Pd/C nanocatalyst with high turnover frequency for hydrogen generation from the formic acid-formate mixtures

International Journal of Hydrogen Energy

Volumn 39, Issue 2, 2014, Pages 837-843

  Wang, Xin ^a   Qi, Gong Wei ^a   Tan, Chun Hui ^a   Li, Ye Ping ^a   Guo, Jing ^a   Pang, Xin Jing ^a   Zhang, Shu Yong ^a  

^a SHANDONG UNIVERSITY   (China)

Author keywords

Formic acid formate mixture; Hydrogen generation; Pd C catalyst; Turnover frequency

Indexed keywords

EX SITU; FOURIER TRANSFORM INFRARED SPECTROMETER; HYDROGEN GENERATIONS; NANO-CATALYST; PD/C CATALYST; TURNOVER FREQUENCY;

CATALYST DEACTIVATION; CITRIC ACID; ENERGY DISPERSIVE SPECTROSCOPY; FORMIC ACID; FOURIER TRANSFORM INFRARED SPECTROSCOPY; HYDROGEN PRODUCTION; MIXTURES; PHOTOELECTRONS; TRANSMISSION ELECTRON MICROSCOPY; X RAY PHOTOELECTRON SPECTROSCOPY;

CATALYST ACTIVITY;

EID: 84890442747     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2013.10.154     Document Type: Article

References (27)

1. R. Coontz, and B. Hanson Not so simple Science 305 2004 957
2. L. Schlapbach, and A. Züttel Hydrogen-storage materials for mobile applications Nature 414 2001 353 358
3. B. Loges, A. Boddien, F. Gärtner, H. Junge, and M. Beller Catalytic generation of hydrogen from formic acid and its derivatives: useful hydrogen storage materials Top Catal 53 2010 902 914
4. 2 catalysts J Mater Sci 46 2011 7144 7151
5. G.A. Deluga Renewable hydrogen from ethanol by autothermal reforming Science 303 2004 993 997
6. 4 hydrolysis J Alloys Compd 543 2012 159 166
7. X. Zhou, Y. Huang, W. Xing, C. Liu, J. Liao, and T.H. Lu High-quality hydrogen from the catalyzed decomposition of formic acid by Pd-Au/C and Pd-Ag/C Chem Commun 2008 3540
8. A. Boddien, F. Gärtner, R. Jackstell, H. Junge, A. Spannenberg, and W. Baumann Ortho-metalation of iron(0) tribenzylphosphine complexes: homogeneous catalysts for the generation of hydrogen from formic acid Angew Chem Int Ed 49 2010 8993 8996
9. A. Boddien, B. Loge, H. Junge, F. Gärtner, J.R. Noyes, and M. Beller Continuous hydrogen generation from formic acid: highly active and stable ruthenium catalysts Adv Synth Catal 351 2009 2517 2520
10. A. Boddien, D. Mellmann, F. Gartner, R. Jackstell, H. Junge, and P.J. Dyson Efficient dehydrogenation of formic acid using an iron catalyst Science 333 2011 1733 1736
11. A. Boddien, B. Loges, H. Junge, and M. Beller Hydrogen generation at ambient conditions: application in fuel cells ChemSusChem 1 2008 751 758
12. G. Papp, J. Csorba, G. Laurenczy, and F. Joó A charge/discharge device for chemical hydrogen storage and generation Angew Chem Int Ed 50 2011 10433 10435
13. C. Fellay, P.J. Dyson, and G. Laurenczy A viable hydrogen-storage system based on selective formic acid decomposition with a ruthenium catalyst Angew Chem Int Ed 120 2008 4030 4032
14. M. Grasemann, and G. Laurenczy Formic acid as a hydrogen source - recent developments and future trends Energy Environ Sci 5 2012 8171 8181
15. A. Boddien, and H. Junge Acidic ideas for hydrogen storage Nature Nanotech 6 2011 265 266
16. Y. Zhao, L. Deng, S.Y. Tang, D.M. Lai, B. Liao, and Y. Fu Selective decomposition of formic acid over immobilized catalysts Energy Fuels 25 2011 3693
17. R. Williams, R.S. Crandall, and A. Bloom Use of carbon dioxide in energy storage Appl Phys Lett 33 1978 381 383
18. H. Wiener, and Y. Sasson Palladium-catalyzed decomposition of aqueous alkali metal formate solution J Mol Catal 35 1986 277 284
19. S.P. Hill, and J.M. Winterbottom The conversion of polysaccharides to hydrogen gas. Part I: the palladium catalysed decomposition of formic acid - sodium formate solutions Chem Technol Biotechnol 41 1987 121 133
20. Z.L. Wang, J.M. Yan, H.L. Wang, Y. Ping, and Q. Jiang Pd/C Synthesized with citric acid: an efficient catalyst for hydrogen generation from formic acid/sodium formate Sci Rep 2 2012 1 6
21. x-supported Pd catalyst at low temperatures J Catal 294 2012 29 36
22. X.W. Zhou, Y.L. Gan, Z.X. Dai, and R.H. Zhang Monodispersed Pd nanospheres and their electrocatalytic properties for methanol oxidation in alkaline medium J Electroanal Chem 685 2012 97 102
23. Y.Y. Gao, C.H. Tan, Y.P. Li, J. Guo, and S.Y. Zhang Formic acid-formate blended solution: a new fuel system with high oxidation activity Int J Hydrogen Energy 23 2012 3433 3437
24. J. Guo, Y.Y. Gao, C.H. Tan, Y.P. Li, and S.Y. Zhang Study on the oxidation enhancement of formic acid and formate blended fuel solution on Pt catalyst Fuel Cells 13 2013 167 173
25. L. Lu, H.Z. Li, Y. Hong, Y.F. Luo, Y.W. Tang, and T.H. Lu Improvement of electrocatalytic performance of carbon supported Pd anodic catalyst in direct formic acid fuel cell by ethylenediamine-tetramethylene phosphonic acid J Power Sources 210 2012 154 157
26. Y.F. Luo, H.Z. Li, T.T. Chen, C.W. Ge, Y.W. Tang, and Y. Chen Effect of Pd ions in electrolyte on electrocatalytic performance of carbon supported Pd catalyst for oxidation of formic acid Electrochim Acta 87 2013 839 843
27. H. Meng, S.H. Sun, J.P. Masse, and J.P. Dodelet Electrosynthesis of Pd single-crystal nanothorns and their application in the oxidation of formic acid Chem Mater 20 2008 6998 7002