Thermal properties and ionic conductivities of confined LiBF4 dimethyl carbonate solutions

Journal of Physical Chemistry C

Volumn 118, Issue 1, 2014, Pages 366-375

  Burba, Christopher M ^a   Butson, Eric D ^a   Atchley, Justin R ^a   Johnson, Mioto Sato ^a  

^a NORTHEASTERN STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ELECTROLYTE SOLUTIONS; ELECTRON PARAMAGNETIC RESONANCES (EPR); GIBBS-THOMSON EQUATIONS; LITHIUM TETRAFLUOROBORATE; PHASE-TRANSITION TEMPERATURE; ROTATIONAL CORRELATION TIME; SUB-ZERO TEMPERATURES; TEMPERATURE-DEPENDENT CONDUCTIVITY;

ELECTROLYTES; ELECTRON SPIN RESONANCE SPECTROSCOPY; IONIC CONDUCTIVITY; MAGNETIC RESONANCE; MELTING POINT; SPIN DYNAMICS;

MESOPOROUS MATERIALS;

EID: 84892597490     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp409243b     Document Type: Article

References (58)

1. Schreiber, A.; Ketelsen, I.; Findenegg, G. H. Melting and Freezing of Water in Ordered Mesoporous Silica Materials Phys. Chem. Chem. Phys. 2001, 3, 1185
2. Tombari, E.; Salvetti, G.; Ferrari, C.; Johari, G. P. Thermodynamic Functions of Water and Ice Confined to 2 nm Radius Pores J. Chem. Phys. 2005, 122, 104712
3. 129Xe NMR: A Novel Method for Determining the Pore Sizes J. Phys. Chem. B 2005, 109, 757
4. 2H NMR Investigations of Acetonitrile Confined in Porous Silica Phys. Chem. Chem. Phys. 2003, 5, 2680
5. Wulff, M. Pore Size Determination by Thermoporometry Using Acetonitrile Thermochim. Acta 2004, 419, 291
6. 2H NMR Studies of Benzene Confined in Porous Solids: Melting Point Depression and Pore Size Distribution Solid State Nucl. Magn. Reson. 2004, 25, 146
7. Dosseh, G.; Xia, Y.; Alba-Simionesco, C. Cyclohexane and Benzene Confined in MCM-41 and SBA-15: Confinement Effects on Freezing and Melting J. Phys. Chem. B 2003, 107, 6445
8. Zhu, X.; Farrer, R. A.; Fourkas, J. T. Ultrafast Orientational Dynamics of Nanoconfined Benzene. Mater. Res. Soc. Symp. Proc. 2006, 899E.
9. Amanuel, S.; Bauer, H.; Bonventre, P.; Lasher, D. Nonfreezing Interfacial Layers of Cyclohexane in Nanoporous Silica J. Phys. Chem. C 2009, 113, 18983
10. Morineau, D.; Xia, Y.; Alba-Simionesco, C. Finite-Size and Surface Effects on the Glass Transition of Liquid Toluene Confined in Cylindrical Mesopores J. Chem. Phys. 2002, 117, 8966
11. Dutta, D.; Pujari, P. K.; Sudarshan, K.; Sharma, S. K. Effect of Confinement on the Phase Transition of Benzene in Nanoporous Silica: A Positron Annihilation Study J. Phys. Chem. C 2008, 112, 19055
12. Jackson, C. L.; McKenna, G. B. Vitrification and Crystallization of Organic Liquids Confined to Nanoscale Pores Chem. Mater. 1996, 8, 2128
13. Jackson, C. L.; McKenna, G. B. The Glass Transition of Organic Liquids Confined to Small Pores J. Non-Cryst. Solids 1991, 131-133, 221
14. Jackson, C. L.; McKenna, G. B. The Melting Behavior of Organic Materials Confined in Porous Solids J. Chem. Phys. 1990, 93, 9002
15. Johari, G. P. Thermodynamic Contributions from Pre-melting or Pre-transformation of Finely Dispersed Crystals Philos. Mag. A 1998, 77, 1367
16. Kittaka, S.; Ishimaru, S.; Kuranishi, M.; Matsuda, T.; Yamaguchi, T. Enthalpy and Interfacial Free Energy Changes of Water Capillary Condensed in Mesoporous Silica, MCM-41 and SBA-15 Phys. Chem. Chem. Phys. 2006, 8, 3223
