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Volumn 90, Issue 12, 2013, Pages 1703-1707

Which elements are metalloids?

Author keywords

First Year Undergraduate General; High School Introductory Chemistry; Inorganic Chemistry; Metalloids Semimetals; Misconceptions Discrepant Events; Periodicity Periodic Table; Physical Chemistry

Indexed keywords


EID: 84890544507     PISSN: 00219584     EISSN: 19381328     Source Type: Journal    
DOI: 10.1021/ed3008457     Document Type: Article
Times cited : (50)

References (84)
  • 1
    • 33845554345 scopus 로고
    • Metalloids
    • Goldsmith, R. H. Metalloids J. Chem. Educ. 1982, 59 (6) 526-527
    • (1982) J. Chem. Educ. , vol.59 , Issue.6 , pp. 526-527
    • Goldsmith, R.H.1
  • 2
    • 0035665596 scopus 로고    scopus 로고
    • Semimetallicity
    • Hawkes, S. J. Semimetallicity J. Chem. Educ. 2001, 78 (12) 1686-1687
    • (2001) J. Chem. Educ. , vol.78 , Issue.12 , pp. 1686-1687
    • Hawkes, S.J.1
  • 3
    • 77955884401 scopus 로고    scopus 로고
    • Polonium and astatine are not semimetals
    • Hawkes, S. J. Polonium and astatine are not semimetals J. Chem. Educ. 2010, 87 (8) 783
    • (2010) J. Chem. Educ. , vol.87 , Issue.8 , pp. 783
    • Hawkes, S.J.1
  • 4
    • 84890469584 scopus 로고    scopus 로고
    • Although Holt, Rinehart, and Wilson reached the same conclusion as Hawkes on the classification of polonium and astatine, their analysis is less thorough, in terms of breadth and depth, than that of the latter author. Accordingly, their work is not further considered here. Holt A. Rinehart B. Wilson C. Why polonium and astatine are not metalloids in HRW texts. c. 2007. (accessed Oct)
    • Although Holt, Rinehart, and Wilson reached the same conclusion as Hawkes on the classification of polonium and astatine, their analysis is less thorough, in terms of breadth and depth, than that of the latter author. Accordingly, their work is not further considered here. Holt A.; Rinehart B.; Wilson C. Why polonium and astatine are not metalloids in HRW texts. c. 2007. http://go.hrw.com/resources/go-sc/periodic/Po-At-Metalloids.pdf (accessed Oct 2013).
    • (2013)
  • 5
    • 84887891333 scopus 로고
    • For example, Brande and Cauvin (1845) classified the elements as gases (O, H, and N); halogens; metalloids (S, P, C, B, and Si?) - "resemble the metals in certain respects, but are in others wildly different" and metals, predating Mendeléeff's announcement of the discovery of periodic law in 1869. As another example, Tilden (1876) subsequently divided the elements into ("basigenic") true metals, metalloids ("imperfect metals"), and ("oxigenic") nonmetals. He counted H, As, Sb, Bi, and Te as metalloids, along with Ti(?), Zr, V, Nb(?), Ta(?), Mo, W, and U. Mendeléeff (1891) similarly regarded tellurium as forming "a transition from the metals to the non-metals" Harper & Brothers: New York
    • For example, Brande and Cauvin (1845) classified the elements as gases (O, H, and N); halogens; metalloids (S, P, C, B, and Si?)-"resemble the metals in certain respects, but are in others wildly different"; and metals, predating Mendeléeff's announcement of the discovery of periodic law in 1869. As another example, Tilden (1876) subsequently divided the elements into ("basigenic") true metals, metalloids ("imperfect metals"), and ("oxigenic") nonmetals. He counted H, As, Sb, Bi, and Te as metalloids, along with Ti(?), Zr, V, Nb(?), Ta(?), Mo, W, and U. Mendeléeff (1891) similarly regarded tellurium as forming "a transition from the metals to the non-metals". Brande, W. T.; Cauvin, J. A Dictionary of Science, Literature and Art; Harper & Brothers: New York, 1845; p 223
    • (1845) A Dictionary of Science, Literature and Art , pp. 223
    • Brande, W.T.1    Cauvin, J.2
  • 6
    • 84890454925 scopus 로고
    • 5 th ed. Kamensky, G. Greenaway, A. J. Longmans, Green & Co. London, Vol
    • Mendeléeff, D. I. The Principles of Chemistry, 5 th ed.; Kamensky, G.; Greenaway, A. J., Ed.; Longmans, Green & Co.: London, 1891; Vol. 2, p 264
    • (1891) The Principles of Chemistry , vol.2 , pp. 264
    • Mendeléeff, D.I.1
  • 8
    • 84890491590 scopus 로고    scopus 로고
    • Main page for the list of metalloid lists. (accessed Oct), as compiled, created and edited by the author
    • Main page for the list of metalloid lists. http://en.wikipedia.org/wiki/ List-of-metalloid-lists (accessed Oct 2013), as compiled, created and edited by the author.
