In situ and quantitative characterization of solid electrolyte interphases

Nano Letters

Volumn 14, Issue 3, 2014, Pages 1405-1412

  Cresce, Arthur V ^a   Russell, Selena M ^a   Baker, David R ^a   Gaskell, Karen J ^b   Xu, Kang ^a  

^a U S ARMY RESEARCH LABORATORY   (United States)

^b Bldg 142   (United States)

Author keywords

AFM; electrolyte; HOPG; in situ characterization; Interphase; Li ion battery; SEI

Indexed keywords

ELECTROLYTES; LITHIUM; LITHIUM BATTERIES; SEEBECK EFFECT; TOOLS;

AFM; HOPG; IN-SITU CHARACTERIZATION; INTERPHASE; LI-ION BATTERIES; SEI;

SOLID ELECTROLYTES;

EID: 84896369712     PISSN: 15306984     EISSN: 15306992     Source Type: Journal    
DOI: 10.1021/nl404471v     Document Type: Article

References (43)

1. Peled, E. The Electrochemical Behavior of Alkali and Alkaline Earth Metals in Nonaqueous Battery Systems-The Solid Electrolyte Interphase Model J. Electrochem. Soc. 1979, 126 (12) 2047-2051
2. Xu, K. Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries Chem. Rev. 2004, 104 (10) 4303-4418
3. Winter, M., The Solid Electrolyte Interphase-The Most Important and the Least Understood Solid Electrolyte in Rechargeable Li Batteries Z. Phys. Chem. 2009, 223.
4. Peled, E. Lithium Stability and Film Formation in Organic and Inorganic Electrolyte for Lithium Battery Systems. Lithium Batteries; Gabano, J. P., Ed.; Academic Press: New York, 1983; pp 43-72.
5. 6 in Propylene Carbonate (PC) J. Phys. Chem. C 2013, 117 (48) 25381-25389
6. Shkrob, I. A.; Zhu, Y.; Marin, T. W.; Abraham, D. Reduction of Carbonate Electrolytes and the Formation of Solid-Electrolyte Interface (SEI) in Lithium-Ion Batteries. 1. Spectroscopic Observations of Radical Intermediates Generated in One-Electron Reduction of Carbonates J. Phys. Chem. C 2013, 117 (38) 19255-19269
7. Lu, P.; Harris, S. J. Lithium Transport Within the Solid Electrolyte Interphase Electrochem. Commun. 2011, 13 (10) 1035-1037
8. Lu, P.; Li, C.; Schneider, E. W.; Harris, S. J. Chemistry, Impedance, and Morphology Evolution in Solid Electrolyte Interphase Films during Formation in Lithium Ion Batteries J. Phys. Chem. C 2013, 118 (2) 896-903
9. Zhang, J.; Wang, R.; Yang, X.; Lu, W.; Wu, X.; Wang, X.; Li, H.; Chen, L. Direct Observation of Inhomogeneous Solid Electrolyte Interphase on MnO Anode with Atomic Force Microscopy and Spectroscopy Nano Lett. 2012, 12 (4) 2153-2157
10. Niehoff, P.; Passerini, S.; Winter, M. Interface Investigations of a Commercial Lithium Ion Battery Graphite Anode Material by Sputter Depth Profile X-ray Photoelectron Spectroscopy Langmuir 2013, 29 (19) 5806-5816
11. Xu, K.; Lam, Y.; Zhang, S. S.; Jow, T. R.; Curtis, T. B. Solvation Sheath of Li+ in Nonaqueous Electrolytes and Its Implication of Graphite/Electrolyte Interface Chemistry J. Phys. Chem. C 2007, 111 (20) 7411-7421
12. Aurbach, D.; Daroux, M.; Faguy, P.; Yeager, E. The Electrochemistry of Noble Metal Electrodes in Aprotic Organic Solvents Containing Lithium Salts J. Electroanal. Chem. Interfacial Electrochem. 1991, 297 (1) 225-244
13. Tang, M.; Miyazaki, K.; Abe, T.; Newman, J. Effect of Graphite Orientation and Lithium Salt on Electronic Passivation of Highly Oriented Pyrolytic Graphite J. Electrochem. Soc. 2012, 159 (5) A634-A641
