A facile supercritical alcohol route for synthesizing carbon coated hierarchically mesoporous Li4Ti5O12 microspheres

Journal of Physical Chemistry C

Volumn 118, Issue 1, 2014, Pages 183-193

  Nugroho, Agung ^a   Chung, Kyung Yoon ^a   Kim, Jaehoon ^b  

^a Korea Institute of Science and Technology   (South Korea)

^b Sungkyunkwan University   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

DISCHARGE CAPACITIES; ELECTROCHEMICAL PERFORMANCE; HIGH-RATE PERFORMANCE; MESOPOROUS STRUCTURES; SUPERCRITICAL ETHANOL; SUPERCRITICAL METHANOL; SYNTHESIS CONDITIONS; VOLUMETRIC ENERGY DENSITIES;

CARBON; CARBONIZATION; COATINGS; LITHIUM; MICROSPHERES;

MESOPOROUS MATERIALS;

EID: 84892585501     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp4099182     Document Type: Article

References (81)

1. Arico, A. S.; Bruce, P.; Scrosati, B.; Tarascon, J.-M.; van Schalkwijk, W. Nanostructured materials for advanced energy conversion and storage devices Nat. Mater. 2005, 4, 366-377
2. Armand, M.; Tarascon, J. M. Building better batteries Nature 2008, 451, 652-657
3. TM for Automotive Applications J. Soc. Automot. Eng. Jpn. 2012, 66, 23-27
4. TM High-Safety Rechargeable Battery Toshiba Rev. 2008, 63, 54-57
5. Super-Charge Ion Battery (SCiB); http://www.toshiba.com/ind/product- display.jsp?id1=821.
6. 12 having excellent characteristics as an electrode active material for power storage cells J. Power Sources 2003, 117, 131-136
7. 4 for Rechargeable Lithium Cells J. Electrochem. Soc. 1995, 142, 1431-1435
8. 12 as negative electrode for Li-ion polymer rechargeable batteries J. Power Sources 1999, 81-82, 300-305
9. 12 prepared by molten salt method as an electrode material for hybrid electrochemical supercapacitors J. Electrochem. Soc. 2006, 153, A1472-A1477
10. 2 solid as raw material with high electrochemical performance J. Alloys Compd. 2009, 477, 665-672
11. 12 Coated with N-Doped Carbon from Ionic Liquids for Li-Ion Batteries Adv. Mater. 2011, 23, 1385-1388
12. 12 nanoparticles and their electrochemical and biocompatible superiority for lithium rechargeable batteries Chem. Commun. 2011, 47, 11474-11476
13. 12 Spinel Thin Film Electrodes with Nanocrystalline Framework for High Rate Rechargeable Lithium Batteries: Relationships among Charge Storage, Electrical Conductivity, and Nanoscale Structure Chem. Mater. 2011, 23, 4384-4393
14. 12 As High-Rate Performance Li-Ion Battery Anode Chem. Mater. 2010, 22, 2857-2863
15. 12: Effect of wall structure on electrochemical properties Chem. Mater. 2006, 18, 482-489
16. 12 Crystals by the Cooling of a Sodium Chloride Flux Cryst. Growth Des. 2011, 11, 4401-4405
17. 12 in supercritical water Electrochem. Commun. 2011, 13, 650-653
18. 12 hollow microspheres assembled by nanosheets as an anode material for high-rate lithium ion batteries Electrochim. Acta 2009, 54, 6244-6249
19. 12: one-step synthesis and electrochemical performance optimization J. Mater. Chem. 2012, 22, 17773-17781
20. Amine, K.; Belharouak, I.; Chen, Z.; Tran, T.; Yumoto, H.; Ota, N.; Myung, S.-T.; Sun, Y.-K. Nanostructured Anode Material for High-Power Battery System in Electric Vehicles Adv. Mater. 2010, 22, 3052-3057
21. 12 for high-rate lithium ion batteries J. Power Sources 2012, 200, 59-66
22. 12 as an anode material for lithium-ion batteries Electrochim. Acta 2008, 53, 7242-7247
23. 12 hollow-sphere anode material J. Power Sources 2007, 166, 514-518
24. 12 Negative Electrode via Carbon-Coated Mesoporous Uniform Pores with a Simple Self-Assembly Method Adv. Funct. Mater. 2011, 21, 4349-4357
25. 12 microspheres for high rate lithium ion batteries J. Mater. Chem. 2010, 20, 6998-7004
26. Tang, Y.; Yang, L.; Qiu, Z.; Huang, J. Template-free synthesis of mesoporous spinel lithium titanate microspheres and their application in high-rate lithium ion batteries J. Mater. Chem. 2009, 19, 5980-5984
27. 12 anode for lithium batteries Electrochim. Acta 2007, 53, 79-82