    • (2013)
  • 13
    • 0034728628 scopus 로고    scopus 로고
    • Configuration energies of the main group elements
    • Mann et al. in fact refer to these elements as "the recognized metalloids" () (2783) - 2783
    • Mann et al. in fact refer to these elements as "the recognized metalloids": Mann, J. B.; Meek, T. L.; Allen, L. C. Configuration energies of the main group elements J. Am. Chem. Soc. 2000, 122 (12) 2780-2783 (2783)
    • (2000) J. Am. Chem. Soc. , vol.122 , Issue.12 , pp. 2780
    • Mann, J.B.1    Meek, T.L.2    Allen, L.C.3
  • 14
    • 0004257922 scopus 로고
    • 4 th ed. W. B. Saunders: Philadelphia, PA, p. Masterton and Slowinski also comment that polonium and astatine are ordinarily classified as metalloids, but add that "since very little is known about their chemical and physical properities, any such classification must be rather arbitrary"
    • Masterton, W. L.; Slowinski, E. J. Chemical Principles, 4 th ed.; W. B. Saunders: Philadelphia, PA, 1977; p 160. Masterton and Slowinski also comment that polonium and astatine are ordinarily classified as metalloids, but add that "since very little is known about their chemical and physical properities, any such classification must be rather arbitrary".
    • (1977) Chemical Principles , pp. 160
    • Masterton, W.L.1    Slowinski, E.J.2
  • 15
    • 84890461718 scopus 로고    scopus 로고
    • Main page for metalloids. (accessed Oct)
    • Main page for metalloids. http://en.wikipedia.org/wiki/Metalloid (accessed Oct 2013).
    • (2013)
  • 16
    • 2242471471 scopus 로고    scopus 로고
    • National Institute of Standards and Technology (NIST): Gaithersburg, MD, (accessed Oct 2013). Values shown in the table have been converted from the NIST values, which are given in eV
    • Martin, W. C.; Musgrove, A.; Kotochigova, S.; Sansonetti, J. E. Ground Levels and Ionization Energies for Neutral Atoms [online]; National Institute of Standards and Technology (NIST): Gaithersburg, MD, 2010. http://www.nist.gov/ pml/data/ion-energy.cfm (accessed Oct 2013). Values shown in the table have been converted from the NIST values, which are given in eV.
    • (2010) Ground Levels and Ionization Energies for Neutral Atoms [Online]
    • Martin, W.C.1    Musgrove, A.2    Kotochigova, S.3    Sansonetti, J.E.4
  • 19
    • 0009172017 scopus 로고    scopus 로고
    • 5 th ed. Nelson Thornes: Cheltenham
    • Hill, G.; Holman, J. Chemistry in Context, 5 th ed.; Nelson Thornes: Cheltenham, 2000; p 41.
    • (2000) Chemistry in Context , pp. 41
    • Hill, G.1    Holman, J.2
  • 20
    • 0035928162 scopus 로고    scopus 로고
    • A consistent approach toward atomic radii
    • (5942-5943) - 5944
    • Suresh, C. H.; Koga, N. A consistent approach toward atomic radii J. Phys. Chem. A 2001, 105 (24) 5940-5944 (5942-5943)
    • (2001) J. Phys. Chem. A , vol.105 , Issue.24 , pp. 5940
    • Suresh, C.H.1    Koga, N.2
  • 22
    • 84925047147 scopus 로고    scopus 로고
    • Explaining the role of classification in science, Jones (2010) however writes that 'Classes are usually defined by more than two attributes.'; Cambridge University: Cambridge, U.K
    • Explaining the role of classification in science, Jones (2010) however writes that 'Classes are usually defined by more than two attributes...' Jones, B. W. Pluto: Sentinel of the Outer Solar System; Cambridge University: Cambridge, U.K., 2010; p 169.
