Evidence of entropy-driven bistability through 15N NMR analysis of a temperature- and solvent-induced, chiroptical switching polycarbodiimide

Journal of the American Chemical Society

Volumn 135, Issue 51, 2013, Pages 19292-19303

  Reuther, James F ^a,b   Novak, Bruce M ^b  

^a NORTH CAROLINA STATE UNIVERSITY   (United States)

^b UNIVERSITY OF TEXAS AT DALLAS   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHIROPTICAL SWITCHING; CHLOROFORM SOLVENTS; ENDOTHERMIC PROCESS; LARGE DEVIATIONS; NMR AND IR SPECTRUM; POLYMER CONFORMATION; SPECIFIC OPTICAL ROTATIONS; VAN'T HOFF ANALYSIS;

CONFORMATIONS; ENTHALPY; ENTROPY; NAPHTHALENE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ORGANIC SOLVENTS; POLYMERS; SOLVENTS;

SWITCHING;

CHLOROFORM; IMIDE; NITROGEN 15; POLYCARBODIIMIDE; POLYMER; SOLVENT; TOLUENE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL INTERACTION; CONFORMATION; CONFORMATIONAL TRANSITION; ENTHALPY; ENTROPY; HIGH TEMPERATURE; INFRARED SPECTROSCOPY; MOLECULAR STABILITY; NITROGEN NUCLEAR MAGNETIC RESONANCE; OPTICAL ROTATION; PROTON NUCLEAR MAGNETIC RESONANCE; SYNTHESIS; TEMPERATURE DEPENDENCE;

EID: 84891320887     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja4098803     Document Type: Article

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