Factors Affecting the Sorption-Desorption of Trace Elements in Soil Environments

Biophysico-Chemical Processes of Heavy Metals and Metalloids in Soil Environments

Volumn , Issue , 2007, Pages 169-213

  Violante, Antonio ^a   Krishnamurti, Gummuluru S R ^b   Pigna, Massimo ^a  

^a UNIVERSITY OF NAPLES FEDERICO II   (Italy)

^b NONE   (Canada)

Author keywords

And parabolic diffusion models; Inorganic and organic ligands; Power function; Trace elements and micronutrients

Indexed keywords

TRACE ELEMENTS;

DIFFUSION MODEL; ELEMENTS IN SOIL; ORGANIC LIGANDS; POWER FUNCTIONS;

SOIL POLLUTION;

EID: 84889399472     PISSN: None     EISSN: None     Source Type: Book    
DOI: 10.1002/9780470175484.ch5     Document Type: Chapter

References (146)

1. Agbenin, J. O., and Olojo, L. A. (2004). Competitive adsorption of copper and zinc by a Bt horizon of a savanna Alfisol as affected by pH and selective removal of hydrous oxides and organic matter. Geoderma 119, 85-95.
2. Ainsworth, C. C., Pilon, J. L., Gassman, P. L., and Van Der Sluys, W. G. (1994). Cobalt, cadmium, and lead adsorption to hydrous iron oxide: residence time effect. Soil Sci. Soc. Am. J. 58, 1615-1623.
3. Arai, Y., and Sparks, D. L. (2002). Residence time effects on arsenate surface speciation at the aluminum oxide-water interface. Soil Sci. 167, 303-314.
4. Auliitia, T. U., and Pickering, W. F. (1988). Sediment analysis: lability of selectively extracted fractions. Talanta 35, 559-566.
5. Balistrieri, L. S., and Chao, T. T. (1987). Selenium adsorption by goethite. Soil Sci. Soc. Am. J. 51, 1145-1151.
6. Barrow, N. J. (1992). The effect of time on the competition between anions for sorption. J. Soil Sci., 43, 424-428.
7. Benjamin, M. M., and Leckie, J. O. (1981). Multiple-site adsorption of Cd, Cu, Zn and Pb on amorphous iron oxyhydroxide. J. Colloid Surf. Sci. 79, 209-221.
8. Bermond, A., Yousfi, I., and Ghestem, J. P. (1998). Kinetic approach to the chemical speciation of trace metals in soils. Analyst (London) 123, 785-789.
9. Beveridge, T. J. (1989a). Metal ions and bacteria. In Metal Ions and Bacteria, ed. Beveridge, T. J., and Doyle, R. J., Wiley, New York, 1-29.
10. Beveridge, T. J. (1989b). Role of cellular design in bacterial metal accumulation and mineralization. Annu. Rev. Microbiol. 43, 147-171.
11. Bolan, N. S., and Duraisamy V. P. (2003). Role of inorganic and organic soil amendments on immobilisation and phytoavailability of heavy metals: a review involving specific case studies. Aust. J. Soil Res. 41, 533-555.
12. Bolan, N. S., Naidu, R., Syers, J. K., and Tillman, R. W. (1999). Surface charge and solute interactions in soils. Adv. Agron., 67, 87-140.
13. Bolan, N. S., Adriano, D. C., Natesan, R., and Koo, B.-J. (2003). Effects of organic amendments on the reduction and phytoavailability of chromate in mineral soil. J. Environ. Qual. 32, 120-128.
14. Bolland, M. D. A., Posner, A. M., and Quirk, J. P. (1977). Zinc adsorption by goethite in the absence and presence of phosphate. Aust. J. Soil. Res. 15, 279-286.
15. Boyd, S. A., and Mortland, M. M. (1990). Enzyme interactions with clays and clay-organic matter complexes. In Soil Biochemistry, Vol. 6, ed. Bollag, J.-M., and Stotzky, G., Marcel Dekker, New York, 1-28.
16. Bruemmer, G. W., Gerth, J., and Tiller, K. G. (1988). Reaction kinetics of adsorption and desorption of nickel, zinc and cadmium by goethite, I: Adsorption and diffusion of metals. J. Soil Sci. 39, 37-52.
