Imai In situ and real-time monitoring of oxide growth in a few monolayers at surfaces of platinum nanoparticles in aqueous media J. Am. Chem. Soc. 131 2009 6293 6300
58. 4 solution ECS Trans. 16 24 2009 117 123
59. K. Sashikata, N. Furuya, and K. Itaya In situ electrochemical scanning tunneling microscopy of single crystal surfaces of Pt(111), Rh(111), and Pd(111) in aqueous sulfuric acid solution, J. Vac. Sci. Technol. B 9 1991 457 464
60. B.E. Conway Electrochemical oxide film formation at noble metals as a surface-chemical process Prog. Surf. Sci. 49 1995 331 452
61. A. Miki, S. Ye, T. Senzaki, and M. Osawa Surface-enhanced infrared study of catalytic electrooxidation of formaldehyde, methyl formate, dimethoxymethane on platinum electrodes in acidic solution, J. Electroanal. Chem. 563 2004 23 31
62. Y. Mukouyama, M. Kikuchi, G. Samjeské, M. Osawa, and H. Okamoto Potential oscillations in galvanostatic electrooxidation of formic acid on platinum: a mathematical modeling and simulation J. Phys. Chem. B 110 2006 11912 11917 (Pubitemid 44024809)
63. 4 solutions. The potential of zero charge J. Electroanal. Chem. 411 1996 95 102 (Pubitemid 126645816)
64. M. Wakisaka, H. Suzuki, S. Mitsui, H. Uchida, and M. Watanabe Identification and quantification of oxygen species adsorbed on Pt(111) single-crystal and polycrystalline Pt electrodes by photoelectron spectroscopy Langmuir 25 2009 1897 1900