17. Dutta, D.; Sharma, S. K.; Maheshwari, P.; Sudarshan, K.; Pujari, P. K. Freezing of Nanodroplets: Phase Transition of Organic Liquids Confined in Nanopores Studied by Positron Annihilation Spectroscopy Mater. Sci. Forum 2009, 607, 218
18. Bellissent-Funel, M.-C.; Lal, J.; Bosio, L. Structural Study of Water Confined in Porous Glass by Neutron Scattering J. Chem. Phys. 1993, 98, 4246
19. Fouzri, A.; Dorbez-Sridi, R.; Oumezzine, M. Water Confined in Silica Gel and in Vycor Glass at Low and Room Temperature, X-ray Diffraction Study J. Chem. Phys. 2002, 116, 791
20. Morishige, K.; Yasunaga, H.; Uematsu, H. Stability of Cubic Ice in Mesopores J. Phys. Chem. C 2009, 113, 3056
21. Coasne, B.; Fourkas, J. T. Structure and Dynamics of Benzene Confined in Silica Nanopores J. Phys. Chem. C 2011, 115, 15471
22. 6 Confined to Nanoporous Silica Glasses J. Phys. Chem. 1996, 100, 16789
23. Xia, Y.; Dosseh, G.; Morineau, D.; Alba-Simionesco, C. Phase Diagram and Glass Transition of Confined Benzene J. Phys. Chem. B 2006, 110, 19735
24. 6-Dimethyl Carbonate Solutions Relevant to Lithium Rechargeable Batteries ECS Trans. 2011, 35, 77
25. Khan, S. A.; Baker, G. L.; Colson, S. Composite Polymer Electrolytes using Fumed Silica Fillers: Rheology and Ionic Conductivity Chem. Mater. 1994, 6, 2359
26. Raghavan, S. R.; Riley, M. W.; Fedkiw, P. S.; Khan, S. A. Composite Polymer Electrolytes Based on Poly(ethylene glycol) and Hydrophobic Fumed Silica: Dynamic Rheology and Microstructure Chem. Mater. 1998, 10, 244
27. Walls, H. J.; Fedkiw, P. S.; Zawodzinski, T. A., Jr.; Khan, S. A. Ion Transport in Silica Nanocomposite Electrolytes J. Electrochem. Soc. 2003, 150, E165
28. Walls, H. J.; Riley, M. W.; Singhal, R. R.; Spontak, R. J.; Fedkiw, P. S.; Khan, S. A. Nanocomposite Electrolytes with Fumed Silica and Hectorite Clay Networks: Passive Versus Active Fillers Adv. Funct. Mater. 2003, 13, 710
29. Beck, J. S.; Vartuli, J. C.; Roth, J.; Leonowicz, M. E.; Kresge, C. T.; Schmitt, K. D.; Chu, C. T.-W.; Olson, D. H.; Sheppard, E. W.; McCullen, S. B.; Higgins, J. B.; Schlenker, J. L. A New Family of Mesoporous Molecular Sieves Prepared with Liquid Crystal Templates J. Am. Chem. Soc. 1992, 114, 10834
30. Zhao, D.; Feng, J.; Huo, Q.; Melosh, N.; Fredrickson, G. H.; Chmelka, B. F.; Stucky, G. D. Triblock Copolymer Synthesis of Mesoporous Silica with Periodic 50 to 300 Angstrom Pores Science 1998, 279, 548
31. Freed, J. H. F.; Fraenkel, G. K. Theory of Linewidths in Electron Spin Resonance Spectra J. Chem. Phys. 1963, 39, 326
32. Fraenkel, G. K. Static and Dynamic Frequency Shifts in Electron Spin Resonance Spectra J. Chem. Phys. 1965, 42, 4275
33. Goldman, S. A.; Bruno, G. V.; Polnaszek, C. F.; Freed, J. H. An ESR Study of Anisotropic Rotational Reorientation and Slow Tumbling in Liquid and Frozen Media J. Chem. Phys. 1972, 56, 716
34. Hwang, J. S.; Mason, R. P.; Hwang, L.-P.; Freed, J. H. Electron Spin Resonance Studies of Anisotropic Rotational Reorientation and Slow Tumbling in Liquid and Frozen Media. 111. Perdeuterated 2,2,6,6-Tetramethyl-4-piperidone-N- Oxide and an Analysis of Fluctuating Torques J. Phys. Chem. 1975, 79, 489
35. Kowert, B. A. Determination of the Anisotropic and Nonsecular Contributions to ESR Line Widths in Liquids J. Phys. Chem. 1981, 85, 229