    • (2010) Pluto: Sentinel of the Outer Solar System , pp. 169
    • Jones, B.W.1
  • 23
    • 0346963761 scopus 로고    scopus 로고
    • A study of the mechanical and structural properties of polonium
    • (12) - 413
    • Kraig, R. E.; Roundy, D.; Cohen, M. L. A study of the mechanical and structural properties of polonium Solid State Commun. 2004, 129 (6) 411-413 (12)
    • (2004) Solid State Commun. , vol.129 , Issue.6 , pp. 411
    • Kraig, R.E.1    Roundy, D.2    Cohen, M.L.3
  • 25
    • 77955887508 scopus 로고    scopus 로고
    • Polonium and astatine are not semimetals
    • Hawkes, S. J. Polonium and astatine are not semimetals Chem 13 News 1999, 27 (Feb) p 14
    • (1999) Chem 13 News , vol.27 , Issue.FEB , pp. 14
    • Hawkes, S.J.1
  • 27
    • 34250455124 scopus 로고
    • Quantitative characteristics of bond metallicity in crystals
    • Batsanov, S. S. Quantitative characteristics of bond metallicity in crystals J. Struct. Chem. 1971, 12 (5) 809-813 (811)
    • (1971) J. Struct. Chem. , vol.12 , Issue.5 , pp. 809-813
    • Batsanov, S.S.1
  • 28
    • 84890537619 scopus 로고    scopus 로고
    • Main page for astatine. (accessed Oct)
    • Main page for astatine. http://en.wikipedia.org/wiki/Astatine (accessed Oct 2013).
    • (2013)
  • 29
    • 0013149802 scopus 로고
    • On the occurrence of metallic character in the periodic table of the elements
    • Edwards, P. P.; Sienko, M. J. On the occurrence of metallic character in the periodic table of the elements J. Chem. Educ. 1983, 60 (9) 691-696
    • (1983) J. Chem. Educ. , vol.60 , Issue.9 , pp. 691-696
    • Edwards, P.P.1    Sienko, M.J.2
  • 31
    • 84890512225 scopus 로고    scopus 로고
    • Personal communication, 29 Oct
    • Hawkes, S. J. Personal communication, 29 Oct 2010.
    • (2010)
    • Hawkes, S.J.1
  • 32
    • 84890528872 scopus 로고
    • Regularities in properties of thallium
    • 2 nd ed. State Technical Theoretical Press: Moscow, In Korenman, I. M. Russ. J. Gen. Chem. 1959, English translation, Consultants Bureau: New York, (), (1368). - 1390
    • Bresler, S. E. Radioactive Elements, 2 nd ed.; State Technical Theoretical Press: Moscow, 1952. In Korenman, I. M. Regularities in properties of thallium. Russ. J. Gen. Chem. 1959, English translation, Consultants Bureau: New York, 29 (2), 1366-1390 (1368).
    • (1952) Radioactive Elements , vol.29 , Issue.2 , pp. 1366
    • Bresler, S.E.1
  • 33
    • 84890524206 scopus 로고
    • Handling of astatine
    • In Kugler, H. K. Keller, C. 8 th ed. Springer-Verlag: Berlin, pp (143). - 156
    • Rössler, K. Handling of astatine. In Kugler, H. K.; Keller, C., Eds.; Gmelin Handbook of Inorganic Chemistry, At Astatine, 8 th ed.; Springer-Verlag: Berlin, 1985; pp 140-156 (143).
    • (1985) Gmelin Handbook of Inorganic Chemistry, at Astatine , pp. 140
    • Rössler, K.1
  • 34
    • 33644863358 scopus 로고    scopus 로고
    • Topological space of the chemical elements and its properties
    • (408, 411, 413). In a 2004 paper with the same lead author, and using a smaller set of properties, the authors comment that about 1.6 per cent of missing experimental values were interpolated; I presume the same general approach was taken in the 2006 paper (in the absence of any information therein on this point). - 416
    • Restrepo, G.; Llanos, E. J.; Mesa, H. Topological space of the chemical elements and its properties. J. Math. Chem. 2006, 39, (2)) 401-416 (408, 411, 413). In a 2004 paper with the same lead author, and using a smaller set of properties, the authors comment that about 1.6 per cent of missing experimental values were interpolated; I presume the same general approach was taken in the 2006 paper (in the absence of any information therein on this point).
    • (2006) J. Math. Chem. , vol.39 , Issue.2 , pp. 401
    • Restrepo, G.1    Llanos, E.J.2    Mesa, H.3
  • 38
    • 0003621450 scopus 로고
    • Dover Publications: New York
    • Pauling, L. General Chemistry; Dover Publications: New York, 1988; p 577.
