Fatty acid methyl ester production from acid oil using silica sulfuric acid: Process optimization and reaction kinetics

Chemical Papers

Volumn 68, Issue 4, 2014, Pages 472-483

  Shah, Krunal A ^a   Parikh, Jigisha K ^a   Dholakiya, Bharat Z ^a   Maheria, Kalpana C ^a  

^a SARDAR VALLABHBHAI NATIONAL INSTITUTE OF TECHNOLOGY   (India)

Author keywords

acid oil; biodiesel; esterification; silica sulfuric acid; Taguchi method

Indexed keywords

EID: 84891408630     PISSN: 03666352     EISSN: 13369075     Source Type: Journal    
DOI: 10.2478/s11696-013-0488-4     Document Type: Article

References (54)

1. Allen, C. A. W., Watts, K. C., Ackman, R. G., & Pegg, M. J. (1999). Predicting the viscosity of biodiesel fuels from their fatty acid ester composition. Fuel, 78, 1319-1326. DOI: 10.1016/s0016-2361(99)00059-9.
2. American Oil Chemists' Society, AOCS (2009a). AOCS official method: Iodine value of fats and oils cyclohexane-acetic acid method. AOCS Cd 1d-92. Urbana, IL, USA.
3. American Oil Chemists' Society, AOCS (2009b). AOCS official method: Saponification value modified method using methanol. AOCS Cd 3c-91. Urbana, IL, USA.
4. American Society for Testing and Materials, ASTM (2002a). ASTM standard: Standard test method for density, relative density (specific gravity), or API gravity of crude petroleum and liquid petroleum products by hydrometer method. ASTM D1298-99. West Conshohocken, PA, USA. DOI: 10.1520/D1298-99.
5. American Society for Testing and Materials, ASTM (2002b). ASTM standard: Standard test method for density, relative density, and API gravity of liquids by digital density meter. ASTM D4052-96. West Conshohocken, PA, USA. DOI: 10.1520/D4052-96.
6. American Society for Testing and Materials, ASTM (2002c). ASTM standard: Standard test method for acid number of petroleum product by potentiometric titration. ASTM D664-95. West Conshohocken, PA, USA. DOI: 10.1520/D0664-95.
7. American Society for Testing and Materials, ASTM (2002d). ASTM standard: Standard test method for flash and fire point by Cleveland open cup tester. ASTM D92-02. West Conshohocken, PA, USA. DOI: 10.1520/D0092-02.
8. American Society for Testing and Materials, ASTM (2002e). ASTM standard: Standard test method for pour point of petroleum products. ASTM D97-02. West Conshohocken, PA, USA. DOI: 10.1520/D0097-02.
9. American Society for Testing and Materials, ASTM (2002f). ASTM standard: Standard test method for cloud point of petroleum products. ASTM D2500-02. West Conshohocken, PA, USA. DOI: 10.1520/D2500-02.
10. American Society for Testing and Materials, ASTM (2002g). ASTM standard: Standard specification for biodiesel fuel (B100) blend stock for distillate fuels. ASTM D6751-02. West Conshohocken, PA, USA. DOI: 10.1520/D6751-02.
11. American Society for Testing and Materials, ASTM (2005). ASTM standard: Standard test method for determination of the unsaponifiable nonvolatile matter in sulfated oils. ASTM D5553-95. West Conshohocken, PA, USA. DOI: 10.1520/D5553-95.
12. American Society for Testing and Materials, ASTM (2006). ASTM standard: Standard test method for fatty acids content of naval stores, including rosin, tall oil, and related products. ASTM D1585-96. West Conshohocken, PA, USA. DOI: 10.1520/D1585-96.
