Comparative study between catalysts for esterification prepared from kaolins

Applied Clay Science

Volumn 51, Issue 3, 2011, Pages 267-273

  Do Nascimento, Luís Adriano S ^a   Angélica, Rômulo S ^a   da Costa, Carlos E F ^a   Zamian, José R ^a   da Rocha Filho, Geraldo N ^a  

^a FEDERAL UNIVERSITY OF PARÁ   (Brazil)

Author keywords

Acid leaching; Esterification; Metakaolin; Microporous; Oleic acid

Indexed keywords

ACID LEACHING; ACIDIC SITES; ADSORPTION DESORPTION; AL CONTENT; CATALYTIC RESULTS; COMPARATIVE STUDIES; FREE FATTY ACID; FTIR ANALYSIS; HIGH CONCENTRATION; METAKAOLINS; MICRO-POROUS; PYRIDINE ADSORPTION; REACTION PARAMETERS; SOLID ACID CATALYSTS; SULFURIC ACID SOLUTION;

ADSORPTION; CATALYSTS; DESORPTION; ESTERIFICATION; ESTERS; FLOOD CONTROL; KAOLIN; LEACHING; METHANOL; MICROPOROSITY; OLEIC ACID; SCANNING ELECTRON MICROSCOPY; X RAY DIFFRACTION;

SULFURIC ACID;

BIOFUEL; CATALYST; COMPARATIVE STUDY; ESTER; FATTY ACID; KAOLIN; LEACHING; METHANOL; POROUS MEDIUM;

EID: 79251594683     PISSN: 01691317     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.clay.2010.11.030     Document Type: Article

References (39)