17. Bryce, A. L., Kornicker, W. A., and Elzerman, A. W. (1994). Nickel adsorption to hydrous ferric oxide in the presence of EDTA: effects of component addition sequence. Environ. Sci. Technol. 28, 2353-2359.
18. 2+ by peat. J. Soil Sci. 27, 32-41.
19. Capasso, R., Pigna, M., De Martino, A., Pucci, M., Sannino, F., and Violante, A. (2004). Potential remediation of waters contaminated with Cr(III), Cu and Zn by sorption on the organic polymeric fraction of olive mill wastewater (polymerin) and its derivatives. Environ. Sci. Technol. 38, 5170-5176.
20. Chang, A. C., Page A. L., and Koo, B.-J. (2002). Biogeochemistry of phosphorus, iron, and trace elements as influenced by soil-plant-microbial interactions. In Soil Mineral-Organic Matter-Microorganism Interactions and Ecosystem Health: Ecological Significance of the Interactions Among Clay Minerals, Organic Matter and Soil Biota, ed. Violante, A., Huang, P. M., Bollag, J.-M., and Gianfreda, L., Developments in Soil Science, vol. 28B, Elsevier, New York, 43-57.
21. Chardichai, P., and Ritchie, G. S. P. (1992). The effect of pH on zinc adsorption by a lateritic soil in the presence of citrate and oxalate. J. Soil Sci. 43, 713-728.
22. Christensen, T. H. (1984). Cadmium soil sorption at low concentrations, III: Prediction and observation of mobility. Water Air Soil Pollut. 26, 255-264.
23. Cornell, R. M., and Schwertmann, U. (1996). The Iron Oxides: Structure, Properties, Reactions and Uses, VCH, New York.
24. Cowan, C. E., Zachara, J. M., and Resch, C. T. (1991). Cadmium adsorption on iron oxides in the presence of alkaline-earth elements. Environ. Sci. Technol. 25, 437-446.
25. Dixon, J. B., and Weed, S. B. (1989). Minerals in Soil Environments, Soil Science Society of America, Madison, WI, 1244.
26. Dynes, J. J., and Huang, P. M. (1997). Influence of organic acids on selenite sorption by poorly ordered aluminum hydroxides. Soil Sci. Soc. Am. J. 61, 772-783.
27. Elliott, H. A., Liberati, M. R., and Huang, C. P. (1986). Competitive adsorption of heavy metals by soils. J. Environ. Qual. 15, 214-219.
28. Fangueiro, D., Bermond, A., Santos, E., Carapuca, H., and Duarte, A. (2002). Heavy metal mobility assessment in sediments based on a kinetic approach of the EDTA extraction: search for optimal experimental conditions. Anal. Chim. Acta 459, 245-256.
29. Farrah, H., and Pickering, W. F. (1976a). The sorption of copper species by clays, I: Kaolinite. Aust. J. Chem. 29, 1167-1176.
30. Farrah, H., and Pickering, W. F. (1976b). The sorption of copper species by clays, II: Illite and montmorillonite. Aust. J. Chem. 29, 1177-1184.
31. Fendorf, S. E. (1995). Surface reactions of chromium in soils and waters. Geoderma 67, 55-71.
32. Fendorf, S. E., Lamble, G. M., Stapleton, M. G., Kelley, M. J., and Sparks, D. L. (1994). Mechanisms of chromium(III) sorption on silica, I: Cr(III) surface structure derived by extended x-ray absorption fine structure spectroscopy. Environ. Sci. Technol. 28, 284-289.
33. Fendorf, S. E., Eick, M. J., Grossl, P. R., and Sparks, D. L. (1997). Arsenate and chro-mate retention mechanisms on goethite, I: Surface structure. Environ. Sci. Technol. 31, 315-320.
34. Frankenberger, W. T., Jr. (2002). Environmental Chemistry of Arsenic, Marcel Dekker, New York.
35. Fuller, C. C., Davis, J. A., and Weychunas, G. A. (1993). Surface chemistry of ferrihydrite, II: Kinetics of arsenate adsorption and coprecipitation. Geochim. Cosmochim. Acta 57, 2271-2282.
36. Garman, S. M., Luxton, T. P., and Eick, M. J. (2004). Kinetics of chromate adsorption on goethite in the presence of sorbed silicic acid. J. Environ. Qual. 33, 1703-1708.