28. Yu, S.-H.; Pucci, A.; Herntrich, T.; Willinger, M.-G.; Baek, S.-H.; Sung, Y.-E.; Pinna, N. Surfactant-free nonaqueous synthesis of lithium titanium oxide (LTO) nanostructures for lithium ion battery applications J. Mater. Chem. 2011, 21, 806-810
29. 12 nanoporous micro-sphere as anode material for high-rate lithium-ion batteries Energy Environ. Sci. 2011, 4, 4016-4022
30. 12 Coated with C[n.63743]N Compounds Derived from Pyrolysis of Urea through a Low-Temperature Approach ChemSusChem 2012, 5, 526-529
31. 12 for Lithium Ion Batteries J. Am. Chem. Soc. 2008, 130, 14930-14931
32. 12 with double surface modification of Ti(III) and carbon J. Mater. Chem. 2009, 19, 6789-6795
33. 12 as ultra high power anode material for lithium batteries Energy Environ. Sci. 2011, 4, 1345-1351
34. Adschiri, T.; Hakuta, Y.; Arai, K. Hydrothermal Synthesis of Metal Oxide Fine Particles at Supercritical Conditions Ind. Eng. Chem. Res. 2000, 39, 4901-4907
35. Adschiri, T.; Kanazawa, K.; Arai, K. Rapid and Continuous Hydrothermal Crystallization of Metal Oxide Particles in Supercritical Water J. Am. Ceram. Soc. 1992, 75, 1019-1022
36. Adschiri, T.; Lee, Y.-W.; Goto, M.; Takami, S. Green materials synthesis with supercritical water Green Chem. 2011, 13, 1380-1390
37. Kim, J.; Park, Y.-S.; Veriansyah, B.; Kim, J.-D.; Lee, Y.-W. Continuous Synthesis of Surface-Modified Metal Oxide Nanoparticles Using Supercritical Methanol for Highly Stabilized Nanofluids Chem. Mater. 2008, 20, 6301-6303
38. Roig, Y.; Marre, S. Cardinal, T.; Aymonier, C., Synthesis of Exciton Luminescent ZnO Nanocrystals Using Continuous Supercritical Microfluidics Angew. Chem., Int. Ed. 2011, 50, 12071-12074
39. Slostowski, C.; Marre, S.; Babot, O.; Toupance, T.; Aymonier, C. Near- and Supercritical Alcohols as Solvents and Surface Modifiers for the Continuous Synthesis of Cerium Oxide Nanoparticles Langmuir 2012, 28, 16656-16663
40. Sue, K.; Suzuki, M.; Arai, K.; Ohashi, T.; Ura, H.; Matsui, K.; Hakuta, Y.; Hayashi, H.; Watanabe, M.; Hiaki, T. Size-controlled synthesis of metal oxide nanoparticles with a flow-through supercritical water method Green Chem. 2006, 8, 634-638
41. Veriansyah, B.; Kim, J.-D.; Min, B. K.; Kim, J. Continuous synthesis of magnetite nanoparticles in supercritical methanol Mater. Lett. 2010, 64, 2197-2200
42. 2 Particles Prepared by Supercritical Water Synthesis Electrochem. Solid-State Lett. 2000, 3, 256-258
43. 2 in supercritical water J. Supercrit. Fluids 2009, 50, 250-256
44. 4 obtained through a one step continuous hydrothermal synthesis process working in supercritical water Solid State Ionics 2009, 180, 861-866
45. 4) synthesized continuously in supercritical water: Comparison with solid-state method J. Supercrit. Fluids 2011, 55, 1027-1037
46. 4) particles synthesized in subcritical and supercritical water J. Supercrit. Fluids 2005, 35, 83-90
47. 4 (M = Fe, Mn) colloidal nanocrystals by supercritical ethanol process Chem. Commun. 2010, 46, 7548-7550
48. 4) nanoparticles in supercritical water: Effect of mixing tee J. Supercrit. Fluids 2013, 73, 70-79
49. 4): Comparison between continuous supercritical hydrothermal method and solid-state method Chem. Eng. J. 2012, 198-199, 318-326
50. Kanamura, K.; Dokko, K.; Kaizawa, T. Synthesis of Spinel LiMn2 O 4 by a Hydrothermal Process in Supercritical Water with Heat-Treatment J. Electrochem. Soc. 2005, 152, A391-A395
51. 2 cathode materials by using a supercritical water method in a batch reactor Electrochim. Acta 2010, 55, 3015-3021
52. 4 (M = Fe, Mn) as High-Capacity Li-Ion Battery Electrode Nano Lett. 2012, 12, 1146-1151
53. 4 anode material by using supercritical water in a batch reactor J. Supercrit. Fluids 2010, 55, 252-258
54. 12 Nanocrystals for Li Ion Battery Applications J. Electrochem. Soc. 2012, 159, A166-A171
55. 12/carbon nanocomposite synthesized by a supercritical alcohol approach RSC Adv. 2012, 2, 10805-10808