    • (1988) General Chemistry , pp. 577
    • Pauling, L.1
  • 39
    • 0004282869 scopus 로고    scopus 로고
    • 9 th ed. enhanced; Brooks/Cole: Belmont, CA
    • Ebbing, D. D; Gammon, S. D. General Chemistry, 9 th ed. enhanced; Brooks/Cole: Belmont, CA, 2010; p 891.
    • (2010) General Chemistry , pp. 891
    • Ebbing, D.D.1    Gammon, S.D.2
  • 41
    • 33644839041 scopus 로고    scopus 로고
    • Aluminum is sometimes instead regarded as a pre-transition metal, a category which includes beryllium and magnesium, as well as the alkali metals and the rest of the alkaline earth metals. 2 nd ed. Bios Scientific: London - 186
    • Aluminum is sometimes instead regarded as a pre-transition metal, a category which includes beryllium and magnesium, as well as the alkali metals and the rest of the alkaline earth metals. Cox, P. A. Inorganic Chemistry, 2 nd ed.; Bios Scientific: London, 2004; pp 185-186.
    • (2004) Inorganic Chemistry , pp. 185
    • Cox, P.A.1
  • 42
    • 84890504117 scopus 로고
    • Compounds of tin: General trends
    • In Smith, P. J. Ed. 2 nd ed. Blackie Academic & Professional: London
    • Harrison, P. G. Compounds of tin: General trends. In Smith, P. J., Ed. Chemistry of Tin, 2 nd ed.; Blackie Academic & Professional: London, 1974; p 12.
    • (1974) Chemistry of Tin , pp. 12
    • Harrison, P.G.1
  • 46
    • 0022698886 scopus 로고
    • Semiconducting black phosphorus
    • Morita, A. Semiconducting black phosphorus J. Appl. Phys. 1986, 39 (4) 227-242 (230)
    • (1986) J. Appl. Phys. , vol.39 , Issue.4 , pp. 227-242
    • Morita, A.1
  • 47
    • 79251526172 scopus 로고    scopus 로고
    • Ab initio studies on atomic and electronic structures of black phosphorus
    • Du, Y.; Ouyang, C.; Shi, S.; Lei, M. Ab initio studies on atomic and electronic structures of black phosphorus J. Appl. Phys. 2010, 107 (9) 093718-1-093718-4
    • (2010) J. Appl. Phys. , vol.107 , Issue.9 , pp. 093718-0937210937184
    • Du, Y.1    Ouyang, C.2    Shi, S.3    Lei, M.4
  • 48
    • 0343634630 scopus 로고
    • D. C. Heath and Company: Boston, MA
    • Rochow, E. G. The Metalloids; D. C. Heath and Company: Boston, MA, 1966; p 7.
    • (1966) The Metalloids , pp. 7
    • Rochow, E.G.1
  • 49
    • 0004211783 scopus 로고    scopus 로고
    • Arsenic, antimony and bismuth: Some general properties and aspects of periodicity
    • In Norman, N. C. Blackie Academic & Professional: London, (7). - 38
    • Carmalt, C. J.;; Norman, N. C. Arsenic, antimony and bismuth: Some general properties and aspects of periodicity. In Norman, N. C., Ed.; Chemistry of Arsenic, Antimony, and Bismuth; Blackie Academic & Professional: London, 1998; 1-38 (7).
    • (1998) Chemistry of Arsenic, Antimony, and Bismuth , pp. 1
    • Carmalt, C.J.1    Norman, N.C.2
  • 50
    • 84890511527 scopus 로고
    • Half-way elements: The technology of metalloids (book review)
    • Adler, D. Half-way elements: The technology of metalloids (book review) Technol. Rev. 1969, 72 (1) 18-19
    • (1969) Technol. Rev. , vol.72 , Issue.1 , pp. 18-19
    • Adler, D.1
  • 55
    • 0343634630 scopus 로고
    • D. C. Heath and Company: Boston, MA
    • Rochow, E. G. The Metalloids; D. C. Heath and Company: Boston, MA, 1966; p 4.
    • (1966) The Metalloids , pp. 4
    • Rochow, E.G.1
  • 56
    • 0004010686 scopus 로고    scopus 로고
    • Academic Press: San Diego, CA
    • Wiberg, N. Inorganic Chemistry; Academic Press: San Diego, CA, 2001; p 160.