37. Gismera, M. J., Lacal, J., da Silva, P., Garcia, R., Sevilla, M. T., and Procopio, J. R. (2004). Study of metal fractionation in river sediments: a comparison between kinetic and sequential extraction procedures. Environ. Pollut. 127, 175-182.
38. Goldberg, S. (2002). Competitive adsorption of arsenate and arsenite on oxides and clay minerals. Soil Sci. Soc. Am. J. 66, 413-421.
39. Goldberg, S., and Glaubig, R. A. (1988a). Anion sorption on a calcareous montmorillonitic soil: selenium. Soil Sci. Soc. Am. J. 52, 954-958.
40. Goldberg, S., and Glaubig, R. A. (1988b). Anion sorption on a calcareous montmorillonitic soil: arsenic. Soil Sci. Soc. Am. J. 52, 1297-1300.
41. Goldberg, S., Davis, J. A., and Hem, J. D. (1996a). The surface chemistry of aluminum oxides and hydroxides. In The Environmental Chemistry of Aluminum, 2nd ed., ed. Sposito, G., Lewis Publishers, Boca Raton, FL, 271-331.
42. Goldberg, S., Forster, H. S., Lesch, S. M., and Heich, E. L. (1996b). Influence of anion competition on boron adsorption by clay minerals and soils. Soil Sci. 161, 99-103.
43. Grafe, M., Eick, M. J., and Grossl, P. R. (2001). Adsorption of arsenate(V) and arsenite(III) on goethite in the presence and absence of dissolved organic carbon. Soil Sci. Soc. Am. J. 65, 1680-1687.
44. Grafe, M., Eick, M. J., and Grossl, P. R. (2002). Adsorption of arsenate and arsenite on ferrihydrite in the presence and absence of dissolved organic carbon. J. Environ. Qual. 31, 1115-1123.
45. Grossl, P. R., Eick, M. J., Sparks, D. L., Goldberg, S., and Ainsworth, C. C. (1997). Arsenate and chromate retention on goethite, II: Kinetic evaluation using a pressure-jump relaxation technique. Environ. Sci. Technol. 31, 321-326.
46. Hanada, S., Nakano, M., Saitoh, H., and Mochizuki, T. (1975). Studies on the pollution of apple orchard surface soils and its improvement in relation to inorganic spray residues, I. Bull. Fac. Agric. Hirosaki Univ. 25, 13-17.
47. Hayes, K. F., Roe, A. L., Brown, G. E., Hodgson, K. O., Lee, J. O., and Parks, G. A. (1987). In situ x-ray absorption study of surface complexes: selenium oxyanions on a-FeOOH. Science (Washington, DC, ) 238, 783-786.
48. Hettiarichchi, G. M., Pierzynski, G. M., Zwonitzer, J., and Lambert, M. (1997). Phosphorus sources and rate effects on cadmium, lead and zinc bioavailability in a metal-contaminated soil. Proc. 4th International Conference on the Biogeochemistry of Trace Elements, Berkley, CA, June 23-26, 1997, 463-472.
49. Hingston, F. J. (1981). A review of anion adsorption. In Adsorption of Inorganics at Solid-Liquid Interfaces, ed. Anderson, M. A., and Rubin, A. J., Ann Arbor Science, Ann Arbor, MI, 51-84.
50. Hongshao, Z., and Stanforth, R. (2001). Competitive adsorption of phosphate and arsenate on goethite. Environ. Sci. Technol. 24, 4753-4757.
51. Hsia, T. H., Lo, S. L., Lin, C. F., and Lee, D. Y. (1994). Characterization of arsenate adsorption on hydrous iron oxide using chemical and physical methods. Colloids Surf. A Physicochem. Eng. Asp., 85, 1-7.
52. Huang, P. M. (2000). Abiotic catalysis. In Handbook of Soil Science, ed. Sumner, M. E., CRC Press, Boca Raton, FL, B303-B332.
53. Huang, P. M., and Germida, J. J. (2002). Chemical and biochemical processes in the rhi-zosphere: metal pollutants. In Interactions Between Soil Particles and Microorganisms: Impact on the Terrestrial Ecosystem, ed. Huang, P. M., Bollag, J.-M., and Senesi, N., Wiley, New York, 381-438.