14. Chu, A. C.; Josefowicz, J. Y.; Farrington, G. C. Electrochemistry of Highly Ordered Pyrolytic Graphite Surface Film Formation Observed by Atomic Force Microscopy J. Electrochem. Soc. 1997, 144 (12) 4161-4169
15. Jeong, S.-K.; Inaba, M.; Abe, T.; Ogumi, Z. Surface Film Formation on Graphite Negative Electrode in Lithium-Ion Batteries: AFM Study in an Ethylene Carbonate-Based Solution J. Electrochem. Soc. 2001, 148 (9) A989-A993
16. El Abedin, S. Z.; Garsuch, A.; Endres, F. Aluminium Nanowire Electrodes for Lithium-Ion Batteries Aust. J. Chem. 2012, 65 (11) 1529-1533
17. Hirasawa, K. A.; Sato, T.; Asahina, H.; Yamaguchi, S.; Mori, S. In Situ Electrochemical Atomic Force Microscope Study on Graphite Electrodes J. Electrochem. Soc. 1997, 144 (4) L81-L84
18. Besenhard, J. O.; Winter, M.; Yang, J.; Biberacher, W. Filming Mechanism of Lithium-Carbon Anodes in Organic and Inorganic Electrolytes J. Power Sources 1995, 54 (2) 228-231
19. ycn-in PC-Based Electrolytes Electrochem. Commun. 2005, 7 (9) 947-952
20. Peled, E.; Golodnitsky, D.; Ardel, G. Advanced Model for Solid Electrolyte Interphase Electrodes in Liquid and Polymer Electrolytes J. Electrochem. Soc. 1997, 144 (8) L208-L210
21. Domi, Y.; Ochida, M.; Tsubouchi, S.; Nakagawa, H.; Yamanaka, T.; Doi, T.; Abe, T.; Ogumi, Z. In Situ AFM Study of Surface Film Formation on the Edge Plane of HOPG for Lithium-Ion Batteries J. Phys. Chem. C 2011, 115 (51) 25484-25489
22. Matsuoka, O.; Hiwara, A.; Omi, T.; Toriida, M.; Hayashi, T.; Tanaka, C.; Saito, Y.; Ishida, T.; Tan, H.; Ono, S. S.; Yamamoto, S. Ultra-Thin Passivating Film Induced by Vinylene Carbonate on Highly Oriented Pyrolytic Graphite Negative Electrode in Lithium-Ion Cell J. Power Sources 2002, 108 (1-2) 128-138
23. Jeong, S.-K.; Inaba, M.; Mogi, R.; Iriyama, Y.; Abe, T.; Ogumi, Z. Surface Film Formation on a Graphite Negative Electrode in Lithium-Ion Batteries: Atomic Force Microscopy Study on the Effects of Film-Forming Additives in Propylene Carbonate Solutions Langmuir 2001, 17 (26) 8281-8286
24. Jeong, S.-K.; Inaba, M.; Iriyama, Y.; Abe, T.; Ogumi, Z. Surface Film Formation on a Graphite Negative Electrode in Lithium-Ion Batteries: Afm Study on the Effects of Co-solvents in Ethylene Carbonate-based Solutions Electrochim. Acta 2002, 47, 1975-1982
25. Domi, Y.; Ochida, M.; Tsubouchi, S.; Nakagawa, H.; Yamanaka, T.; Doi, T.; Abe, T.; Ogumia, Z. Electrochemical AFM Observation of the HOPG Edge Plane in Ethylene Carbonate-Based Electrolytes Containing Film-Forming Additives J. Electrochem. Soc. 2012, 159 (8) A1292-A1297
26. Tsubouchi, S.; Domi, Y.; Doi, T.; Ochida, M.; Nakagawa, H.; Yamanaka, T.; Abe, T.; Ogumi, Z. Spectroscopic Analysis of Surface Layers in Close Contact with Edge Plane Graphite Negative-Electrodes J. Electrochem. Soc. 2013, 160 (4) A575-A580
27. Nie, M.; Chalasani, D.; Abraham, D. P.; Chen, Y.; Bose, A.; Lucht, B. L. Lithium Ion Battery Graphite Solid Electrolyte Interphase Revealed by Microscopy and Spectroscopy J. Phys. Chem. C 2013, 117 (3) 1257-1267
28. Ota, H.; Sakata, Y.; Inoue, A.; Yamaguchi, S. Analysis of Vinylene Carbonate Derived SEI Layers on Graphite Anode J. Electrochem. Soc. 2004, 151 (10) A1659-A1669
