Transport of Gases and Vapors in Glassy and Rubbery Polymers

Materials Science of Membranes for Gas and Vapor Separation

Volumn , Issue , 2006, Pages 1-47

  Matteucci, Scott ^a   Yampolskii, Yuri ^b   Freeman, Benny D ^a   Pinnau, Ingo ^c  

^a The University of Texas at Austin   (United States)

^b TOPCHIEV INSTITUTE OF PETROCHEMICAL SYNTHESIS   (Russian Federation)

^c Membrane Technology & Research Inc   (United States)

Author keywords

Fractional free volume (FFV); Gas and polymer effect on transport coefficient; Gas and vapor transport and 'solution diffusion' concept; Gas and vapor transport in glassy, rubbery polymers; Gas separation membranes; Gas transport properties and polymer connector groups; Permeability and diffusion coefficients and glass transition temperatures; Permeability selectivity trade off maps; Reverse selective vapor separations

Indexed keywords

EID: 84888635233     PISSN: None     EISSN: None     Source Type: Book    
DOI: 10.1002/047002903X.ch1     Document Type: Chapter

References (175)

1. D. R. Paul, 'The solution-diffusion model for swollen membranes', Separation and Purification Methods, 5 (1976), 33-50.
2. J. G. Wijmans and R. W. Baker, 'The solutiondiffusion model: a review', Journal of Membrane Science, 107 (1995), 1-21.
3. J. K. Mitchell, 'On the penetrativeness of fluids', Journal of Membrane Science, 100 (1995), 11-16.
4. T. Graham, 'On the absorption and dialytic separation of gases by colloid septa. Action of a septum of caoutchouc', Philosophical Magazine, 32 (1866), 401-420.
5. S. von Wroblewski, 'Ueber die natur der absorption der gase durch flussigkeiten unter hohen drucken', Ann Physik u Chem, 8 (1879), 29-52.
6. K. W. Boeddeker, 'Commentary Tracing Membrane Science', Journal of Membrane Science, Special Issue: The Early History of Membrane Science, 100 (1995), 1-68.
7. K. Ghosal and B. D. Freeman, 'Gas separation using polymer membranes: An overview', Polymers forAdvancedTechnology, 5 (1994), 673-697.
8. J. H. Petropoulos, 'Mechanisms and theories for sorption and diffusion of gases in polymers', in D. R. Paul and Y. P. Yampolskii (Eds), Polymeric Gas Separation Membranes, CRC Press, Boca Raton, FL, USA (1994), pp. 17-82.
9. R. M. Felder and G. S. Huvard, Permeation, Diffusion and Sorption of Gases and Vapors, Methods of Experimental Physics, Vol. 16C, Academic Press, New York, NY, USA (1980), pp. 315-377.
10. H. Lin and B. D. Freeman, Permeation and Diffusion, Springer-Handbook of Materials Measurement Methods, Vol. 16C, Springer-Verlag, Berlin, Germany (2005).
11. W. J. Koros and C. M. Zimmerman, 'Transport and Barrier Properties', in R. F. J. Brady (Ed.), Comprehensive Desk Reference of Polymer Characterization and Analysis, Oxford University Press,Washington, DC,USA(2003), pp. 680-699.
12. V. Bondar, B. D. Freeman and Y. P. Yampolskii, 'Sorption of gases and vapors in an amorphous glassy perfluorodioxide copolymer', Macromolecules, 32 (1999), 6163-6171.
13. V. I. Bondar, B. D. Freeman and I. Pinnau, 'Gas sorption and characterization of poly(ether-bamide) segmented block copolymers', Journal of Polymer Science, Part B: Polymer Physics, 37 (1999), 2463-2475.
14. S. N. Dhoot, B. D. Freeman and M. Stewart, 'Sorption and transport of linear esters and branched alkanes in biaxially oriented poly (ethylene terephthalate)', Industrial and Engineering Chemistry Research, 43 (2004), 2966-2976.