54. Huang, P. M., and Schnitzer M. (eds). (1986). Interactions of Soil Minerals with Natural Organics and Microbes, Spec. Publ. 17, Soil Science Society of America, Madison, WI.
55. Jackson, T. A. (1998). The biogeochemical and ecological significance of interactions between colloidal minerals and trace elements. In Environmental Interactions of Clays, ed. Parker, A., and Rae, J. E., Springer-Verlag, Berlin, 93-205.
56. Jackson, T. A., and Leppard, G. G. (2002). Energy dispersive x-ray microanalysis and its applications in biological research. In Soil Mineral-Organic Matter-Microorganism Interactions and Ecosystem Health: Dynamics, Mobility and Transformations of Pollutants and Nutrients, Developments in Soil Science, Vol. 28, ed. Violante, A., Huang, P. M., Bollag, J.-M, and Gianfreda, L., Elsevier, New York, 219-260.
57. - release stoichiometry. Environ. Sci. Technol. 33, 1179-1184.
58. Kabata-Pendias, A. (2001). Trace Elements in Soils and Plants, 3rd ed., CRC Press, Boca Raton, FL.
59. Kampf, N., Scheinost, A. C., and Schultze, D. G. (2000). Oxide minerals. In Handbook of Soil Science, ed. Sumner, M. E., CRC Press, Boca Raton, FL, F125-F168.
60. Kinniburgh, D. G., and Jackson, M. L. (1976). Adsorption of alkaline earth, transition and heavy metal cations by hydrous oxides gels of iron and aluminum. Soil Sci. Soc. Am. J. 40, 796-799.
61. Kinniburgh, D. G., and Jackson, M. L. (1981). Cation adsorption by hydrous metal oxides and clays. In Adsorption of Inorganics at Solid-Liquid Interfaces, ed. Anderson, M. A., and Rubin, A. S., Ann Arbor Science, Ann Arbor, MI, 91-160.
62. Kinniburgh, D. G., Milne, C. J., Benedetti, M. F., Pinheiro, J. P., Filius, J., Koopal, L. K., and van Riemsdijk, W. H. (1996). Metal ion binding by humic acid: application of the NICA-Donnan model. Environ. Sci. Technol. 30, 1687-1698.
63. Kitagishi, K., and Yamane, I. (1981). Heavy Metal Pollution in Soils of Japan, Japan Science Society Press, Tokyo.
64. Kraemer, S. M., Xu, J., Raymond, K. N., and Sposito, G. (2002). Adsorption of Pb(II) and Eu(III) by oxide minerals in the presence of natural and synthetic hydroxamate siderophore. Environ. Sci. Technol. 36, 1287-1291.
65. Kretzschmar, R., and Voegelin, A. (2001). Modeling competitive sorption and release of heavy metals in soils. In Heavy Metals Release in Soils, ed. Selim, H. M., and Sparks, D. L., Lewis Publishers, Boca Raton, FL, 55-88.
66. Krishnamurti, G. S. R., and Naidu, R. (2002). Solid-solution speciation and phytoavail-ability of copper and zinc in soils. Environ. Sci. Technol. 36, 2645-2651.
67. Krishnamurti, G. S. R., Huang, P. M., Van Rees, K. C. J., Kozak, L. M., and Rostad, H. P. W. (1995). A new soil test method for the determination of plant-available cadmium in soils. Commun. Soil Sci. Plant Anal. 26, 2857-2867.
68. Krishnamurti, G. S. R., Cies'linski, G., Huang, P. M., and Van Rees, K. C. J. (1997). Kinetics of cadmium release from soils as influenced by organic acids: implication in cadmium availability. J. Environ. Qual. 26, 271-277.
69. Krishnamurti, G. S. R., Huang, P. M., and Kozak, L. M. (1999a). Desorption kinetics of cadmium from soils using M ammoinium nitrate and M ammonium chloride. Commun. Soil Sci. Plant Anal. 30, 2785-2800.
70. Krishnamurti, G. S. R., Huang, P. M., and Kozak, L. M. (1999b). Sorption and desorption kinetics of cadmium from soils: influence of phosphate. Soil Sci. 164, 888-898.
71. Krishnamurti, G. S. R., Megharaj, M., and Naidu, R. 2004. Bioavailability of cadmium-organic complexes to soil alga: an exception to the free ion model. J. Agric. Food Chem. 52, 3894-3899.
