Esterification of oleic acid and high acid content palm oil over an acid-activated bentonite catalyst

Applied Clay Science

Volumn 87, Issue , 2014, Pages 272-277

  Jeenpadiphat, Sirima ^a   Tungasmita, Duangamol Nuntasri ^a  

^a CHULALONGKORN UNIVERSITY   (Thailand)

Author keywords

Acid activation; Bentonite; Biodiesel; Catalyst; Esterification

Indexed keywords

ACID ACTIVATION; ACID CONTENT; ACID-BASE TITRATION; ESTERIFICATION OF OLEIC ACIDS; FREE FATTY ACID; METHYL OLEATE; NA BENTONITES; NITROGEN ADSORPTION;

BENTONITE; BIODIESEL; CATALYST ACTIVITY; CATALYSTS; ESTERIFICATION; ESTERS; GAS ADSORPTION; METHANOL; OLEIC ACID; PALM OIL; TITRATION;

NITRIC ACID;

ACID; ADSORPTION; CATALYST; METHANOL; NITROGEN; REACTION KINETICS; SCANNING ELECTRON MICROSCOPY; X-RAY DIFFRACTION; X-RAY FLUORESCENCE;

JATROPHA;

EID: 84891159072     PISSN: 01691317     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.clay.2013.11.025     Document Type: Article

References (29)

1. Breen C., Watson R. Acid-activated organoclays: preparation, characterisation and catalytic activity of polycation-treated bentonites. Appl. Clay Sci. 1998, 12:479-494.
2. Caetano C.S., Fonseca I.M., Ramos A.M., Vital J., Castanheiro J.E. Hydrolysis of sucrose using sulfonated poly(vinyl alcohol) as catalyst. Catal. Commun. 2008, 9:1996-1999.
3. Caetano C.S., Guerreiro L., Fonseca I.M., Ramos A.M., Vital J., Castanheiro J.E. Esterification of fatty acids to biodiesel over polymers with sulfonic acid groups. Appl. Catal. A Gen. 2009, 359:41-46.
4. Carmo A.C., Souza L.K.C., Costa C.E.F., Longo E., Zamian J.R., Rocha G.N. Production of biodiesel by esterification of palmitic acid over mesoporous aluminosilicate Al-MCM-41. Fuel 2009, 88:461-468.
5. Dorado M.P., Ballesteros E., Arnal J.M., Gomez J., Lopez F.J. Exhaust emissions from a diesel engine fuelled with transesterified waste olive oil. Fuel 2003, 82:1311-1315.
6. Grim R.E., Guven N. Bentonites, Geology, Mineralogy, Properties and Uses. Development in Sedimentology 1978, vol. 24. Elsevier, Amsterdam.
7. Hart M.P., Brown D.R. Surface acidities and catalytic activities of acid-activated clays. J. Mol. Catal. A Chem. 2004, 212:315-321.
8. Komadel P., Madejová J. Acid activation of clay minerals. Handbook of Clay Science 2006, 263-287. Elsevier, Oxford. F. Bergaya, B.K.G. Theng, G. Lagaly (Eds.).
9. Komadel P., Schmidt D., Madejova J., Cicel B. Alteration of smectites by treatments with hydrochloric acid and sodium carbonate solutions. Appl. Clay Sci. 1990, 5:113-122.
10. Koono, S., Moriya, O., Noguchi, T., Okamura, H., 1993. EP patent 566,047.
11. Labeckas G., Slavinskas S. The effect of rapeseed oil methyl ester on direct injection diesel engine performance and exhaust emissions. Energy Convers. Manage. 2006, 47:1954-1967.
12. Lagaly G., Bergaya F. Surface modification of clay minerals. Appl. Clay Sci. 2001, 19:1-3.
13. Ma F., Hanna M.A. Biodiesel production: a review. Bioresour. Technol. 1999, 70:1-15.
14. Mbaraka I.K., Radu D.R., Lin V.S., Shanks B.H. Organosulfonic acid-functionalized mesoporous silicas for the esterification of fatty acid. J. Catal. 2003, 219:329-336.
15. Melero J.A., Bautista L.F., Morales G., Iglesias J., Sanchez-Vazquez R. Biodiesel production from crude palm oil using sulfonic acid-modified mesostructured catalysts. J. Chem. Eng. 2010, 161:323-331.
16. Moraes D.S., Angelica R.S., Costa C.E.F., Filho G.N.R., Zamian J.R. Functionalized with propyl sulfonic acid groups used as catalyst in esterification reactions. Appl. Clay Sci. 2011, 51:209-213.
17. Murray H.H. Traditional and new applications for kaolin, smectite, and palygorskite: a general overview. Appl. Clay Sci. 2000, 17:207-221.
18. Nascimento L.A.S., Angelica R.S., Costa C.E.F., Zamian J.R., Filho G.N.R. Comparative study between catalysts for esterification prepared from kaolins. Appl. Clay Sci. 2011, 51:267-273.
19. Noyan H., Onal M., Sarikaya Y. The effect of sulphuric acid activation on the crystallinity, surface area, porosity, surface acidity, and bleaching power of a bentonite. Food Chem. 2007, 105:156-163.
20. Nuttapol L., Nourredine A., Luke A., Foster A. Mechanistic modeling of palmitic acid esterification via heterogeneous catalysis. Ind. Eng. Chem. Res. 2011, 50:1177-1186.
21. Onal M., Sarikaya Y., Alemdaroglu T. The effect of acid activation on some physicochemical properties of a bentonite. Turk. J. Chem. 2002, 26:409-416.
22. Pintoa A.C., Guarieiroa L.L.N., Rezendea M.J.C., Ribeiroa N.M., Torresb E.A., Lopesc W.A., Pereirac P.A.P., Andrade J.B. Biodiesel: an overview. J. Braz. Chem. Soc. 2005, 16:1313-1330.
23. Russbueldt B.M.E., Hoelderich W.F. New sulfonic acid ion-exchange resins for the preesterification of different oils and fats with high content of free fatty acids. Appl. Catal. A Gen. 2009, 362:47-57.
24. Salem A., Karimi L. Physico-chemical variation in bentonite by sulfuric acid activation. J. Chem. Eng. 2009, 26:980-984.
25. Stavarache C., Vinatoru M., Nishimura R., Maeda Y. Fatty acids methyl esters from vegetable oil by means of ultrasonic energy. Ultrason. Sonochem. 2005, 12:367-372.
26. Ulusoy Y., Tekin Y., Cetinkaya M., Karaosmanoglu F. The engine tests of biodiesel from used frying oil. Energy Sources 2004, 26:927-932.
27. Wypych F., Zatta L., Gardolinski J.E.F. Raw alloysite as reusable heterogeneous catalyst for esterification of lauric acid. Appl. Clay Sci. 2011, 51:165-169.
28. Xinfeng X., Yanfen D., Zhongzhong Q., Feng W., Bin W., Hu Z., Shimin Z., Mingshu Y. Degradation of poly(ethylene terephthalate)/clay nanocomposites during melt extrusion: effect of clay catalysis and chain extension. Polym. Degrad. Stab. 2009, 94:113-118.
29. Xu L., Yang X., Yu X., Guo Y. Preparation of mesoporous polyoxometalate-tantalum pentoxide composite catalyst for efficient esterification of fatty acid. Catal. Commun. 2008, 9:1607-1611.