Interactions between the room-temperature ionic liquid [C2C 1Im][OTf] and Pd(111), well-ordered Al2O3, and supported Pd model catalysts from IR spectroscopy

Journal of Physical Chemistry C

Volumn 118, Issue 6, 2014, Pages 3188-3193

  Schernich, Stefan ^a   Kostyshyn, Dmytro ^a   Wagner, Valentin ^a   Taccardi, Nicola ^a   Laurin, Mathias ^a   Wasserscheid, Peter ^a   Libuda, Jörg ^a  

^a UNIVERSITY OF ERLANGEN NUREMBERG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 84894089992     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp5006692     Document Type: Article

References (43)

1. Wasserscheid, P.; Welton, T. Ionic Liquids in Synthesis; Wiley-VCH: Weinheim; 2007.
2. Brennecke, J. F.; Rogers, R. D.; Seddon, K. R. Ionic Liquids IV: Not Just Solvents Anymore; American Chemical Society: Washington DC, 2007.
3. Kernchen, U.; Etzold, B.; Korth, W.; Jess, A. Solid Catalyst with Ionic Liquid Layer (SCILL)-A New Concept to Improve Selectivity Illustrated by Hydrogenation of Cyclooctadiene Chem. Eng. Technol. 2007, 8, 985-994
4. Sobota, M.; Happel, M.; Amende, M.; Paape, N.; Wasserscheid, P.; Laurin, M.; Libuda, J. Ligand Effects in SCILL Model Systems: Site-Specific Interactions with Pt and Pd Nanoparticles Adv. Mater. 2011, 23, 2617-2621
5. Arras, J.; Paki, E.; Roth, C.; Radnik, J.; Lucas, M.; Claus, P. How a Supported Metal Is Influenced by an Ionic Liquid: In-Depth Characterization of SCILL-Type Palladium Catalysts and Their Hydrogen Adsorption J. Phys. Chem. C 2010, 114, 10520-10526
6. Herrmann, T.; Rößmann, L.; Lucas, M.; Claus, P. High-Performance Supported Catalysts With an Ionic Liquid Layer for the Selective Hydrogenation of Acetylene Chem. Commun. 2011, 47, 12310-12312
7. Wörz, N.; Arras, J.; Claus, P. Continuous Selective Hydrogenation of Citral in a Trickle-Bed Reactor Using Ionic Liquid Modified Catalysts Appl. Catal., A 2011, 391, 319-324
8. Meyer, C.; Hager, V.; Schwieger, W.; Wasserscheid, P. Enhanced Activity and Selectivity in n-Octane Isomerization Using a Bifunctional SCILL Catalyst J. Catal. 2012, 292, 157-165
9. Miller, S. F.; Friedrich, H. B.; Holzapfel, C. W. The Effects of SCILL Catalyst Modification on the Competitive Hydrogenation of 1-Octyne and 1,7-Octadiene versus 1-Octene ChemCatChem 2012, 4, 1337-1344
10. Nassor, E. C. O.; Tristão, J. C.; dos Santos, E. N.; Moura, F. C. C.; Lago, R. M.; Araujo, M. H. Ionic Liquid layer on Pd/C Catalyst: Membrane-Like Effect on the Selectivity for Multistep Hydrogenation Reactions J. Mol. Catal. A: Chem. 2012, 363, 74-80
11. Steinrück, H.-P. Surface Science Goes Liquid! Surf. Sci. 2010, 604, 481-484
12. 2N] Thin Films on a Well-Ordered Alumina Surface Langmuir 2010, 26, 7199-7207
13. 2N] on Au(111) Langmuir 2011, 27, 3662-3671
14. 2N] Films on Metallic and Oxidised Ni(111) Surfaces Phys. Chem. Chem. Phys. 2012, 14, 5153-5163
15. 3 (100) Surface Calculated by Density Functional Theory Int. J. Quantum Chem. 2012, 112, 3234-3239
16. Schernich, S.; Laurin, M.; Lykhach, Y.; Steinrück, H.-P.; Tsud, N.; Skála, T.; Prince, K. C.; Taccardi, N.; Matolín, V.; Wasserscheid, P. Functionalization of Oxide Surfaces through Reaction with 1,3-Dialkylimidazolium Ionic Liquids J. Phys. Chem. Lett. 2013, 4, 30-35
17. Perdikaki, A. V.; Vangeli, O. C.; Karanikolos, G. N.; Stefanopoulos, K. L.; Beltsios, K. G.; Alexandridis, P.; Kanellopoulos, N. K.; Romanos, G. E. Ionic Liquid-Modified Porous Materials for Gas Separation and Heterogeneous Catalysis J. Phys. Chem. C 2012, 116, 16398-16411
18. 2 on Ordered Alumina Films and Mixed Baria-Alumina Nanoparticles: Cooperative Versus Non-Cooperative Reaction Mechanisms J. Catal. 2008, 260, 315-328
19. Jäger, R. M.; Kuhlenbeck, H.; Freund, H.-J.; Wuttig, M.; Hoffmann, W.; Franchy, R.; Ibach, H. Formation of a Well-Odered Aluminium-Oxide Overlayer by Oxidation of NiAl(110) Surf. Sci. 1991, 259, 235-252
20. Libuda, J.; Winkelmann, F.; Bäumer, M.; Freund, H.-J.; Bertrams, T.; Neddermeyer, H.; Müller, K. Structure and Defects of an Ordered Alumina Film on NiAl(110) Surf. Sci. 1994, 318, 61-73
21. Freund, H.-J.; Bäumer, M.; Libuda, J.; Risse, T.; Rupprechter, G.; Shaikhutdinov, S. Preparation and Characterization of Model Catalysts: From Ultrahigh Vacuum to In Situ Conditions at the Atomic Dimension J. Catal. 2003, 216, 223-235