56. 12 in supercritical water for Li-ion batteries: Reaction mechanism and high-rate performance Electrochim. Acta 2012, 78, 623-632
57. 12 nanosheets as anode materials for Li-ion batteries Electrochim. Acta 2010, 55, 6596-6600
58. 12 as a high-performance anode material for Li-ion batteries J. Mater. Sci. 2009, 44, 198-203
59. 12 nanocrystallites as anode material for lithium-ion batteries Solid State Ionics 2007, 178, 1590-1594
60. 12 spinel as electrode for electrochemical generators J. Power Sources 2003, 119-121, 88-94
61. 12 Particles by Mechanically Activating Intermediates with Amino Acids J. Am. Ceram. Soc. 2008, 91, 1522-1527
62. Mathias, P. M.; Copeman, T. W. Extension of the Peng-Robinson equation of state to complex mixtures: Evaluation of the various forms of the local composition concept Fluid Phase Equilib. 1983, 13, 91-108
63. Veriansyah, B.; Park, H.; Kim, J.-D.; Min, B. K.; Shin, Y. H.; Lee, Y.-W.; Kim, J. Characterization of surface-modified ceria oxide nanoparticles synthesized continuously in supercritical methanol J. Supercrit. Fluids 2009, 50, 283-291
64. Veriansyah, B.; Kim, J.-D.; Min, B. K.; Shin, Y. H.; Lee, Y.-W.; Kim, J. Continuous synthesis of surface-modified zinc oxide nanoparticles in supercritical methanol J. Supercrit. Fluids 2010, 52, 76-83
65. 12 Appl. Surf. Sci. 2007, 253, 9336-9341
66. 2 by Diffuse Reflectance Infrared Fourier Transform Spectroscopy Appl. Spectrosc. 1983, 37, 38-44
67. Bonhomme, F.; Lassègues, J. C.; Servant, L. Raman Spectroelectrochemistry of a Carbon Supercapacitor J. Electrochem. Soc. 2001, 148, E450-E458
68. Ding, Z.; Zhao, L.; Suo, L.; Jiao, Y.; Meng, S.; Hu, Y.-S.; Wang, Z.; Chen, L. Towards understanding the effects of carbon and nitrogen-doped carbon coating on the electrochemical performance of Li4Ti5O12 in lithium ion batteries: a combined experimental and theoretical study Phys. Chem. Chem. Phys. 2011, 13, 15127-15133
69. Rouzaud, J. N.; Oberlin, A.; Beny-Bassez, C. Carbon films: Structure and microtexture (optical and electron microscopy, Raman spectroscopy) Thin Solid Films 1983, 105, 75-96
70. Wilcox, J. D.; Doeff, M. M.; Marcinek, M.; Kostecki, R. Factors Influencing the Quality of Carbon Coatings on LiFePO4 J. Electrochem. Soc. 2007, 154, A389-A395
71. 4 Electrochem. Solid-State Lett. 2003, 6, A207-A209
72. Li, H.; Zhou, H. Enhancing the performances of Li-ion batteries by carbon-coating: present and future Chem. Commun. 2012, 48, 1201-1217
73. Wanger, C. D.; Riggs, W. M.; Davis, L. E.; Moulder, J. F.; E.Muilenberg, G. Handbook of X-ray Photoelectron Spectroscopy; Perkin-Elmer Corp., Physical Electronics Division: Eden Prairie, MN, 1979; p 190.
74. Choi, H.; Veriansyah, B.; Kim, J.; Kim, J.-D.; Kang, J. W. Continuous synthesis of metal nanoparticles in supercritical methanol J. Supercrit. Fluids 2010, 52, 285-291
75. Kim, J.; Kim, D.; Veriansyah, B.; Won Kang, J.; Kim, J.-D. Metal nanoparticle synthesis using supercritical alcohol Mater. Lett. 2009, 63, 1880-1882
76. Nursanto, E. B.; Nugroho, A.; Hong, S.-A.; Kim, S. J.; Yoon Chung, K.; Kim, J. Facile synthesis of reduced graphene oxide in supercritical alcohols and its lithium storage capacity Green Chem. 2011, 13, 2714-2718
77. Ross, D. S.; Blessing, J. E. Alcohols as H-donor media in coal conversion. 1. Base-promoted H-donation to coal by isopropyl alcohol Fuel 1979, 58, 433-437
78. Nakagawa, T.; Ozaki, H.; Kamitanaka, T.; Takagi, H.; Matsuda, T.; Kitamura, T.; Harada, T. Reactions of supercritical alcohols with unsaturated hydrocarbons J. Supercrit. Fluids 2003, 27, 255-261
79. 12 as a function of heat-treatment atmosphere J. Power Sources 2006, 154, 287-289
80. 12 (spinel) exhibiting fast Li insertion Electrochem. Solid-State Lett. 2002, 5, A39-A42
81. Shannon, R. Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Acta Crystallogr., Sect. A 1976, 32, 751-767