15. V. T. Stannett, W. J. Koros, D. R. Paul and H. K. Lonsdale, 'Recent advances in membrane science and technology', Advances in Polymer Science, 32 (1979), 69-121.
16. I. Pinnau and B. D. Freeman, Membrane Formation andModification Overview, in I. Pinnau and B. D. Freeman (Eds.) American Chemical Society Symposium Series 744, American Chemical Society,Washington, D.C, (2000), pp. 1-22.
17. W. J. Koros and I. Pinnau, 'Membrane formation for gas separation processes', in D. R. Paul and Y. P. Yampolskii (Eds), Polymeric Gas Separation Membranes, CRC Press, Boca Raton, FL, USA (1994), pp. 209-272.
18. L. M. Robeson, 'Correlation of separation factor versus permeability for polymeric membranes', Journal ofMembraneScience,62(1991),165-185.
19. D. T. Coker, B. D. Freeman and G. K. Fleming, 'Modeling multicomponent gas separation using hollow-fiber membrane contactors', AIChE Journal, 44 (1998), 1289-1302.
20. A. Y. Alentiev and Y. P. Yampolskii, 'Free volume model and tradeoff relations of gas permeability and selectivity in glassy polymers', Journal of Membrane Science, 165 (2000), 201-216.
21. B. D. Freeman, 'Basis of permeability/selectivity tradeoff relations in polymeric gas separation membranes', Macromolecules, 32 (1999), 375-380.
22. D.W. Breck, Zeolite Molecular Sieves: Structure, Chemistry and Use, JohnWiley & Sons, Inc. New York, NY, USA (1974), pp. 593-724.
23. S. A. Stern, 'Polymers for gas separations: The next decade', Journal of Membrane Science, 94 (1994), 1-65.
24. M. Cohen and T. Turnbull, 'Molecular transport in liquids and glasses', Journal of Chemical Physics, 31 (1959), 1164-1169.
25. R. W. Baker, 'Future directions of membrane gas separation technology', Industrial and Engineering Chemistry Research, 41 (2002), 1393-1411.
26. R. W. Baker, J. G. Wijmans and J. H. Kaschemekat, 'The design of membrane vapor-gas separation systems', Journal of Membrane Science, 151 (1998), 55-62.
27. X. Wang, R. Daniels and R.W. Baker, 'Recovery of VOCs from high-volume, low-VOC-concentration air systems', AIChE Journal, 47 (2001), 1094-1100.
28. B. D. Freeman and I. Pinnau, 'Separation of gases using solubility-selective polymers', Trends in Polymer Science, 5 (1997), 167-173.
29. D. V. Laciak, L. M. Robeson and C. D. Smith, 'Group contribution modeling of gas transport in polymeric membranes', in B. D. Freeman and I. Pinnau (Eds), Polymer Membranes for Gas and Vapor Separations, ACS Symposium Series 733, American Chemical Society, Washington, DC, USA (1999), pp. 151-177.
30. J. Y. Park and D. R. Paul, 'Correlation and prediction of gas permeability in glassy polymer membrane materials via modified free volume based group contribution method', Journal of Membrane Science, 125 (1997), 23-39.
31. D. W. van Krevelen, Properties of Polymers, 3rd Edn., Elsevier, Amsterdam, The Netherlands (1990).
32. H. Lin and B. D. Freeman, 'Gas solubility, diffusivity and permeability in poly(ethylene oxide)', Journal of Membrane Science, 239 (2004), 105-117.
33. A. S. Michaels and H. J. Bixler, 'Flow of gases through polyethylene', Journal of Polymer Science, 50 (1961), 412-439.
34. T. C. Merkel, V. Bondar, K. Nagai, B. D. Freeman and I. Pinnau, 'Gas sorption, diffusion, and permeation in poly(dimethylsiloxane)', Journal of Polymer Science, Part B: Polymer Physics, 38 (2000), 415-434.
