Reversible hydrogen evolution and oxidation on Pt electrode mediated by molecular ion

Applied Surface Science

Volumn 290, Issue , 2014, Pages 13-17

  Juodkazis, Kȩstutis ^a   Juodkazyte, Jurga ^a   Šebeka, Benjaminas ^a   Juodkazis, Saulius ^b,c  

^a CENTER FOR PHYSICAL SCIENCES AND TECHNOLOGY   (Lithuania)

^b SWINBURNE UNIVERSITY OF TECHNOLOGY   (Australia)

^c MELBOURNE CENTRE FOR NANOFABRICATION   (Australia)

Author keywords

Absorption; Adsorption; HER; HOR; Hydrogen; Hydrogen generation; Molecular ion; Thermodynamics; Transition metals

Indexed keywords

ABSORPTION; ADSORPTION; ATOMS; DIGITAL STORAGE; ELECTRODES; FREE RADICALS; HYDROGEN; HYDROGEN STORAGE; ION SOURCES; IONS; REACTION INTERMEDIATES; THERMODYNAMICS; TRANSITION METAL COMPOUNDS; TRANSITION METALS;

ADSORBED HYDROGEN; HYDROGEN EVOLUTION; HYDROGEN GENERATIONS; MOLECULAR HYDROGEN; MOLECULAR IONS; OXIDATION REACTIONS; SURFACE PROCESS; THERMODYNAMIC BALANCE;

HYDROGEN PRODUCTION;

EID: 84890979098     PISSN: 01694332     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.apsusc.2013.10.164     Document Type: Article

References (35)