13. Balat, M., & Balat, H. (2008). A critical review of bio-diesel as a vehicular fuel. Energy Conversion and Management, 49, 2727-2741. DOI: 10.1016/j.enconman.2008.03.016.
14. Berrios, M., Siles, J., Martin, M. A., & Martin, A. (2007). A kinetic study of esterification of free fatty acids (FFA) in sunflower oil. Fuel, 86, 2383-2388. DOI: 10.1016/j.fuel.2007.02.002. (Pubitemid 47371290)
15. Brahmkhatri, V., & Patel, A. (2011). 12-Tungstophosphoric acid anchored to SBA-15: An efficient, environmentally benign reusable catalyst for biodiesel production by esterification of free fatty acids. Applied Catalysis A: General, 403, 161-172. DOI: 10.1016/j.apcata.2011.06.027.
16. Černoch, M., Hájek, M., & Skopal, F. (2010). Relationship among flash point, carbon residue, viscosity and some impurities in biodiesel after ethanolysis of rape-seed oil. Bioresource Technology, 101, 7397-7401. DOI: 10.1016/j.biortech.2010.05.003.
17. Chen, R. X., Ju, Y. H., & Mou, C. Y. (2007). Direct synthesis of mesoporous sulfated silica-zirconia catalysts with high catalytic activity for biodiesel via esterification. The Journal of Physical Chemistry C, 111, 18731-18737. DOI: 10.1021/jp0749221.
18. Chen, X., Du, W., & Liu, D. H. (2008). Response surface optimization of biocatalytic biodiesel production with acid oil. Biochemical Engineering Journal, 40, 423-429. DOI: 10.1016/j.bej.2008.01.012.
19. Chongkhong, S., Tongurai, C., Chetpattananondh, P., & Bunyakan, C. (2007). Biodiesel production by esterification of palm fatty acid distillate. Biomass and Bioenergy, 31, 563-568. DOI: 10.1016/j.biombioe.2007.03.001. (Pubitemid 47031640)
20. Desai, M. A., & Parikh, J. K. (2012). Hydrotropic extraction of Citral from Cymbopogon flexuosus (Steud.) Wats. Industrial & Engineering Chemistry Research, 51, 3750-3757. DOI: 10.1021/ie202025b.
21. dos Santos Corra̧a, I. N., de Souza, S. L., Catran, M., Bernardes, O. L., Figueiredo Portilho, M., & Pereira Langone, M. A. (2011). Enzymatic biodiesel synthesis using byproduct obtained from palm oil refining. Enzyme Research, 2011, 1-8. DOI: 10.4061/2011/814507.
22. Echim, C., Verhé, R., de Greyt, W., & Stevens, C. (2009). Production of biodiesel from side-stream refining products. Energy & Environmental Science, 2, 1131-1141. DOI: 10.1039/b905925c.
23. European Committee for Standardization, CEN (2008). European standard: Automotive fuels - Fatty acid methyl esters (FAME) for diesel engines - Requirements and test methods. EN 14214:2008+A1:2009. Brussels, Belgium.
24. Fang, L., Xing, R., Wu, H. H., Li, X. H., Liu, Y. M., & Wu, P. (2010). Clean synthesis of biodiesel over solid acid catalysts of sulfonated mesopolymers. Science China Chemistry, 53, 1481-1486. DOI: 10.1007/s11426-010- 3206-x.
25. Ghosh, S., & Bhattacharya, D. K. (1995). Utilization of acid oil in making valuable fatty products by microbial lipase technology. Journal of the American Oil Chemist's Society, 72, 1541-1544. DOI: 10.1007/bf02577851.
26. Guo, F., Xiu, Z. L., & Liang, Z. X. (2012). Synthesis of biodiesel form acidified soybean soapstock using lignin-derived carbonaceous catalysts. Applied Energy, 98, 47-52. DOI: 10.1016/j.apenergy.2012.02.071.