36. Snipes, W.; Cupp, J.; Cohn, G.; Keith, A. Electron-Spin Resonance Analysis of Nitroxide Spin Label 2,2,6,6-tetramethylpiperidone- N -oxyl (TEMPONE) in Single Crystals of the Reduced Tempone Matrix Biophys. J. 1974, 14, 20
37. Spin Labeling: Theory and Applications; Berliner, L. J., Ed.; Academic Press: New York, 1976.
38. Orazem, M. E.; Tribollet, B. Electrochemical Impedance Spectrosopy; John Wiley & Sons, Inc.: Hoboken, NJ, 2008.
39. Impedance Spectroscopy: Theory, Experiment, and Applications, 2 nd ed.; Barsoukov, E.; Macdonald, J. R., Eds.; Wiley-Interscience: Hoboken, NJ, 2005.
40. Singh, M. P.; Singh, R. K.; Chandra, S. Properties of Ionic Liquid Confined in Porous Silica Matrix ChemPhysChem 2010, 11, 2036
41. 10 Confined in Mesoporous Silica Materials Phys. Chem. Chem. Phys. 2010, 12
42. Néouze, M.-A.; Le Bideau, J.; Gaveau, P.; Bellayer, S.; Vioux, A. Ionogels, New Materials Arising from the Confinement of Ionic Liquids within Silica-Derived Networks Chem. Mater. 2006, 18, 3931
43. Han, K. S.; Wang, X.; Dai, S.; Hagaman, E. W. Distribution of 1-Butyl-3-Methylimidazolium Bistrifluoromethylsulfonimide in Mesoporous Silica as a Function of Pore Filling J. Phys. Chem. C 2013, 117, 15754
44. Coasne, B.; Viau, L.; Vioux, A. Loading-Controlled Stiffening in Nanoconfined Ionic Liquids J. Phys. Chem. Lett. 2011, 2, 1150
45. Ho, T. A.; Argyris, D.; Cole, D. R.; Striolo, A. Aqueous NaCl and CsCl Solutions Confined in Crystalline Slit-Shaped Silica Nanopores of Varying Degree of Protonation Langmuir 2012, 28, 1256
46. Bonnaud, P. A.; Coasne, B.; Pellenq, R. J.-M. Solvated Calcium Ions in Charged Silica Nanopores J. Chem. Phys. 2012, 137, 064706
47. Zhou, J. D.; Cui, S. T.; Cochran, H. D. Molecular Simulation of Aqueous Electrolytes in Model Silica Nanochannels Mol. Phys. 2003, 101, 1089
48. Lo, W. Y.; Chan, K.-Y. Poisson-Boltzmann Calculations of Ions in Charged Capillaries J. Chem. Phys. 1994, 101, 1431
49. Rice, C. L.; Whitehead, R. Electrokinetic Flow in a Narrow Cylindrical Capillary J. Phys. Chem. 1965, 69, 4017
50. Levine, S.; Marriott, J. R.; Neale, G.; Epstein, N. Theory of Electrokinetic Flow in Fine Cylindrical Capillaries at High Zeta-Potentials J. Colloid Interface Sci. 1975, 52, 136
51. Olivares, W.; Croxton, T. L.; McQuarrie, D. A. Electrokinetic Flow in a Narrow Cylindrical Capillary J. Phys. Chem. 1980, 84, 867
52. Sigal, V. L.; Ginsburg, Y. Y. Solution of the Nonlinear Poisson-Boltzmann Equation for the Inner Problems of the Electrical Double-Layer Theory J. Phys. Chem. 1981, 85, 3736
53. Vlachy, V.; McQuarrie, D. A. Ion Distributions in a Cylindrical Capillary J. Phys. Chem. 1986, 90, 3248
54. Vlachy, V.; Haymet, A. D. J. Electrolytes in Micropores Aust. J. Chem. 1990, 43, 1961
55. Jamnik, B.; Vlachy, V. Monte Carlo and Poisson-Boltzmann Study of Electrolyte Exclusion from Charge Cylindrical Micropores J. Am. Chem. Soc. 1993, 115, 660
56. Vlachy, V.; Haymet, A. D. J. Salt Exclusion from Charged and Uncharged Micropores J. Electroanal. Chem. 1990, 283, 77
57. Vlachy, V.; Haymet, A. D. J. Electrolytes in Charged Micropores J. Am. Chem. Soc. 1989, 111, 477
58. Salis, A.; Parsons, D. F.; Broström; Medda, L.; Barse, B.; Ninham, B. W.; Monduzzi, M. Ion Specific Surface Charge Density of SBA-15 Mesoporous Silica Langmuir 2010, 26, 2484