Dynamic kinetic resolution of allylic sulfoxides by Rh-catalyzed hydrogenation: A combined theoretical and experimental mechanistic study

Journal of the American Chemical Society

Volumn 136, Issue 1, 2014, Pages 291-298

  Dornan, Peter K ^a,b,c   Kou, Kevin G M ^a,c   Houk, K N ^b   Dong, Vy M ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b UNIVERSITY OF CALIFORNIA   (United States)

^c UNIVERSITY OF TORONTO   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

ASYMMETRIC HYDROGENATION; COMPUTATIONAL STUDIES; DYNAMIC KINETIC RESOLUTION; MECHANISTIC STUDIES; NON-POLAR SOLVENTS; OLEFIN HYDROGENATION; SIGMATROPIC REARRANGEMENTS; THEORETICAL MODELING;

HYDROGENATION; KINETICS; RHODIUM;

RHODIUM COMPOUNDS;

RHODIUM; RHODIUM COMPLEX; SULFOXIDE;

ARTICLE; CATALYST; DYNAMICS; ENANTIOMER; ENANTIOSELECTIVITY; EPIMERIZATION; EXPERIMENTAL STUDY; HYDROGENATION; HYPOBARISM; ISOMERIZATION; KINETICS; RACEMIZATION; THEORETICAL STUDY;

CATALYSIS; COMPUTER SIMULATION; HYDROGENATION; KINETICS; METHYLENE CHLORIDE; RHODIUM; STEREOISOMERISM; SULFOXIDES;

EID: 84892140949     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja409824b     Document Type: Article

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