29. Lee, J. T.; Nitta, N.; Benson, J.; Magasinski, A.; Fuller, T. F.; Yushin, G. Comparative Study of the Solid Electrolyte Interphase on Graphite in Full Li-Ion Battery Cells Using X-ray Photoelectron Spectroscopy, Secondary Ion Mass Spectrometry, and Electron Microscopy Carbon 2013, 52 (0) 388-397
30. Wagner, M. S.; Graham, D. J.; Ratner, B. D.; Castner, D. G. Maximizing Information Obtained from Secondary Ion Mass Spectra of Organic Thin Films Using Multivariate Analysis Surf. Sci. 2004, 570 (1-2) 78-97
31. Aurbach, D.; Gamolsky, K.; Markovsky, B.; Gofer, Y.; Schmidt, M.; Heider, U. On the Use of Vinylene Carbonate (VC) as an Additive to Electrolyte Solutions for Li-Ion Batteries Electrochim. Acta 2002, 47 (9) 1423-1439
32. McMillan, R.; Slegr, H.; Shu, Z. X.; Wang, W. Fluoroethylene Carbonate Electrolyte and Its Use in Lithium Ion Batteries with Graphite Anodes J. Power Sources 1999, 81-82 (0) 20-26
33. Zhang, S. S. A Review on Electrolyte Additives for Lithium-Ion Batteries J. Power Sources 2006, 162 (2) 1379-1394
34. von Cresce, A.; Xu, K. Electrolyte Additive in Support of 5 V Li Ion Chemistry J. Electrochem. Soc. 2011, 158 (3) A337
35. Tasaki, K.; Goldberg, A.; Lian, J.-J.; Walker, M.; Timmons, A.; Harris, S. J. Solubility of Lithium Salts Formed on the Lithium-Ion Battery Negative Electrode Surface in Organic Solvents J. Electrochem. Soc. 2009, 156 (12) A1019-A1027
36. Jones, J.; Anouti, M.; Caillon-Caravanier, M.; Willmann, P.; Sizaret, P.-Y.; Lemordant, D. Solubilization of SEI Lithium Salts in Alkylcarbonate Solvents Fluid Phase Equilib. 2011, 305 (2) 121-126
37. Xu, K. Whether EC and PC Differ in Interphasial Chemistry on Graphitic Anode and How J. Electrochem. Soc. 2009, 156 (9) A751-A755
38. Aurbach, D.; Daroux, M. L.; Faguy, P. W.; Yeager, E. Identification of Surface Films Formed on Lithium in Propylene Carbonate Solutions J. Electrochem. Soc. 1987, 134 (7) 1611-1620
39. Aurbach, D.; Ein-Ely, Y.; Zaban, A. The Surface Chemistry of Lithium Electrodes in Alkyl Carbonate Solutions J. Electrochem. Soc. 1994, 141 (1) L1-L3
40. Krämer, E.; Schedlbauer, T.; Hoffmann, B.; Terborg, L.; Nowak, S.; Gores, H. J.; Passerini, S.; Winter, M. Mechanism of Anodic Dissolution of the Aluminum Current Collector in 1 M LiTFSI EC:DEC 3:7 in Rechargeable Lithium Batteries J. Electrochem. Soc. 2013, 160 (2) A356-A360
41. Nguyen, C. C.; Woo, S.-W.; Song, S.-W. Understanding the Interfacial Processes at Silicon-Copper Electrodes in Ionic Liquid Battery Electrolyte J. Phys. Chem. C 2012, 116 (28) 14764-14771
42. Markevich, E.; Sharabi, R.; Borgel, V.; Gottlieb, H.; Salitra, G.; Aurbach, D.; Semrau, G.; Schmidt, M. A. In situ FTIR Study of the Decomposition of N-butyl-N-methylpyrrolidinium bis(trifluoromethanesulfonyl)amide Ionic Liquid during Cathodic Polarization of Lithium and Graphite Electrodes Electrochim. Acta 2010, 55 (8) 2687-2696
43. Howlett, P. C.; Brack, N.; Hollenkamp, A. F.; Forsyth, M.; MacFarlane, D. R. Characterization of the Lithium Surface in N-Methyl-N-alkylpyrrolidinium Bis(trifluoromethanesulfonyl)amide Room-Temperature Ionic Liquid Electrolytes J. Electrochem. Soc. 2006, 153 (3) A595-A606