One-step conversion of biomass-derived 5-hydroxymethylfurfural to 1,2,6-hexanetriol over ni-co-al mixed oxide catalysts under mild conditions

ACS Sustainable Chemistry and Engineering

Volumn 2, Issue 2, 2014, Pages 173-180

  Yao, Shengxi ^a   Wang, Xicheng ^a   Jiang, Yijun ^a   Wu, Feng ^a   Chen, Xinguo ^a   Mu, Xindong ^a,b  

^a QINGDAO INSTITUTE OF BIOENERGY AND BIOPROCESS TECHNOLOGY   (China)

^b Qingdao Engineering Research Center for Biomass Green Chemical Conversion   (China)

Author keywords

1,2,6 Hexanetriol; 5 Hydroxymethylfurfural; CoO; Furan derivatives; Mixed metal oxide catalyst; NiO

Indexed keywords

ALUMINUM ALLOYS; ALUMINUM METALLOGRAPHY; ALUMINUM OXIDE; CARBON DIOXIDE; CATALYST ACTIVITY; COBALT ALLOYS; COBALT METALLOGRAPHY; METALS; NICKEL OXIDE; TEMPERATURE PROGRAMMED DESORPTION; X RAY POWDER DIFFRACTION;

1,2,6-HEXANETRIOL; 5 HYDROXYMETHYL FURFURALS; FURAN DERIVATIVES; H2 TEMPERATURE-PROGRAMMED REDUCTION; HYDROTALCITE-LIKE COMPOUND (HTLCS); MILD REACTION CONDITIONS; MIXED METAL OXIDE CATALYST; PRODUCT DISTRIBUTIONS;

COBALT COMPOUNDS;

EID: 84893319030     PISSN: None     EISSN: 21680485     Source Type: Journal    
DOI: 10.1021/sc4003714     Document Type: Article

References (30)