72. Kuo, S. (1986). Concurrent sorption of phosphate and zinc, cadmium, or calcium by hydrous ferric oxide. Soil Sci. Soc. Am. J. 50, 1040-1044.
73. Leckie, J. O., and James, R. O. (1974). Control mechanisms for trace metals in natural waters. In Aqueous-Environmental Chemistry of Metals, ed. Rubin, A. J., Ann Arbor Science, Ann Arbor, MI, 1-76.
74. Lehman, R. G., and Harter, R. D. (1984). Assessment of copper-soil bond strength by desorption kinetics. Soil Sci. Soc. Am. J. 48, 769-772.
75. Lopez-Hernandez, D., Siegert, G., and Rodriguez, J. V. (1986). Competitive adsorption of phosphate with malate and oxalate by tropical soils. Soil Sci. Soc. Am. J. 50, 1460-1462.
76. Lorenz, S. E., Hamon, R. E., Holm, P. E., Dominiques, H. C., Sequira, E. M., Christensen, T. H., and McGrath, S. P. (1997). Cadmium and zinc in plants and soil solutions from contaminated soils. Plant Soil 189, 21-31.
77. Lund, W. (1990). Speciation analysis: Why and how? Fresenius' J. Anal. Chem. 337, 557-564.
78. Manceau, A., and Charlet, L. (1994). The mechanism of selenate adsorption on goethite and hydrous ferric oxide. J. Colloid Interface Sci. 168, 87-93.
79. Mandel, R., Salam, M. S. A., Murimboh, J., Hassan, N. M., Chakrabarti, C. L., Back, M. H., and Gregorie, D. C. (2000). Competition of Ca(II) and Mg(II) with Ni(II) for binding by a well-characterized fulvic acid in model solutions. Environ. Sci. Technol. 34, 2201-2208.
80. Manning, B. A., and Goldberg, S. (1996a). Modeling competitive adsorption of arsenate with phosphate and molybdate on oxide minerals. Soil Sci. Soc. Am. J. 60, 121-131.
81. Manning, B. A., and Goldberg, S. (1996b). Modeling arsenate competitive adsorption on kaolinite, montmorillonite and illite. Clays Clay Miner. 44, 609-623.
82. Manning, B. A., Fendorf, S. E., and Goldberg, S. (1998). Surface structures and stability of arsenic(III) on goethite: spectroscopic evidence for inner-sphere complexes. Environ. Sci. Technol. 32, 2383-2388.
83. Marschner, H. (1998). Mineral Nutrition of Higher Plants, 2nd ed., Academic Press, London.
84. 2+-adsorption characteristics of aluminum hydroxide and oxy-hydroxides. Clays Clay Miner. 30, 21-28.
85. McBride, M. B. (1985). Sorption of copper(II) on aluminum hydroxide as affected by phosphate. Soil Sci. Soc. Am. J. 49, 843-846.
86. McBride, M. B. (1989). Reactions controlling heavy metal solubility in soils. Adv. Soil Sci. 10, 1-56.
87. McBride, M. B. (1991). Processes of heavy and transition metal sorption by soil minerals. In Interactions at the Soil Colloid-Soil Solution Interface, ed. Bolt, G. H., De Boodt, M. F., Haynes, M. H. B., and McBride, M. B., Vol. 190, Kluver Academic, Dordrecht, The Netherlands, 149-176.
88. McBride, M. B. (1994). Environmental Soil Chemistry, Oxford University, Press, New York.
89. McBride, M. B. (2000). Chemisorption and precipitation reactions. In Handbook of Soil Science, ed. Sumner, M. E., CRC Press, Boca Raton, FL, B265-B302.
90. McBride, M. B., Sauve, S., and Hendershot, W. (1997). Solubility control of Cu, Zn, Cd and Pb in contaminated soils. Eur. J. Soil Sci. 48, 337-346.
91. McKenzie, R. M. (1980). The adsorption of lead and other heavy metals on oxides of manganese and iron. Aust. J. Soil Res. 21, 505-513.
92. Mench, M., and Martin, E. (1991). Mobilization of cadmium and other metals from two soils by root exudates of Zea maize L., Nicotiana tabacum L. and Nicotiana rustica L. Plant Soil 132, 187-196.