35. A. S. Michaels, W. R. Vieth and J. A. Barrie, 'Diffusion of gases in polyethylene terephthalate', Journal of Applied Physics, 34 (1963), 13-21.
36. G. J. van Amerongen, 'Diffusion in Elastomers', Rubber Chemistry and Technology, 37 (1964), 1065-1153.
37. V. V. Teplyakov and S. G. Durgaryan, 'Correlation analysis of permeation parameters for polymers', Vysokomolekuliarnye Soedineniia (Polymer Science, Series A), 26 (1984), 1498-1505.
38. V. V. Teplyakov and P. Meares, 'Correlation aspects of the selective gas permeabilities of polymeric materials and membranes', Gas Separation and Purification, 4 (1990), 66-73.
39. V. P. Shantarovich, I. B. Kevdina, Y. P. Yampolskii and A. Y. Alentiev, 'Positron annihilation lifetimes of high and low free volume glassy polymers: effects of free volume sizes on the permeability and permselectivity', Macromolecules, 33 (2000), 7453-7466.
40. P. Meares, 'The diffusion of gases through polyvinyl acetate', Journal of the American Chemical Society, 76 (1954), 3415-3422.
41. G. S. Park, Transport Principles-Solution, Diffusion and Permeation in Polymer Membranes, NATO ASI Series, Series C, 181 Kluwer Academic Publishers, Dordrecht, The Netherlands (1986), pp. 57-107.
42. P. E. J. Rouse, 'Diffusion of vapors in films', Journal of the American Chemical Society, 69 (1947), 1068-1073.
43. J. D. Wellons and V. T. Stannett, 'Permeation, sorption, and diffusion of water in ethyl cellulose', Journal of Polymer Science, 4 (1966), 593-602.
44. K. A. Schult and D. R. Paul, 'Water sorption and transport in a series of polysulfones', Journal of Polymer Science, Part B: Polymer Physics, 34 (1996), 2805-2817.
45. K. Ghosal, R. T. Chern and B. D. Freeman, 'Effect of basic substituents on gas sorption and permeation in polysulfone', Macromolecules, 29 (1996), 4360-4369.
46. E. L. Spotz, The equation of state of gases at low and moderate densities, in J. O. Hirschfelder, C. F. Curtiss and R. B. Bird (Eds), Molecular Theory of Gases and Liquids, Structure of Matter Series, JohnWiley & Sons, Inc., New York, USA (1954), pp. 131-230.
47. T. Titani, 'Viscosity of vapors of organic compounds. II', Bulletin of the Chemical Society of Japan, 5 (1930), 98-108.
48. B. E. Poling, J. M. Prausnitz and J. P. O'Connell, The Properties of Gases and Liquids, 5th Edn, McGraw-Hill, New York, NY, USA (2000).
49. T. H. Chung, M. Ajlan, L. L. Lee and K. E. Starling, 'Generalized multiparameter correlation for nonpolar and polar fluid transport properties', Industrial and Engineering Chemistry Research, 27 (1988), 671-679.
50. T. H. Chung, L. L. Lee and K. E. Starling, 'Application of kinetic gas theories and multiparameter correlation for prediction of dilute gas viscosity and thermal conductivity', Industrial and Engineering Chemistry Research, 23 (1984), 8-13.
51. E. L.Spotz, 'Transportphenomena of dilutegases', in J. O. Hirschfelder, C. F. Curtiss and R. B. Bird (Eds), Molecular Theory of Gases and Liquids, Structure of Matter Series, John Wiley & Sons, Inc., New York, NY, USA (1954), pp. 131-230.
52. J. S. Rowlinson, 'The second virial coefficients of polar gases', Transactions of the Faraday Society, 45 (1949), 974-984.