27. Haas, M. J., Michalski, P. J., Runyon, S., Nunez, A., & Scott, K. M. (2003). Production of FAME from acid oil, a byproduct of vegetable oil refining. Journal of the American Oil Chemist's Society, 80, 97-102. DOI: 10.1007/s11746-003- 0658-4.
28. Haas, M. J., McAloon, A. J., Yee, W. C., & Foglia, T. A. (2006). A process model to estimate biodiesel production costs. Bioresource Technology, 97, 671-678. DOI: 10.1016/j.biortech.2005.03.039. (Pubitemid 41773027)
29. Kiss, A. A., Dimian, A. C., & Rothenberg, G. (2006). Solid acid catalysts for biodiesel production - Towards sustainable energy. Advanced Synthesis & Catalysis, 348, 75-81. DOI: 10.1002/adsc.200505160. (Pubitemid 43155978)
30. Kulkarni, M. G., & Dalai, A. K. (2006). Waste cooking oil - An economical source for biodiesel: A review. Industrial & Engineering Chemistry Research, 45, 2901-2913. DOI: 10.1021/ie0510526.
31. Lam, M. K., Lee, K. T., & Mohamed, A. R. (2010). Homogeneous, heterogeneous and enzymatic catalysis for transesterification of high free fatty acid oil (waste cooking oil) to biodiesel: A review. Biotechnology Advances, 28, 500-518. DOI: 10.1016/j.biotechadv.2010.03.002.
32. Levenspiel, O. (2007). Chemical reaction engineering (3rd ed.). India: Willey India Pvt. Ltd.
33. Li, Y., Zhang, X. D., & Sun, L. (2010). Fatty acid methyl esters from soapstocks with potential use as biodiesel. Energy Conversion and Management, 51, 2307-2311. DOI: 10.1016/j.enconman.2010.04.003.
34. Lin, L., Zhou, C. S., Saritporn, W., Shen, X. Q., & Dong, M. D. (2011). Opportunities and challenges for biodiesel fuel. Applied Energy, 88, 1020-1031. DOI: 10.1016/j.apenergy.2010.09.029.
35. Lou, W. Y., Zong, M. H., & Duan, Z. Q. (2008). Efficient production of biodiesel from high free fatty acid-containing waste oils using various carbohydrate-derived solid acid catalysts. Bioresource Technology, 99, 8752-8758. DOI: 10.1016/j.biortech.2008.04.038.
36. Mbaraka, I. K., Radu, D. R., Lin, V. S. Y., & Shanks, B. H. (2003). Organosulfonic acid-functionalized mesoporous silicas for the esterification of fatty acid. Journal of Catalysis, 219, 329-336. DOI: 10.1016/s0021-9517(03) 00193-3.
37. Melero, J. A., Iglesias, J., & Morales, G. (2009). Heterogeneous acid catalysts for biodiesel production: current status and future challenges. Green Chemistry, 11, 1285-1308. DOI: 10.1039/b902086a.
38. Özbay, N., Otkar, N., & Tapan, N. A. (2008). Esterification of free fatty acids in waste cooking oils (WCO): Role of ion-exchange resins. Fuel, 87, 1789-1798. DOI: 10.1016/j.fuel.2007.12.010.
39. Phan, A. N., & Phan T. M. (2008). Biodiesel production from waste cooking oils. Fuel, 87, 3490-3496. DOI: 10.1016/j.fuel.2008.07.008.
40. Ramachandran, K., Sivakumar, P., Suganya, T., & Renganathan, S. (2011). Production of biodiesel from mixed waste vegetable oil using an aluminium hydrogen sulphate as a heterogeneous acid catalyst. Bioresource Technology, 102, 7289-72893. DOI: 10.1016/j.biortech.2011.04.100.
41. Ross, P. J. (1996). Taguchi techniques for quality engineering (2nd ed.). New York, NY, USA: McGraw-Hill.