1. Rosatella, A. A.; Simeonov, S. P.; Frade, R. F. M.; Afonso, C. A. M. 5-Hydroxymethylfurfural (HMF) as a building block platform: Biological properties, synthesis and synthetic applications Green Chem. 2011, 13 (4) 754-793
2. Tess, R. W.; Harline, R. D.; Mika, T. F. 1,2,6-Hexanetriol in alkyd resins Ind. Eng. Chem. 1957, 49 (3) 374-378
3. Miura, Y.; Hata, M.; Yuge, M.; Numano, K.; Iwakiri, K. Allergic contact dermatitis from 1,2,6-hexanetriol in fluocinonide cream Contact Dermatitis 1999, 41 (2) 118-119
4. Endo, K.; Sawada, T. Control of polymer structure by a chain-transfer reaction in the radical polymerization of acrylamide by beta-mercaptopropionic acid and 1,2,6-hexanetriol trithioglycolate Colloid Polym. Sci. 2001, 279 (11) 1058-1063
5. Buntara, T.; Noel, S.; Phua, P.; Melián-Cabrera, I. Catalyst screening studies on the conversion of 1,2,6-hexanetriol to 1,6-hexanediol Top. Catal. 2012, 55 (7-10) 612-619
6. Schirmann, J. P.; Weiss, F.; Benite, P. Process for the preparation of 1,2,6-hexanetriol. U.S. Patent 3773842, 1973.
7. Liu, L.; Ye, X. P.; Bozell, J. J. A comparative review of petroleum-based and bio-based acrolein production ChemSusChem 2012, 5 (7) 1162-1180
8. Nakagawa, Y.; Tomishige, K. Production of 1,5-pentanediol from biomass via furfural and tetrahydrofurfuryl alcohol Catal. Today 2012, 195 (1) 136-143
9. Koso, S.; Nakagawa, Y.; Tomishige, K. Mechanism of the hydrogenolysis of ethers over silica-supported rhodium catalyst modified with rhenium oxide J. Catal. 2011, 280 (2) 221-229
10. Koso, S.; Furikado, I.; Shimao, A.; Miyazawa, T.; Kunimori, K.; Tomishige, K. Chemoselective hydrogenolysis of tetrahydrofurfuryl alcohol to 1,5-pentanediol Chem. Commun. 2009, 15, 2035-2037
11. Chen, K.; Koso, S.; Kubota, T.; Nakagawa, Y.; Tomishige, K. Chemoselective hydrogenolysis of tetrahydropyran-2-methanol to 1,6-hexanediol over rhenium-modified carbon-supported rhodium catalysts ChemCatChem 2010, 2 (5) 547-555
12. Chen, K.; Mori, K.; Watanabe, H.; Nakagawa, Y.; Tomishige, K. C-O bond hydrogenolysis of cyclic ethers with OH groups over rhenium-modified supported iridium catalysts J. Catal. 2012, 294 (0) 171-183
13. Chia, M.; Pagán-Torres, Y. J.; Hibbitts, D.; Tan, Q.; Pham, H. N.; Datye, A. K.; Neurock, M.; Davis, R. J.; Dumesic, J. A. Selective hydrogenolysis of polyols and cyclic ethers over bifunctional surface sites on rhodium-rhenium catalysts J. Am. Chem. Soc. 2011, 133 (32) 12675-12689
14. 4 catalyst Chem. Commun. 2011, 47 (13) 3924-3926
15. Buntara, T.; Noel, S.; Phua, P. H.; Melián-Cabrera, I.; de Vries, J. G.; Heeres, H. J. Caprolactam from renewable resources: Catalytic conversion of 5-hydroxymethylfurfural into caprolactone Angew. Chem., Int. Ed. 2011, 50 (31) 7083-7087
16. x catalyst in aqueous phase Green Chem. 2012, 14 (12) 3402-3409
17. Zhou, S.; Qian, Z.; Sun, T.; Xu, J.; Xia, C. Catalytic wet peroxide oxidation of phenol over Cu-Ni-Al hydrotalcite Appl. Clay Sci. 2011, 53 (4) 627-633
18. Basile, F.; Benito, P.; Fornasari, G.; Vaccari, A. Hydrotalcite-type precursors of active catalysts for hydrogen production Appl. Clay Sci. 2010, 48 (1-2) 250-259
19. Xu, W. J.; Liu, X. H.; Ren, J. W.; Zhang, P.; Wang, Y. Q.; Guo, Y. L.; Guo, Y.; Lu, G. Z. A novel mesoporous Pd/cobalt aluminate bifunctional catalyst for aldol condensation and following hydrogenation Catal. Commun. 2010, 11 (8) 721-726
20. 4 solid solutions in multiphase Ni-Co-O systems Ind. Eng. Chem. Res. 2011, 50 (4) 2015-2020
21. 2 reforming of methane Catal. Today. 2009, 148 (3-4) 206-211
22. x on well-mixed oxides derived from Co-Mg/Al hydrotalcite-like compounds J. Phys. Chem. B 2006, 110 (9) 4291-4300
23. Xu, W. J.; Liu, X. H.; Ren, J. W.; Liu, H. H.; Ma, Y. C.; Wang, Y. Q.; Lu, G. Z. Synthesis of nanosized mesoporous Co-Al spinel and its application as solid base catalyst Microporous Mesoporous Mater. 2011, 142 (1) 251-257
24. Hermes, N. A.; Lansarin, M. A.; Perez-Lopez, O. W. Catalytic decomposition of methane over M-Co-Al catalysts (M = Mg, Ni, Zn, Cu) Catal. Lett. 2011, 141 (7) 1018-1025
25. He, L.; Berntsen, H.; Ochoa-Fernandez, E.; Walmsley, J. C.; Blekkan, E. A.; Chen, D. Co-Ni catalysts derived from hydrotalcite-like materials for hydrogen production by ethanol steam reforming Top. Catal. 2009, 52 (3) 206-217
26. x and soot particulate over Co-Al mixed oxide catalysts derived from hydrotalcites Catal. Commun. 2007, 8 (11) 1659-1664
27. Marco, J. F.; Gancedo, J. R.; Ortiz, J.; Gautier, J. L. Characterization of the spinel-related oxides Ni(x)Co(3- x)O4 (x = 0.3, 1.3, 1.8) prepared by spray pyrolysis at 350 degrees C Appl. Surf. Sci. 2004, 227 (1-4) 175-186
28. 2 catalysts J. Catal. 2011, 280 (1) 17-27
29. Yan, F. Q.; Qiao, M. H.; Wei, X. M.; Liu, Q. P.; Deng, J. F.; Xu, G. Q. Coordination and reaction mechanism of furan on Ru (001) J. Chem. Phys. 1999, 111 (17) 8068-8076
30. Alamillo, R.; Tucker, M.; Chia, M.; Pagan-Torres, Y.; Dumesic, J. The selective hydrogenation of biomass-derived 5-hydroxymethylfurfural using heterogeneous catalysts Green Chem. 2012, 14 (5) 1413-1419