22. Libuda, J.; Freund, H.-J. Molecular Beam Experiments on Model Catalysts Surf. Sci. Rep. 2005, 57, 157-298
23. 2N]: A New Approach to the Modification of Surface Properties with Ultrathin Ionic Liquid Films ChemPhysChem 2008, 9, 2185-2190
24. Steinrück, H.-P.; Libuda, J.; Wasserscheid, P.; Cremer, T.; Kolbeck, C.; Laurin, M.; Maier, F.; Sobota, M.; Schulz, P. S.; Stark, M. Surface Science and Model Catalysis with Ionic Liquid-Modified Materials Adv. Mater. 2011, 23, 2571-2587
25. Yudanov, I. V.; Sahnoun, R.; Neyman, K. M.; Rösch, N. Metal Nanoparticles as Models of Single Crystal Surfaces and Supported Catalysts: Density Functional Study of Size Effects for CO/Pd(111) J. Chem. Phys. 2002, 117, 9887-9896
26. Bäumer, M.; Libuda, J.; Neyman, K. M.; Rösch, N.; Rupprechter, G.; Freund, H.-J. Adsorption and Reaction of Methanol on Supported Palladium Catalysts: Microscopic-Level Studies from Ultrahigh Vacuum to Ambient Pressure Conditions Phys. Chem. Chem. Phys. 2007, 9, 3541-3558
27. - J. Phys. Chem. 1993, 97, 3712-3715
28. Johnston, D. H.; Shriver, D. F. Vibrational Study of the Trifluoromethanesulfonate Anion: Unambiguous Assignment of the Asymmetric Stretching Modes Inorg. Chem. 1993, 32, 1045-1047
29. -Ethyl-3- methylimidazolium Trifluoromethanesulfonate Ionic Liquid with Alumina Nanoparticles and Organic Solvents Studied by Infrared Spectroscopy J. Phys. Chem. C 2013, 117, 12210-12217
30. Baldelli, S. Interfacial Structure of Room-Temperature Ionic Liquids at the Solid-Liquid Interface as Probed by Sum Frequency Generation Spectroscopy J. Phys. Chem. Lett. 2013, 4, 244-252
31. Greenler, R. G. Infrared Study of Adsorbed Molecules on Metal Surfaces by Reflection Techniques J. Chem. Phys. 1966, 44, 310-315
32. Pearce, H. A.; Sheppard, N. Possible Importance of a ″Metal-Surface Selection Rule″ in Interpretation of Infrared Spectra of Molecules Adsorbed on Particulate Metals; Infrared-Spectra from Ethylene Chemisorbed on Silica-Supported Metal-Catalysts Surf. Sci. 1976, 59, 205-217
33. Stöhr, J.; Outka, D. A. Determination of Molecular Orientations on Surfaces from the Angular Dependence of Near-Edge X-Ray-Absorption Fine-Structure Spectra Phys. Rev. B 1987, 36, 7891-7905
34. Faguy, P. W.; Markovic, N.; Adzic, R. R.; Fierro, C. A.; Yeager, E. B. A Study of Bisulfate Adsorption on Pt(111) Single-Crystal Electrodes Using In-Situ Fourier-Transform Infrared-Spectroscopy J. Electroanal. Chem. 1990, 289, 245-262
35. Ogasawara, H.; Sawatari, Y.; Inukai, J.; Ito, M. Adsorption of Bisulfate Anion on a Pt(111) Electrode-A Comparison of In-Situ and Ex-Situ IRAS J. Electroanal. Chem. 1993, 358, 337-342
36. Sawatari, Y.; Inukai, J.; Ito, M. The Structure of Bisulfate and Perchlorate on a Pt(111) Electrode Surface Studied by Infrared Spectroscopy and Ab-Initio Molecular Orbital Calculation J. Electron Spectrosc. Relat. Phenom. 1993, 64-5, 515-522
37. Sawatari, Y.; Sueoka, T.; Shingaya, Y.; Ito, M.; Osamura, Y. Vibrational Spectroscopic Studies of the Structure of Species Derived from the Chemisorption of Bisulfate Anion on a Pt(111) Single-Crystal Electrode Spectrochim. Acta, Part A 1994, 50, 1555-1561
38. Funtikov, A. M.; Linke, U.; Stimming, U.; Vogel, R. An In-Situ STM Study of Anion Adsorption on Pt(111) from Sulfuric-Acid-Solutions Surf. Sci. 1995, 324, L343-L348
39. Funtikov, A. M.; Stimming, U.; Vogel, R. Anion Adsorption from Sulfuric Acid Solutions on Pt(111) Single Crystal Electrodes J. Electroanal. Chem. 1997, 428, 147-153
40. Braunschweig, B.; Daum, W. Superstructures and Order-Disorder Transition of Sulfate Adlayers on Pt(111) in Sulfuric Acid Solution Langmuir 2009, 25, 11112-11120
41. Santana, J. A.; Cabrera, C. R.; Ishikawa, Y. A Density-Functional Theory Study of Electrochemical Adsorption of Sulfuric Acid Anions on Pt(111) Phys. Chem. Chem. Phys. 2010, 12, 9526-9534
42. 4/Pt(111) Interface Phys. Chem. Chem. Phys. 2013, 15, 992-997
43. Yeh, K.-Y.; Restaino, N. A.; Esopi, M. R.; Maranas, J. K.; Janik, M. J. The Adsorption of Bisulfate and Sulfate Anions over a Pt(111) Electrode: A First Principle Study of Adsorption Configurations, Vibrational Frequencies and Linear Sweep Voltammogram Simulations Catal. Today 2013, 202, 20-35