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Strictly speaking, this analysis needs to be performed in frequency space. However, where g is close to isotropic and the shape of the spectrum is not changed substantially, the errors introduced by performing double integration in field space (as in the present case) will not be significant. See ref 31, pp 42-53
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Strictly speaking, this analysis needs to be performed in frequency space. However, where g is close to isotropic and the shape of the spectrum is not changed substantially, the errors introduced by performing double integration in field space (as in the present case) will not be significant. See ref 31, pp 42-53.
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7 systems, related to that given in ref 6 but using more energy levels deriving from spin - orbit and ligand field splittings, has been applied to plots of the type shown in Figure 5. Kennedy, B. J.; Fallon, G. D.; Gatehouse, B. M.; Murray, K. S. Inorg. Chem. 1984, 23, 580-588.
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7 systems, related to that given in ref 6 but using more energy levels deriving from spin - orbit and ligand field splittings, has been applied to plots of the type shown in Figure 5. Kennedy, B. J.; Fallon, G. D.; Gatehouse, B. M.; Murray, K. S. Inorg. Chem. 1984, 23, 580-588.
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The temperatures at which the resonances appeared are affected both by the melting point of the solvent and experimental conditions such as the cold nitrogen gas flow rate through the insert dewar and whether a particular series of measurements at the various temperatures commenced with a well frozen solution (e.g, at 110 K) or from the liquid phase. Although the freezing point of CHCl3 is ca. 210 K and that of DMSO ca. 290 K, motion of the solvent molecules would appear to occur well below these temperatures resulting in a less rigid glassy medium
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