93. Mesuere, K., and Fish, W. (1992). Chromate and oxalate adsorption on goethite, 2: Surface complexation modeling of competitive adsorption. Environ. Sci. Technol. 26, 2365-2370.
94. Murphy, E. M., and Zachara, J. M. (1995). The role of sorbed humic substances on the distribution of organic and inorganic contaminants in groundwater. Geoderma 67, 103-124.
95. Nagarajah, S., Posner, A. M., and Quirk, J. P. (1970). Competitive adsorption of phosphate with polygalacturonate and other organic anions on kaolinite and oxide surface. Nature (London) 228, 83-84.
96. Naidu, R., and Harter, R. D. (1998). Effect of different organic ligands on cadmium sorption by and extractability from soils. Soil Sci. Soc. Am. J. 62, 644-650.
97. Neal, R. H., and Sposito, G. (1986). Effects of soluble organic matter and sewage sludge amendments on cadmium adsorption by soils at low cadmium concentrations. Soil Sci. 142, 164-172.
98. Neubauer, U., Nowak, B., Furrer, G., and Schulin, R. (2000). Heavy metal sorption on clay minerals affected by the siderophore desferrioxamine B. Environ. Sci. Technol. 34, 2749-2755.
99. Neubauer, U., Furrer, G., and Schulin, R. (2002). Heavy metal sorption on soil minerals affected by the siderophore desferrioxamine B: the role of Fe(III) (hydr)oxides and dissolved Fe(III). Eur. J. Soil Sci. 53, 45-55.
100. O'Connor, G. A., O'Connor, C., and Cline, G. R. (1984). Sorption of cadmium by calcareous soils: influence of solution composition. Soil Sci. Soc. Am. J. 48, 1244-1247.
101. O'Reilly, S. E., Strawn, D. G., and Sparks, D. L. (2001). Residence time effects on arsenate adsorption/desorption mechanisms on goethite. Soil Sci. Soc. Am. J. 65, 67-77.
102. Ortiz-Viana, M. M., da Salva, M. P., Agraz, R., Procopio, J. R., Sevilla, M. T., and Hernandez, L. (1999). Comparison of two kinetic approaches for copper speciation using ion-exchange modified carbon paste electrodes. Anal. Chim. Acta 382, 179-188.
103. Oscarson, D. W., Huang P. M., Defose, C., and Herbillon, A. (1981). Oxidative power of Mn(IV) and Fe(III) oxides with respect to As(III) in terrestrial and aquatic environments. Nature (London) 291, 50-51.
104. Peryea, F. J. (1998). Phosphate starter fertilizer temporarily enhances soil arsenic uptake by apple trees grown under field conditions. Hort. Sci. 33, 826-829.
105. Pickering, W. F. (1979). Copper retention by sediment/soil components. In Copper in the Environment Vol. I, Ecological Cycling, ed. Nriagu, J. O., Wiley, New York, 217-253.
106. Pigna, M., Colombo, M., and Violante A. (2004). Competitive adsorption of arsenate and phosphate on synthetic hematites. Proc. Ital. Congr. Agric. Chem. (SICA), 21, 70-76.
107. Reichman, S. M., and Parker, D. R. (2005). Metal complexation by phytosiderophores in the rhizosphere. In Biogeochemistry of Trace Elements in the Rhizosphere, ed. Huang, P. M., and Gobran, G. R., Elsevier, Amsterdam The Netherlands, 129-156.
108. Robarge, W. P. (1998). Precipitation/dissolution reactions in soils. In Soil Physical Chemistry, 2nd ed., ed. Sparks, D. L., CRC Press, Boca Raton, FL, 192-238.
109. Roy, W. R., Hassett, J. J., and Griffin, R. A. (1986). Competitive coefficient for the adsorption of arsenate, molybdate, and phosphate mixtures by soils. Soil Sci Soc. Am. J. 50, 1176-1182.
110. Saha, U. K., Taniguchim, S., and Sakurai, K. (2002). Simultaneous adsorption of cadmium, zinc, and lead on hydroxyaluminum-and hydroxyaluminosilicate-montmorillonite complexes. Soil Sci. Soc. Am. J. 66, 117-128.
