Measuring rate constants for reactions of the simplest criegee intermediate (CH2OO) by monitoring the OH radical

Journal of Physical Chemistry A

Volumn 118, Issue 4, 2014, Pages 741-747

  Liu, Yingdi ^a   Bayes, Kyle D ^a   Sander, Stanley P ^a  

^a CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CRIEGEE INTERMEDIATES; DECAY RATE; FAST PROCESS; HEXAFLUOROACETONE; LASER INDUCED FLUORESCENCE; OH RADICAL; PRESSURE DEPENDENCE;

DECAY (ORGANIC); FREE RADICALS; MOLECULES; REACTION INTERMEDIATES; SULFUR DIOXIDE;

RATE CONSTANTS;

EID: 84893455240     PISSN: 10895639     EISSN: 15205215     Source Type: Journal    
DOI: 10.1021/jp407058b     Document Type: Article

References (39)

1. 2OO) Reactions with Acetone, Acetaldehyde and Hexafluoroacetone Phys. Chem. Chem. Phys. 2012, 14, 10391-10400
2. 2 Science 2012, 335, 204-207
3. Criegee, R. Mechanism of Ozonolysis Angew. Chem. 1975, 14, 745-752
4. 3 with Selected Alkenes Int. J. Chem. Kinet. 2002, 34, 73-85
5. Martinez, R. I.; Herron, J. T.; Huie, R. E. The Mechanism of Ozone-Alkene Reactions in the Gas Phase. A Mass Spectrometric Study of the Reactions of Eight Linear and Branched-Chain Alkenes J. Am. Chem. Soc. 1981, 103, 3807-3820
6. Atkinson, R.; Carter, W. P. L. Kinetics and Mechanisms of the Gas-Phase Reactions of Ozone with Organic Compounds Under Atmospheric Conditions Chem. Rev. 1984, 84, 437-470
7. 3 with a Series of Terpenes J. Geophys. Res. Atmos. 1992, 97, 6065-6073
8. Paulson, S. E.; Chung, M. Y.; Hasson, A. S. OH Radical Formation From the Gas-Phase Reaction of Ozone with Terminal Alkenes and the Relationship between Structure and Mechanism J. Phys. Chem. A 1999, 103, 8125-8138
9. Kroll, J. H.; Hanisco, T. F.; Donahue, N. M.; Demerjian, K. L.; Anderson, J. G. Accurate, Direct Measurements of OH Yields from Gas-Phase Ozone-Alkene Reactions Using an In Situ LIF Instrument Geophys. Res. Lett. 2001, 28, 3863-3866
10. 2OO J. Am. Chem. Soc. 2012, 134, 20045-20048
11. 3HOO J. Chem. Phys. 2013, 138, 244307
12. Niki, H.; Maker, P. D.; Savage, C. M.; Breitenbach, L. P.; Hurley, M. D. FTIR Spectroscopic Study of the Mechanism for the Gas Phase Reaction between Ozone and Tetramethylethylene J. Phys. Chem. 1987, 91, 941-6
13. Herron, J. T.; Huie, R. E. Stopped-flow Studies of the Mechanisms of Ozone-Alkene Reactions in the Gas Phase Propene and Isobutene Int. J. Chem. Kinet. 1978, 10, 1019-1041
14. 3 with a Series of Monoterpenes and Related Compounds at 296K ± 2K Int. J. Chem. Kinet. 1990, 22, 871
15. x Formation in the Gas-Phase Ozone-Alkene Reaction. 1. Direct, Pressure-Dependent Measurements of Prompt OH Yields J. Phys. Chem. A 2001, 105, 1554-1560
16. 3CHOO Generated by the trans-2-Butene Reaction with Ozone in the Gas Phase J. Phys. Chem. A 2000, 104, 9921-9932
17. Donahue, N. M.; Drozd, G. T.; Epstein, S. A.; Presto, A. A.; Kroll, J. H. Adventures in Ozoneland: Down the Rabbit-Hole Phys. Chem. Chem. Phys. 2011, 13, 10848-10857
18. Anglada, J. M.; Crehuet, R.; Bofill, J. M. The Ozonolysis of Ethylene: A Theoretical Study of the Gas-Phase Reaction Mechanism Chem.-Eur. J. 1999, 5, 1809-1822
19. Gutbrod, R.; Schindler, R. N.; Kraka, E.; Cremer, D. Formation of OH Radicals in the Gas Phase Ozonolysis of Alkenes, the Unexpected Role of Carbonyl Oxides Chem. Phys. Lett. 1996, 252, 221-229
20. Fenske, J. D.; Hasson, A. S.; Paulson, S. E.; Kuwata, K. T.; Ho, A.; Houk, K. N. The Pressure Dependence of the OH Radical Yield from Ozone-Alkene Reactions J. Phys. Chem. A 2000, 104, 7821-7833
21. 2 J. Phys. Chem. Lett. 2012, 3, 3399-3403
22. 2" J. Phys. Chem. Lett. 2013, 4, 3824
23. Mollner, A. K.; Valluvadasan, S.; Feng, L.; Sprague, M. K.; Okumura, M.; Milligan, D. B.; Bloss, W. J.; Sander, S. P.; Martien, P. T.; Harley, R. A.; McCoy, A. B.; Carter, W. P. L. Rate of Gas Phase Association of Hydroxyl Radical and Nitrogen Dioxide Science 2010, 330, 646-649
24. 2 J. Chem. Phys. 1996, 105, 10224
25. Haynes, W. CRC Handbook of Chemistry and Physics, 94 th ed.; CRC Press: Boca Raton, FL, 2013.
26. 2 in the Temperature Range 220-360 K J. Phys. Chem. A 2006, 110, 12177-12183
27. 2 J. Phys. Chem. 1995, 99, 13126-13131
28. 2 Phys. Chem. Chem. Phys. 2013, 15, 19119-19124
29. 2 Phys. Chem. Chem. Phys. 2011, 13, 11671-11677
30. Horie, O.; Schafer, C.; Moortgat, G. K. High Reactivity of Hexafluoroacetone toward Criegee Intermediates in the Gas-Phase Ozonolysis of Simple Alkenes Int. J. Chem. Kinet. 1999, 31, 261-269
31. 2, and Their Fate in the Atmosphere Phys. Chem. Chem. Phys. 2012, 14, 14682-14695
32. 2 in the Upper-Troposphere? Atmos. Chem. Phys. 2012, 12, 1339-1351
33. 2I J. Chem. Phys. 1980, 72, 6531-6545
34. 2 J. Phys. Chem. A 2005, 109, 10824-10831
35. 2COO) in Ozone-Olefin Reactions via Microwave Spectroscopy Chem. Phys. Lett. 1977, 51, 453-456
36. 2 and CO, from the Reaction of Ozone with Ethylene Chem. Phys. Lett. 1977, 51, 457-459
37. Wadt, W. R.; Goddard, W. A. Electronic Structure of the Criegee Intermediate. Ramifications for the Mechanism of Ozonolysis J. Am. Chem. Soc. 1975, 97, 3004-3021
38. Vereecken, L.; Francisco, J. S. Theoretical Studies of Atmospheric Reaction Mechanisms in the Troposphere Chem. Soc. Rev. 2012, 41, 6259-6293
39. Olzmann, M.; Kraka, E.; Cremer, D.; Gutbrod, R.; Andersson, S. Energetics, Kinetics, and Product Distributions of the Reactions of Ozone with Ethene and 2,3-Dimethyl-2-Butene J. Phys. Chem. A 1997, 101, 9421-9429