    • (2001) Inorganic Chemistry , pp. 160
    • Wiberg, N.1
  • 58
    • 84890488558 scopus 로고
    • Solid iodine has a silvery metallic appearance under white light at room temperature. In; held at Exeter, July 16-20, 1962; The Institute of Physics and the Physical Society: London
    • Solid iodine has a silvery metallic appearance under white light at room temperature. Koenig, S. H. In Proceedings of the International Conference on the Physics of Semiconductors; held at Exeter, July 16-20, 1962; The Institute of Physics and the Physical Society: London, 1962; p 108.
    • (1962) Proceedings of the International Conference on the Physics of Semiconductors , pp. 108
    • Koenig, S.H.1
  • 60
    • 84875426813 scopus 로고    scopus 로고
    • Bulk metallic glasses
    • (32). Schroers also refers to silicon as a near metalloid - 37
    • Schroers, J. Bulk metallic glasses Phys. Today 2013, 66 (2) 32-37 (32). Schroers also refers to silicon as a near metalloid
    • (2013) Phys. Today , vol.66 , Issue.2 , pp. 32
    • Schroers, J.1
  • 63
    • 84884263324 scopus 로고    scopus 로고
    • Condensed astatine: Monatomic and metallic
    • The authors used three-levels of successively nuanced relativistic modelling. The first level resulted in a molecular structure for astatine, with a band gap of 0.68 ev. The second and third levels resulted in a monatomic metal, with the only difference being a question of structure: (2) body-centred tetragonal; (3) face-centred cubic - 1160-5
    • Hermann, A.; Hoffmann, R.; Ashcroft, N. W. Condensed astatine: Monatomic and metallic. Phys. Rev. Lett. 2013, 111, 11604-1-1160-5. The authors used three-levels of successively nuanced relativistic modelling. The first level resulted in a molecular structure for astatine, with a band gap of 0.68 ev. The second and third levels resulted in a monatomic metal, with the only difference being a question of structure: (2) body-centred tetragonal; (3) face-centred cubic
    • (2013) Phys. Rev. Lett. , vol.111 , pp. 11604-11611
    • Hermann, A.1    Hoffmann, R.2    Ashcroft, N.W.3
  • 64
    • 0004010686 scopus 로고    scopus 로고
    • Academic Press: San Diego, CA
    • Wiberg, N. Inorganic Chemistry; Academic Press: San Diego, CA; 2001, pp. 1279, 1306.
    • (2001) Inorganic Chemistry , pp. 1279
    • Wiberg, N.1
  • 71
    • 0001952602 scopus 로고
    • Inorganic astatine chemistry. Part II: The chameleon behavior and electrophilicity of At-species
    • (99) - 103
    • Viser, G. W. M. Inorganic astatine chemistry. Part II: The chameleon behavior and electrophilicity of At-species Radiochim. Acta, 1989, 47, 97-103 (99)
    • (1989) Radiochim. Acta , vol.47 , pp. 97
    • Viser, G.W.M.1
  • 77
    • 0004010686 scopus 로고    scopus 로고
    • Academic Press: San Diego, CA
    • Wiberg, N. Inorganic Chemistry; Academic Press: San Diego, CA; 2001, p. 594.
    • (2001) Inorganic Chemistry , pp. 594
    • Wiberg, N.1
  • 79
    • 27744435245 scopus 로고    scopus 로고
    • Relativistic effects and the chemistry of the heaviest main-group elements
    • Thayer, J. S. Relativistic effects and the chemistry of the heaviest main-group elements. J. Chem. Educ. 2005, 82 (11) 1721-1726
    • (2005) J. Chem. Educ. , vol.82 , Issue.11 , pp. 1721-1726
    • Thayer, J.S.1
  • 80
    • 0001952602 scopus 로고
    • Inorganic astatine chemistry. Part II: The chameleon behavior and electrophilicity of At-species
    • (100) - 103
    • Viser, G. W. M. Inorganic astatine chemistry. Part II: The chameleon behavior and electrophilicity of At-species Radiochim. Acta, 1989, 47, 97-103 (100)
    • (1989) Radiochim. Acta , vol.47 , pp. 97
    • Viser, G.W.M.1
  • 82
    • 0030582806 scopus 로고    scopus 로고
    • Relativistic effects on the bonding of heavy and superheavy hydrogen halides
    • (362) - 366
    • Saue, T.; Faegri, K.; Gropen, O. Relativistic effects on the bonding of heavy and superheavy hydrogen halides. Chem. Phys. Lett. 1996, 263, 360-366 (362)
    • (1996) Chem. Phys. Lett. , vol.263 , pp. 360
    • Saue, T.1    Faegri, K.2    Gropen, O.3


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