A pomegranate-inspired nanoscale design for large-volume-change lithium battery anodes

Nature Nanotechnology

Volumn 9, Issue 3, 2014, Pages 187-192

  Liu, Nian ^a   Lu, Zhenda ^b   Zhao, Jie ^b   Mcdowell, Matthew T ^b   Lee, Hyun Wook ^b   Zhao, Wenting ^b   Cui, Yi ^b,c  

^a STANFORD UNIVERSITY   (United States)

^b Stanford University   (United States)

^c SLAC NATIONAL ACCELERATOR LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ANODES; CARBON; LITHIUM COMPOUNDS; LITHIUM SULFUR BATTERIES; LITHIUM-ION BATTERIES; NANOPARTICLES; SOLID ELECTROLYTES; SULFUR COMPOUNDS;

COULOMBIC EFFICIENCY; ELECTROLYTE CONTACTS; EXPANSION AND CONTRACTION; LITHIUM BATTERY ANODE; SILICON NANOPARTICLES; SOLID ELECTROLYTE INTERPHASE; STRUCTURAL DEGRADATION; THEORETICAL CAPACITY;

SILICON BATTERIES;

CARBON; ELECTROLYTE; LITHIUM; SILICON;

ARTICLE; BATTERY; CHEMICAL STRUCTURE; ELECTRICAL EQUIPMENT; ELECTRODE; LITHIATION; PARTICLE SIZE; PRIORITY JOURNAL;

EID: 84895920205     PISSN: 17483387     EISSN: 17483395     Source Type: Journal    
DOI: 10.1038/nnano.2014.6     Document Type: Article

References (33)

