Current oscillations during formic acid oxidation on a Pt electrode: Insight into the mechanism by time-resolved IR spectroscopy

Angewandte Chemie - International Edition

Volumn 44, Issue 35, 2005, Pages 5694-5698

  Samjeské, Gabor ^a,b   Osawa, Masatoshi ^a,b  

^a HOKKAIDO UNIVERSITY   (Japan)

^b JAPAN SCIENCE AND TECHNOLOGY AGENCY   (Japan)

Author keywords

Electrochemistry; Formic acid; IR spectroscopy; Oxidation; Surface chemistry

Indexed keywords

ADSORPTION; CARBOXYLIC ACIDS; ELECTRIC CURRENTS; ELECTROCHEMICAL ELECTRODES; ELECTROCHEMISTRY; INFRARED SPECTROSCOPY; MATHEMATICAL MODELS; OSCILLATIONS; PLATINUM; SURFACE CHEMISTRY;

CURRENT OSCILLATIONS; ELECTROOXIDATION; FORMIC ACIDS; TIME RESOLVED IR SPECTROSCOPY;

OXIDATION;

EID: 24944461199     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200501009     Document Type: Article

References (35)

1. For example, see: U. F. Franck, Angew. Chem. 1978, 90, 1;
2. Angew. Chem. Int. Ed. Engl. 1978, 17, 1.
3. a) J. L. Hudson, T. T. Tsotsis, Chem. Eng. Sci. 1994, 49, 1493;
4. b) M. T. M. Koper in Advances in Chemical Physics, Vol. 92 (Eds.: I. Prigogine, S. A. Rice), Wiley, New York, 1996, p. 161;
5. K. Krischer in Modern Aspects of Electrochemistry, Vol. 32 (Eds.: B. E. Conway, J. O. M. Bockris, R. E. White), Kluwer Academic/Plenum, New York, 1999, p. 1.
6. a) E. Müller, S. Tanaka, Z. Elektrochem. 1928, 34, 256;
7. b) J. Wojtowicz, N. Marincic, B. E. Conway, J. Chem. Phys. 1968, 48, 4333;
8. c) F. N. Albahadily, M. Schell, J. Electroanal. Chem. 1991, 308, 151 ;
9. d) N. Markovic, P. N. Ross, J. Phys. Chem. 1993, 97, 9771;
10. e) H. Okamoto, Electrochim. Acta 1992, 37, 37;
11. f) F. Raspel, M. Eiswirth, J. Phys. Chem. 1994, 98, 7613;
12. g) P. Strasser, M. Lübke, F. Raspel, M. Eiswirth, G. Ertl, J. Chem. Phys. 1997, 107, 979;
13. h) T. J. Schmidt, B. N. Grgur, N. M. Markovic, P. N. Ross, J. Electroanal. Chem. 2001, 500, 36.
14. a) M. T. M. Koper, J. H. Sluyters, J. Electroanal. Chem. 1994, 371, 149;
15. b) H. Okamoto, Chem. Phys. Lett. 1996, 248, 289;
16. c) P. Strasser, M. Eiswirth, G. Ertl, J. Chem. Phys. 1997, 107, 991.
17. A. Capon, R. Parsons, J. Electroanal. Chem. 1973, 45, 205.
18. a) K. Kunimatsu, H. Kita, J. Electroanal. Chem. 1987, 218, 155;
19. b) D. S. Corrigan, M. J. Weaver, J. Electroanal. Chem. 1988, 241, 143.
20. Y. Honda, M.-B. Song, M. Ito, Chem. Phys. Lett. 1997, 273, 141.
21. a) M. Osawa, Bull. Chem. Soc. Jpn. 1997, 70, 2861;
22. b) M. Osawa in Vibrational Spectroscopy, Vol. 1 (Eds.: J. Charmers, P. R. Griffiths), Wiley, Chichester, 2002, p. 785.
23. a) A. Miki, S. Ye, M. Osawa, Chem. Commun. 2002, 1500;
24. b) A. Miki, S. Ye, T. Senzaki, M. Osawa, J. Electroanal. Chem. 2004, 563, 23.
25. a) M. Osawa, K. Ataka, K. Yoshii, T. Yotsuyanagi, J. Electron Spectrosc. Relat. Phenom. 1993, 64/65, 371;
26. b) K. Ataka, T. Yotsuyanagi, M. Osawa, J. Phys. Chem. 1996, 100, 10664.
27. For example, see: R. J. Nichols in Adsorption of Molecules at Metal Electrodes (Eds.: J. Lipkowski, P. N. Ross), VCH, New York, 1992, p. 347.
28. F. M. Hoffmann, Surf. Sci. Rep. 1983, 3, 107.
29. See the Supporting Information.
30. L band intensity.
31. a) M. R. Columbia, A. M. Crabtree, P. A. Thiel, J. Am. Chem. Soc. 1992, 114, 1231;
32. b) M. R. Columbia, P. A. Thiel, J. Electroanal. Chem. 1994, 369, 1.
33. a) J. L. Falconer, R. J. Madix, Surf. Sci. 1974, 46, 473;
34. b) T. J. Cassidy, M. D. Allen, Y. Li, M. Bowker, Catal. Lett. 1993, 21, 321;
35. c) R. G. Sharpe, M. Bowker, J. Phys. Condens. Matter 1995, 7, 6379.