111. Sakurai, K., and Huang, P. M. (1995). Cadmium adsorption on the hydroxyalu-minium-montmorillonite complex as influenced by oxalate. In Environmental Impact of Soil Componenet Interactions, Vol. II, Metals, Other Inorganics and Microbial Activities, ed. Huang, P. M., Berthelin, J., Bollag, J.-M., McGill, W. B., and Page, A. L., Lewis Publishers, Boca Raton, FL, 39-46.
112. Sarkar, D., Essington, M. E., and Misra, K. C. (1999). Adsorption of mercury(II) by variable charge surfaces of quartz and gibbsite. Soil Sci Soc. Am. J. 63, 1626-1636.
113. Sauve, S., McBride, M. B., Norwell, W. A., and Hendershot, W. (1997). Copper solubility and speciation of in situ contaminated soils: effects of copper levels, pH and organic matter. Water Air Soil Pollut. 100, 133-149.
114. Scheidegger, A. M., Lamble, G. M., and Sparks, D. L. (1996). Investigation of Ni sorption on pyrophyllite: an XAFS study. Environ. Sci. Technol. 30, 548-554.
115. Scheidegger, A. M., Lamble, G. M., and Sparks, D. L. (1997). Spectroscopic evidence for the formation of mixed-cation hydroxide phases upon metal sorption on clays and aluminum oxides. J. Colloid Interface Sci. 62, 2233-2245.
116. Senesi, N. (1992). Metal-humic substance complexes in the environment: molecular and mechanistic aspects by multiple spectroscopic approach. In Biogeochemistry of Trace Elements, ed. Adriano, D. C., Lewis Publishers, Boca Raton, FL, 429-451.
117. Senesi, N., and Loffredo, E. (1998). The chemistry of soil organic matter. In Soil Physical Chemistry, 2nd ed., ed. Sparks, D. L., CRC Press, Boca Raton, FL, 239-370.
118. Singh, B. R., and Myhr, K. (1998). Cadmium uptake by barley as affected by Cd sources and pH levels. Geoderma 84, 185-194.
119. Smith, E., Naidu, R., and Alston, A. M. (1998). Arsenic in the soil environment: a review. Adv. Agron. 64, 149-195.
120. Sparks, D. L. (1990). Kinetics of Soil Chemical Processes, Academic Press, San Diego, CA.
121. Sparks, D. L. (1995). Kinetics of metal sorption reactions. In Metal Speciation and Contamination of Soil, ed. Allen, H. E., Huang, C. P., Bailey, G. W., and Bowers, A. R., Lewis Publishers, Boca Raton, FL, 36-58.
122. Sparks, D. L. (1999). Kinetics and mechanisms of chemical reactions at the soil mineral/water interface. In Soil Physical Chemistry, 2nd ed, ed. Sparks, D. L., CRC Press, Boca Raton, FL, 135-191.
123. Sparks, D. L. (2003). Environmental Soil Chemistry, 2nd ed. Academic Press, San Diego, CA.
124. Sparks, D. L., and Zhang, P. C. (1991). Relaxation methods for studying kinetics of soil chemical phenomena. In Rates of Soil Chemical Processes, ed. Sparks, D. L., and Suarez, D. L., Spec. Publ. 27, Soil Science Society of America, Madison, WI, 61-94.
125. Sposito, G. (1996). The Environmental Chemistry of Aluminum, CRC Press, Boca Raton, FL.
126. Sun, X., and Doner, H. E. (1996). An investigation of arsenate and arsenite bonding structures on goethite by FTIR. Soil Sci. 161, 865-872.
127. Swedlund, P. J., and Webster, J. G. (1999). Adsorption and polymerization of silicic acid on ferrihydrite, and its effect on arsenic adsorption. Water Res. 33, 3413-3422.
128. Thanabalasingan, P., and Pickering, W. F. (1986). Arsenic sorption by humic acids. Environ. Pollut. 12, 233-246.
129. Tichy, R., Nydl, V., Kuzel, S., and Kolar, L. (1997). Increased cadmium availability to crops on a sewage sludge amended soil. Water Air Soil Pollut. 94, 361-372.
130. Vacca, A., Adamo, P., Pigna, M., and Violante, P. (2002). Properties and classification of selected soils from the Roccamonfina volcano, central-southern Italy. Soil Sci. Soc. Am. J. 67, 198-207.