42. Salehi, P., Zolfigol, M. A., Shirini, F., & Baghbanzadeh, M. (2006). Silica sulfuric acid and silica chloride as efficient reagents for organic reactions. Current Organic Chemistry, 10, 2171-2189. DOI: 10.2174/ 138527206778742650. (Pubitemid 44669764)
43. Shah, K. A., Maheria, K. C., & Parikh, J. K. (2011). Effect of reaction parameters on the catalytic transesterification of cotton-seed oil using silica sulfuric acid. Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, in press. DOI: 10.1080/15567036.2011.636141.
44. Shaterian, H. R., Ghashang, M., & Feyzi, M. (2008). Silica sulfuric acid as an efficient catalyst for the preparation of 2H-indazolo[2, 1-b]phthalazine-triones. Applied Catalysis A: General, 345, 128-133. DOI: 10.1016/j.apcata.2008.04.032.
45. Siti Kartina, A. K., & Nor Suhaila, M. H. (2011). Conversion of waste cooking oil (WCO) and palm fatty acid distillate (PFAD) to biodiesel. In Proceedings of 3rd International Symposium & Exhibition in Sustainable Energy & Environment, June 1-3, 2011 (pp. 42-44). Malacca: Malaysia. DOI: 10.1109/isesee.2011.5977106.
46. Srilatha, K., Kumar, C. R., Devi, B. L. A. P., Prasad, R. B. N., Prasad, P. S. S., & Lingaiah, N. (2011). Efficient solid acid catalysts for esterification of free fatty acids with methanol for the production of biodiesel. Catalysis Science & Technology, 1, 662-668. DOI: 10.1039/c1cy00085c.
47. Sun, P. Y., Sun, J., Yao, J. F., Zhang, L. X., & Xu, N. P. (2010). Continuous production of biodiesel from high acid value oils in microstructured reactor by acid-catalyzed reactions. Chemical Engineering Journal, 162, 364-370. DOI: 10.1016/j.cej.2010.04.064.
48. Taguchi, G., Chowdhury, S., & Wu, Y. (2005). Taguchi's quality engineering handbook. Hoboken, NJ, USA: Wiley.
49. Tropeca̧lo, A. I., Casimiro, M. H., Fonseca, I. M., Ramos, A. M., Vital, J., & Castanheiro, J. E. (2010). Esterification of free fatty acids to biodiesel over heteropolyacids immobilized on mesoporous silica. Applied Catalysis A: General, 390, 183-189. DOI: 10.1016/j.apcata.2010.10.007.
50. Wang, L., Du, W., Liu, D. H., Li, L. L., & Dai, N. M. (2006). Lipase-catalyzed biodiesel production from soybean oil deodorizer distillate with absorbent present in tert-butanol system. Journal of Molecular Catalysis B: Enzymatic, 43, 29-32. DOI: 10.1016/j.molcatb.2006.03.005. (Pubitemid 44693416)
51. Wang, Z. M., Lee, J. S., Park, J. Y., Wu, C. Z., & Yuan, Z. H. (2007). Novel biodiesel production technology from soybean soapstock. Korean Journal of Chemical Engineering, 24, 1027-1030. DOI: 10.1007/s11814-007-0115-6.
52. Zhang, L. P, Sheng, B. Y., Xin, Z., Liu, Q., & Sun, S. Z. (2010). Kinetics of transesterification of palm oil and dimethyl carbonate for biodiesel production at the catalysis of heterogeneous base catalyst. Bioresource Technology, 101, 8144-8150. DOI: 10.1016/j.biortech.2010.05.069.
53. Zhang, Y., Dubé, M. A., McLean, D. D., & Kates, M. (2003). Biodiesel production from waste cooking oil: 1. Process design and technological assessment. Bioresource Technology, 89, 1-16. DOI: 10.1016/s0960-8524(03)00040- 3. (Pubitemid 36379206)
54. 2 as a novel heterogeneous system for production of thionitriles and disulfides under mild conditions. Tetrahedron, 57, 9509-9511. DOI: 10.1016/s0040-4020(01)00960-7. (Pubitemid 33016767)