1. Araújo Melo D.M., Ruiz J.A.C., Melo M.A.F., Sobrinho E.V., Schmall M. Preparation and characterization of terbium palygorskite clay as acid catalyst. Microporous Mesoporous Mater. 2000, 38:345-349.
2. Belver C., Muñoz M.A.B., Vicente M.A. Chemical activation of a kaolinite under acid and alkaline conditions. Chem. Mater. 2002, 14:2033-2043.
3. 3as catalyst. Appl. Catal. B 2009, 89:590-596.
4. Carmo A.C., de Souza L.K.C., Costa C.E.F., Longo E., Zamian J.R., Rocha Filho G.N. Production of biodiesel by esterification of palmitic acid over mesoporous aluminosilicate Al-MCM-41. Fuel 2009, 88:461-468.
5. Carneiro B.S., Angélica R.S., Scheller T., de Castro E.A.S., Neves R.F. Mineralogical and geochemical characterization of the hard kaolin from the Capim region, Pará, northern Brazil. Cerâmica 2003, 49:237-244.
6. Centi G., Perathoner S. Catalysis by layered materials: a review. Microporous Mesoporous Mater. 2008, 107:3-15.
7. Flessner U., Jones D.J., Rozière J., Zajac J., Storaro L., Pavan M., Jiménez-López A., Rodríguez-Castellón E., Trombetta M., Busca G. A study of the surface acidity of acid-treated montmorillonite clay catalysts. J. Mol. Catal. A Chem. 2001, 168:247-256.
8. Ghesti G.F., de Macedo J.L., Parente V.C.I., Dias J.A., Dias S.C.L. Investigation of pyridine sorption in USY and Ce/USY zeolites by liquid phase microcalorimetry and thermogravimetry studies. Microporous Mesoporous Mater. 2007, 100:27-34.
9. Ghesti G.F., de Macedo J.L., Parente V.C.I., Dias J.A., Dias S.C.L. Synthesis, characterization and reactivity of Lewis acid/surfactant cerium trisdodecylsulfate catalyst for transesterification and esterification reactions. Appl. Catal. A 2009, 355:139-147.
10. Gokulakrishnan N., Pandurangan A., Sinha P.K. Esterification of acetic acid with propanol isomers under autogeneous pressure: a catalytic activity study of Al-MCM-41 molecular sieves. J. Mol. Catal. A Chem. 2007, 263:55-61.
11. Jacobson K., Gopinath R., Meher L.C., Dalai A.K. Solid acid catalyzed biodiesel production from waste cooking oil. Appl. Catal. B 2008, 85:86-91.
12. 3+-Montmorillonite. Catal. Lett. 2002, 78:185-188.
13. Kirumakki S.R., Nagaraju N., Chary K.V.R. Esterification of alcohols with acetic acid over zeolites Hβ, HY and HZSM5. Appl. Catal. A 2006, 299:185-192.
14. Kotschoubey B., Truckenbrodt W., Hieronymus B. Depósitos de caulim e argila semi-flint no nordeste do Estado do Pará. Rev. Bras. Geocienc. 1996, 26(2):71-80.
15. Lenarda M., Storaro L., Talon A., Moretti E., Riello P. Solid acid catalysts from clays: preparation of mesoporous catalysts by chemical activation of metakaolin under acid conditions. J. Colloid Interface Sci. 2007, 311:537-543.
16. Liu R., Wang X., Zhao X., Feng P. Sulfonated ordered mesoporous carbon for catalytic preparation of biodiesel. Carbon 2008, 46:1664-1669.
17. López D.E., Goodwin J.G., Bruce D.A., Furuta S. Esterification and transesterification using modified-zirconia catalysts. Appl. Catal. A 2008, 339:76-83.
18. Marchetti J.M., Errazu A.F. Esterification of free fatty acids using sulfuric acid as catalyst in the presence of triglycerides. Biomass Bioenergy 2008, 32:892-895.
19. 29Si MAS NMR study of kaolinite thermal decomposition by controlled rate thermal analysis. J. Am. Ceram. Soc. 1995, 78(11):2940-2944.
20. Mbaraka I.K., Shanks B.H. Acid strength variation due to spatial location of organosulfonic acid groups on mesoporous silica. J. Catal. 2006, 244:78-85.
21. Mbaraka I.K., Radu D.R., Lin V.S.-Y., Shanks B.H. Organosulfonic acid-functionalized mesoporous sílicas for the esterification of fatty acid. J. Catal. 2003, 219:329-336.
22. Mermut A.R., Faz Cano A. Baseline studies of the Clay Minerals Society source clays: chemical analyses of major elements. Clays Clay Miner. 2001, 49(5):381-386.
23. Mo X., Lotero E., Lu C., Liu Y., Goodwin J.G. A novel sulfonated carbon composite solid acid catalyst for biodiesel synthesis. Catal. Lett. 2008, 123:1-6.
24. Oliveira C.F., Dezaneti L.M., Garcia F.A.C., de Macedo J.L., Dias J.A., Dias S.C.L., Alvim K.S.P. Esterification of oleic acid with ethanol by 12-tungstophosphoric acid supported on zirconia. Appl. Catal. A 2010, 372:153-161.
25. Palani A., Pandurangan A. Esterification of acetic acid over mesoporous Al-MCM-41 molecular sieves. J. Mol. Catal. A Chem. 2005, 226:129-134.
26. Parrillo D.J., Adamo A.T., Kokotailo G.T., Gorte R.J. Amine adsorption in H-ZSM-5. Appl. Catal. 1990, 67:107-118.
27. Parry E.P. An infrared study of pyridine adsorbed on acidic solids. Characterization of surface acidity. J. Catal. 1963, 2:371-379.
28. Pentrák M., Madejová J., Komadel P. Acid and alkali treatment of kaolins. Clay Miner. 2009, 44:511-523.
29. Perissinotto M., Lenarda M., Storaro L., Ganzerla R. Solid acid catalysts from clays: acid leached metakaolin as isopropanol dehydration and 1-butene isomerization catalyst. J. Mol. Catal. A Chem. 1997, 121:103-109.
30. Pruett R.J., Webb H.L. Sampling and analysis of Kga-1B well-crystallized kaolin source clay. Clays Clay Miner. 1993, 41(4):514-519.
31. Rabindran Jermy B., Pandurangan A. Catalytic application of Al-MCM-41 in the esterification of acetic acid with various alcohols. Appl. Catal. A 2005, 288:25-33.
32. Rezende, M.J.C., 2006. Uso de Argila Brasileira como Catalisador na Produção de Biodiesel. Ph.D. Thesis, UFRJ, Rio de Janeiro, Brazil. Unpublished results.
33. Rives V. Characterisation by thermal techniques. Catal. Today 2000, 56:357-359.
34. Rouquerol J., Rouquerol F., Sing K. Adsorption by Powders and Porous Solids: Principles, Methodology and Applications 1999, Academic Press, London. first ed.
35. 4 treated metakaolinite of a natural kaolinite as Friedel-Crafts alkylation catalyst. Catal. Today 1999, 49:321-326.
36. Srilatha K., Lingaiah N., Prabhavathi Devi B.L.A., Prasad R.B.N., Venkateswar S., Sai Prasad P.S. Esterification of free fatty acids for biodiesel production over heteropoly tungstate supported on niobia catalysts. Appl. Catal. A 2009, 365:28-33.
37. Vaccari A. Clays and catalysis: a promising future. Appl. Clay Sci. 1999, 14:161-198.
38. 40/R] (R=Me or Ph) hybridcatalyst. Appl. Catal. B 2009, 90(3-4):587-594.
39. Zheng S., Kates M., Dubé M.A., McLean D.D. Acid-catalyzed production of biodiesel from waste frying oil. Biomass Bioenergy 2006, 30:267-272.