131. Violante, A., and Gianfreda, L. (2000). Role of biomolecules in the formation of variablecharge minerals and organo-mineral complexes and their reactivity with plant nutrients and organics in soil. In Soil Biochemistry, Vol. 10, ed. Bollag, J.-M., and Stotzky, G., Marcel Dekker, New York, 207-270.
132. Violante, A., and Pigna, M. (2002). Competitive sorption of arsenate and phosphate on different clay minerals and soils. Soil Sci. Soc. Am. J. 66, 1788-1796.
133. Violante, A., Huang, P. M., Bollag, J.-M., and Gianfreda, L. (2002a). Soil Mineral-Organic Matter-Microorganism Interactions and Ecosystem Health: Dynamics, Mobility and Transformations of Pollutants and Nutrients, Developments in Soil Science, Vol. 28A, Elsevier, New York.
134. Violante, A., Huang, P. M., Bollag, J.-M., and Gianfreda, L. (2002b). Soil Mineral-Organic Matter-Microorganism Interactions and Ecosystem Health: Ecological Significance of the Interactions Among Clay Minerals, Organic Matter and Soil Biota, Developments in Soil Science, Vol. 28B, Elsevier, New York.
135. Violante, A., Krishnamurti, G. S. R., and Huang, P. M. (2002c). Impact of organic substances on the formation of metal oxides in soil environments. In Interactions Between Soil Particles and Microorganism: Impact on the Terrestrial Ecosystem, ed. Huang, P. M, Bollag, J.-M. and Senesi, N., Wiley, New York, 133-188.
136. Violante, A., Ricciardella, M., and Pigna, M. (2003). Adsorption of heavy metals on mixed Fe-Al oxides in the absence or presence of organic ligands. Water Air Soil Pollut. 145, 289-306.
137. Violante, A., Ricciardella, M., Pigna, M., and Capasso, R. (2005a). Effects of organic ligands on the sorption of trace elements onto metal oxides and organo-mineral complexes. In Biogeochemistry of Trace Elements in the Rhizosphere, ed. Huang, P. M., and Gobran, G. R., Elsevier, Amsterdam, The Netherlands, 157-182.
138. Violante, A., Pigna, M., and Del Gaudio, S. (2005b). Adsorption-desorption processes of arsenate in soil environments. In Soil Abiotic and Biotic Interactions and the Impact on the Ecosystem and Human Welfare, ed. Huang, P. M., Bollag, J.-M., Violante, A., and Vityakon P., Science Publishers, Enfield, NH, 269-299.
139. Waltham, C. A., and Eick, M. J. (2002). Kinetics of arsenic adsorption on goethite in the presence of sorbed silicic acid. Soil Sci. Soc. Am. J. 66, 818-825.
140. Waychunas, G. A., Rea, B. A., Fuller, C. C., and Davis, J. A. (1993). Surface chemistry of ferrihydrite, I: EXAFS studies of the geometry of coprecipitates and adsorbed arsenate. Geochim. Cosmochim. Acta 57, 2251-2269.
141. 3 by the triple-layer model. J. Colloid Interface Sci. 233, 259-264.
142. Wu, Z., Gu, Z., Wang, X., Evans, L., and Guo, H. (2003). Effects of organic acids on adsorption of lead onto montmorillonite, goethite and humic acid. Environ. Pollut. 121, 469-475.
143. Yamaguchi, N. U., Scheinost, A. S., and Sparks, D. L. (2002). Influence of gibbsite surface area and citrate on Ni sorption mechanisms at pH 7.5. Clays Clay Miner. 50, 784-790.
144. Yee, N., and Fein, J. B. (2001). Cd adsorption onto bacterial surfaces: A universal adsorption edge? Geochim. Cosmochim. Acta, 65, 2037-2042.
145. Zachara, J. M., Ainsworth, C. C., Cowan, C. E., and Resch, C. T. (1989). Adsorption of chromate by subsurface soil horizons. Soil Sci. Soc. Am. J. 53, 418-428.
146. Zhou, D., De Cristofaro, A., He, J. Z., and Violante, A. (1999). Effect of oxalate on adsorption of copper on goethite, bayerite and kaolinite. In Clays for Our Future, ed. Kodama, H., Mermut, A. R., and Torrance, J. K., Proc. 11th Clay Conference, Ottawa, ON, Canada, 1998, 523-529.