53. L. S. Tee, S. Gotoh andW. E. Stewart, 'Molecular parameters for normal fluids. The Lennard-Jones 12-6 potential', Industrial and Engineering Chemistry Research, 5 (1966), 346-363.
54. W. M. Lee, 'Selection of barrier materials from molecular structure', Polymer Engineering and Science, 20 (1980), 65-69.
55. A. Reynier, P. Dole, S. Humbel and A. Feigenbaum, 'Diffusion coefficients of additives in polymers. I. Correlation with geometric parameters', Journal of Applied Polymer Science, 82 (2001), 2422-2433.
56. H. Fujita, A. Kishimoto and K. Matsumo, 'Concentration and temperature dependence of diffusion coefficients', Transactions of the Faraday Society, 56 (1960), 424-437.
57. Y. P. Yampolskii, S. G. Durgaryan and N. S. Nametkin, 'Permeability, diffusivity, and solubility of n-alkenes in polymers', Vysokomolekuliarnye Soedineniia (Polymer Science, Series B), 21 (1979), 616-621.
58. S. N. Dhoot, B. D. Freeman, M. Stewart and A. J. Hill, 'Sorption and transport of linear alkane hydrocarbons in biaxially oriented poly(ethylene terephthalate)', Journal of Polymer Science, Part B: Polymer Physics, 39 (2001), 1160-1172.
59. K. Tanaka, A. Taguchi, J. Hao, H. Kita and K. Okamoto, 'Permeation and separation properties of polyimide membranes to olefins and paraffins', Journal of Membrane Science, 121 (1996), 197-207.
60. B. D. Freeman and I. Pinnau, 'Polymeric materials for gas separations', in B. D. Freeman and I. Pinnau (Eds), Polymer Membranes for Gas and Vapor Separations, ACS Symposium Series 733, American Chemical Society, Washington, DC, USA (1999), pp. 1-27.
61. R. M. Barrer and G. Skirrow, 'Transport and equilibrium phenomena in gas elastomer systems. Part II. Equilibrium phenomena', Journal of Polymer Science, 3 (1948), 564-575.
62. T. C. Merkel, V. Bondar, K. Nagai and B. D. Freeman, 'Sorption and transport of hydrocarbon and perfluorocarbon gases in poly(1-trimethylsilyl-1-propyne)', Journal of Polymer Science, Part B: Polymer Physics, 38 (1999), 273-296.
63. G. Gee, 'Some thermodynamic properties of high polymers and their molecular interpretation, Quarterly Reviews of the Chemical Society, 1 (1947), 265-298.
64. Y. P. Yampolskii and V. V. Volkov, 'Studies in gas permeability and membrane gas separation in the Soviet Union', Journal of Membrane Science, 64 (1991), 191-228.
65. W. J. Koros, D. R. Paul and G. S. Huvard, 'Energetics of gas sorption in glassy polymers', Polymer, 20 (1979), 956-960.
66. F. Korosy, 'Two rules concerning solubility of gases and crude data on solubility of krypton', Transactions of the Faraday Society, 33 (1937), 416-425.
67. R. Prabhakar, M. G. De Angelis, G. C. Sarti, B. D. Freeman and M. C. Coughlin, 'Gas and vapor sorption, permeation and diffusion in poly(tetrafluoroethylene-co-perfluoromethyl vinyl ether)' Macromolecules, 38 (2005), 1899-1910.
68. Y. Kamiya, Y. Naito, K. Terada and K. Mizoguchi, 'Volumetric properties and interaction parameters of dissolved gases in poly(dimethylsiloxane) and polyethylene', Macromolecules, 33 (2000), 3111-3119.
69. K. Toi, G. Morel and D. R. Paul, 'Gas sorption and transport in poly(phenylene oxide) and comparisons with other glassy polymers', Journal of Applied Polymer Science, 27 (1982), 2997-3005.
70. A. S. Michaels and H. J. Bixler, 'Solubility of gases in polyethylene', Journal of Polymer Science, 50 (1961), 393-412.