1. Armand, M. & Tarascon, J-M. Building better batteries. Nature 451, 652-657 (2008
2. Arico, A. S., Bruce, P., Scrosati, B., Tarascon, J-M. & van Schalkwijk, W. Nanostructured materials for advanced energy conversion and storage devices. Nature Mater. 4, 366-377 (2005
3. Bruce, P. G., Freunberger, S. A., Hardwick, L. J. & Tarascon, J-M. Li-O2 and Li-S batteries with high energy storage. Nature Mater. 11, 19-29 (2012
4. Beaulieu, L. Y., Eberman, K.W., Turner, R. L., Krause, L. J. & Dahn, J. R. Colossal reversible volume changes in lithium alloys. Electrochem. Solid-State Lett. 4, A137-A140 (2001
5. Obrovac, M. N. & Christensen, L. Structural changes in silicon anodes during lithium insertion/extraction. Electrochem. Solid-State Lett. 7, A93-A96 (2004
6. Obrovac, M. N., Christensen, L., Le, D. B. & Dahn, J. R. Alloy design for lithiumion battery anodes. J. Electrochem. Soc. 154, A849-A855 (2007
7. Larcher, D. et al. Recent findings and prospects in the field of pure metals as negative electrodes for Li-ion batteries. J. Mater. Chem. 17, 3759-3772 (2007
8. Chan, C. K. et al. High-performance lithium battery anodes using silicon nanowires. Nature Nanotech. 3, 31-35 (2008
9. Wu, H. & Cui, Y. Designing nanostructured Si anodes for high energy lithium ion batteries. Nano Today 7, 414-429 (2012
10. Park, M-H. et al. Silicon nanotube battery anodes. Nano Lett. 9, 3844-3847 (2009
11. Magasinski, A. et al. High-performance lithium-ion anodes using a hierarchical bottom-up approach. Nature Mater. 9, 353-358 (2010
12. Deshpande, R., Cheng, Y-T. & Verbrugge, M. W. Modeling diffusion-induced stress in nanowire electrode structures. J. Power Sources 195, 5081-5088 (2010
13. Liu, G. et al. Polymers with tailored electronic structure for high capacity lithium battery electrodes. Adv. Mater. 23, 4679-4683 (2011
14. Lee, S. W., McDowell, M. T., Berla, L. A., Nix, W. D. & Cui, Y. Fracture of crystalline silicon nanopillars during electrochemical lithium insertion. Proc. Natl Acad. Sci. USA 109, 4080-4085 (2012
15. Hwang, T. H., Lee, Y. M., Kong, B-S., Seo, J-S. & Choi, J. W. Electrospun core-shell fibers for robust silicon nanoparticle-based lithium ion battery anodes. Nano Lett. 12, 802-807 (2012
16. Yi, R., Dai, F., Gordin, M. L., Chen, S. & Wang, D. Micro-sized Si-C composite with interconnected nanoscale building blocks as high-performance anodes for practical application in lithium-ion batteries. Adv. Energy Mater. 3, 295-300 (2013
17. Aurbach, D. Review of selected electrode-solution interactions which determine the performance of Li and Li ion batteries. J. Power Sources 89, 206-218 (2000
18. Chan, C. K., Ruffo, R., Hong, S. S. & Cui, Y. Surface chemistry and morphology of the solid electrolyte interphase on silicon nanowire lithium-ion battery anodes. J. Power Sources 189, 1132-1140 (2009
19. Verma, P., Maire, P. & Novák, P. A review of the features and analyses of the solid electrolyte interphase in Li-ion batteries. Electrochim. Acta 55, 6332-6341 (2010
20. Wu, H. et al. Stable cycling of double-walled silicon nanotube battery anodes through solid-electrolyte interphase control. Nature Nanotech. 7, 310-315 (2012
21. Liu, N. et al. A yolk-shell design for stabilized and scalable Li-ion battery alloy anodes. Nano Lett. 12, 3315-3321 (2012
22. Li, X. et al. Hollow core-shell structured porous Si-C nanocomposites for Li-ion battery anodes. J. Mater. Chem. 22, 11014-11017 (2012
23. Chen, S. et al. Silicon core-hollow carbon shell nanocomposites with tunable buffer voids for high capacity anodes of lithium-ion batteries. Phys. Chem. Chem. Phys. 14, 12741-12745 (2012
24. Park, Y. et al. Si-encapsulating hollow carbon electrodes via electroless etching for lithium-ion batteries. Adv. Energy Mater. 3, 206-212 (2012
25. Wang, B. et al. Contact-engineered and void-involved silicon/carbon nanohybrids as lithium-ion-battery anodes. Adv. Mater. 25, 3560-3565 (2013
26. Cho, Y-S., Yi, G-R., Kim, S-H., Pine, D. J. & Yang, S-M. Colloidal clusters of microspheres from water-in-oil emulsions. Chem. Mater. 17, 5006-5013 (2005
27. Yin, Y-X., Xin, S., Wan, L-J., Li, C-J. & Guo, Y-G. Electrospray synthesis of silicon/carbon nanoporous microspheres as improved anode materials for lithium-ion batteries. J. Phys. Chem. C 115, 14148-14154 (2011
28. Jung, D. S., Hwang, T. H., Park, S. B. & Choi, J. W. Spray drying method for large-scale and high-performance silicon negative electrodes in Li-ion batteries. Nano Lett. 13, 2092-2097 (2013
29. Huang, J. Y. et al. In situ observation of the electrochemical lithiation of a single SnO2 nanowire electrode. Science 330, 1515-1520 (2010
30. McDowell, M. T. et al. In situ TEM of two-phase lithiation of amorphous silicon nanospheres. Nano Lett. 13, 758-764 (2013
31. DeVolder, M. F. L., Tawfick, S. H., Baughman, R. H. & Hart, A. J. Carbon nanotubes: Present and future commercial applications. Science 339, 535-539 (2013
32. Liu, N., Hu, L., McDowell, M. T., Jackson, A. & Cui, Y. Prelithiated silicon nanowires as an anode for lithium ion batteries. ACS Nano 5, 6487-6493 (2011
33. Li, N. et al. Sol-gel coating of inorganic nanostructures with resorcinolformaldehyde resin. Chem. Commun. 49, 5135-5137 (2013