1. E. Skulason, V. Tripkovic, M.E. Bjorketun, S. Gudmundsdottir, G. Karlberg, J. Rossmeisl, T. Bligaard, H. Jonsson, and J.K. Nørskov Modeling the electrochemical hydrogen oxidation and evolution reactions on the basis of density functional theory calculations J. Phys. Chem. C 114 2010 18182 18197
2. 2 O dications: H 2 + formation on ultrafast timescales J. Chem. Phys. 136 2 2012 024320
3. M. Pourbaix Atlas D'équilibres Électrochimiques 1963 Gauthier-Villars Paris
4. K.J. Vetter Elektrochemische Kinetik 1961 Springer-Verlag Berlin-Gottingen
5. H. Angerstein-Kozlowska Comprehensive Treaties of Electrochemistry, vol. 9 1984 Plenum Press New York
6. 2 , and the role of chemisorbed H Electrochim. Acta 47 2002 3571 3594
7. G. Jerkiewicz Hydrogen sorption at/in electrodes Prog. Surf. Sci. 57 1998 137 186
8. Q.-S. Chen, J. Solla-Gullóna, S.-G. Sun, and J.M. Feliu The potential of zero total charge of pt nanoparticles and polycrystalline electrodes with different surface structure: the role of anion adsorption in fundamental electrocatalysis Electrochim. Acta 55 2010 7982 7994
9. A. Lasia On the mechanism of the hydrogen absorption reaction J. Electroanal. Chem. 593 2006 159 166
10. B. Losiewicz, R. Jurczakowski, and A. Lasia Kinetics of hydrogen underpotential deposition at polycrystalline platinum in acidic solutions Electrochim. Acta 80 2012 292 301
11. L. Pauling General Chemistry 1988 Dover Publications, Inc. New York
12. S. Dutta, S. Ganguly, and B. Dutta-Roy A cartoon in one dimension of the hydrogen molecular ion Eur. J. Phys. 29 2008 235 249
13. K. Juodkazis, J. Juodkazyte, A. Griguceviciene, and S. Juodkazis Hydrogen species within the metals: role of molecular hydrogen ion H 2 + Appl. Surf. Sci. 258 2011 743 747
14. K. Hirota, and J. Horiuti The mechanism of the hydrogen electrode process-II. the electrochemical mechanism the existence of hydrogen molecule ions on the surface of the electrode Bull. Chem. Soc. Jpn 13 1 1939 228 233
15. F.G. Will, and C.A. Knorr Untersuchung von adsorptionserscheinungen an rhodium, iridium, palladium und gold mit der potentiostatischen dreieckmethode Z. Electrochem. 64 1960 270 275
16. T. Biegler, D.A.J. Rand, and R. Woods Limiting oxygen coverage on platinized platinum; relevance to determination of real platinum area by hydrogen adsorption J. Electroanal. Chem. 29 1971 269 277
17. J. Emsley The Elements 2nd ed. 1991 Clarendon Press Oxford
18. M.M. Markovic, and P.N. Ross Jr. Surface science studies of model fuel cell electrocatalysts Surf. Sci. Rep. 45 2002 117 229
19. F. Dion, and A. Lasia The use of regularization methods in the deconvolution of underlying distributions in electrochemical processes J. Electroanal. Chem. 475 1999 28 37
20. M. Nakamura, T. Kobayashi, and N. Hoshi Structural dependence of intermediate species for the hydrogen evolution reaction on single crystal electrodes of Pt Surf. Sci. 605 2011 1462 1465
21. Ş.C. Bǎdescu, K. Jacobi, Y. Wang, K. Bedürftig, G. Ertl, P. Salo, T. Ala-Nissila, and S.C. Ying Vibrational states of a H monolayer on the Pt(1 1 1) surface Phys. Rev. B 68 2003 205401
22. T. Koido, K. Tomarikawa, S. Yonemura, and T. Tokumasu Molecular dynamics study of the effects of translational energy and incident angle on dissociation probability of hydrogen/deuterium molecules on Pt(1 1 1) J. Appl. Phys. 110 2011 024301
23. G. Jerkiewicz, and A. Zolfaghari Comparison of hydrogen electroadsorption from the electrolyte with hydrogen adsorption from the gas phase J. Electrochem. Soc. 143 1996 1240 1248
24. K. Christman Interaction of hydrogen with solid surfaces Surf. Sci. Rep. 9 1988 1 163
25. K. Nobuhara, H. Nakanishi, H. Kasai, and A. Okiji Interactions of atomic hydrogen with Cu(1 1 1), Pt(1 1 1), and Pd(1 1 1) J. Appl. Phys. 88 11 2000 6897 6901
26. V.A. Rabinovich, and Z.Y. Khavin Kratkiy Khimicheskiy Spravochnik 1977 Khimiya Leningrad
27. 4 : Reexamination of its mechanism through combined cyclic-voltammetry, electrochemical quartz-crystal nanobalance, and auger electron spectroscopy measurements Electrochim. Acta 49 2004 1451 1459
28. P. Ferrin, S. Kandoi, A. Udaykumar Nilekar, and M. Mavrikakis Hydrogen adsorption, absorption and diffusion on and in transition metal surfaces: a DFT study Surf. Sci. 606 2012 679 689
29. J.R. Anderson Structure of Metallic Catalysts 1975 Academic London
30. S. Trasatti, and O.A. Petrii Izmereniya istinoy ploshchadi poverkhnosti v elektrokhimiyi Elektrokhimiya 29 1994 557 575
31. E. Gileadi Can an electrode reaction occur without electron transfer across the metal/solution interface? Chem. Phys. Lett. 393 2004 421 424
32. J.W. Schultze, and K.J. Vetter Experimental determination and interpretation of the electrosorption valency Electroanal. Chem. Interf. Electrochem. 44 1973 63 81
33. K. Kunimatsu, H. Uchida, M. Osawa, and M. Watanabe In situ infrared spectroscopic and electrochemical study of hydrogen electro-oxidation on pt electrode in sulfuric acid J. Electroanal. Chem. 587 2006 299 307
34. K. Kunimatsu, T. Senzaki, G. Samjeske, M. Tsushima, and M. Osawa Hydrogen adsorption and hydrogen evolution reaction on a polycrystalline pt electrode studied by surface-enhanced infrared absorption spectroscopy Electrochim. Acta 52 2007 5715 5724
35. K. Kunimatsu, T. Senzaki, M. Tsushima, and M. Osawa A combined surface-enhanced infrared and electrochemical kinetics study of hydrogen adsorption and evolution on a Pt electrode Chem. Phys. Lett. 401 2005 451 454