71. G. E. Serad, B. D. Freeman, M. E. Stewart and A. J. Hill, 'Gas and vapor sorption and diffusion in poly(ethylene terephthalate)', Polymer, 42 (2001), 6929-6943.
72. K. Ghosal, R. T. Chern, B. D. Freeman and R. Savariar, 'The effect of aryl nitration on gas sorption and permeation in polysulfone', Journal of Polymer Science, Part B: Polymer Physics, 33 (1995), 657-666.
73. D. R. Stull, E. F. Westrum and G. C. Sinke, The Chemical Thermodynamics of Organic Compounds, John Wiley & Sons, Inc., New York, NY, USA (1969).
74. S. A. Stern, J. T. Mullhaupt and P. J. Garries, 'The effect of pressure on the permeation of gases and vapors through polyethylene. Usefulness of the corresponding states principle', AIChE Journal, Special Issue: The Early History of Membrane Science, 15 (1969), 64-73.
75. Y. P. Yampolskii, D. Wiley and C. Maher, 'Novel correlation for solubility of gases in polymers: effect of molecular surface area of gases', Journal of Applied Polymer Science, 76 (2000), 552-560.
76. M. R. Pixton and D. R. Paul, 'Relationships between structure and transport properties for polymers with aromatic backbones', in D. R. Paul and Y. P. Yampolskii (Eds), Polymeric Gas Separation Membranes, CRC Press, Boca Raton, FL, USA (1994), pp. 83-154.
77. T. C. Merkel, B. D. Freeman, R. J. Spontak, Z. He, I. Pinnau, P. Meakin and A. J. Hill, Ultrapermeable, reverse-selective nanocomposite membranes', Science, 296 (2002), 519-522.
78. I. Pinnau, C. G. Casillas, A. Morisato and B. D. Freeman, 'Hydrocarbon/hydrogen mixed gas permeation in poly(1-trimethylsilyl-1-propyne) (PTMSP), poly(1-phenyl-1-propyne) (PPP) and PTMSP/PPP blends', Journal of Polymer Science, Part B: Polymer Physics, 34 (1996), 2613-2621.
79. Y. P. Yampolskii, S. G. Durgaryan and N. S. Nametkin, 'Translational and rotational mobility of low molecular mass compounds in polymers with different glass transition temperatures', Vysokomolekuliarnye Soedineniia, 24 (1982), 536-541.
80. M. W. Fitch, W. J. Koros, R. L. Nolen and J. R. Carnes, 'Permeation of several gases through elastomers, with emphasis on the D2/H2 pair', Journal of Applied Polymer Science, 47 (1993), 1033-1046.
81. Y. Kawakami, H. Karasawa, T. Aoki, Y. Yamamaura, H. Hisada and Y. Yamashita, 'Polymers with oligoorganosilicone side chains as materials for oxygen permeable membranes', Polymer Journal, 17 (1985), 1159-1172.
82. Y. Kawakami, H. Toda, M. Higashino and Y. Yamashita, 'Polynorbornenes with oligodimethylsiloxanyl substituents for selectively oxygen permeable membrane material', Polymer Journal, 20 (1988), 285-292.
83. Y. Hirayama, T. Yoshinaga, Y. Kusuki, K. Ninomiya, T. Sakakibara and T. Tamari, 'Relation of gas permeability with structure of aromatic polyimides I', Journal of Membrane Science, 111 (1996), 169-182.
84. K. Nagai, T. Masuda, T. Nakagawa, B. D. Freeman and I. Pinnau, 'Poly [1-(trimethylsilyl)-1-propyne] and related polymers: synthesis, properties and functions', Progress in Polymer Science, 26 (2001), 721-798.
85. R. T. Chern, W. J. Koros, E. S. Sanders and R. Yui, 'Second Component effects in sorption and permeation of gases in glassy polymers', Journal of Membrane Science, 15 (1983), 157-169.
86. A. R. Berens and H. B. Hopfenberg, 'Diffusion of organic vapors at low concentrations in glassy PVC, polystyrene and PMMA', Journal of Membrane Science, 10 (1982), 283-303.
87. R. T. Chern,W. J. Koros, H. B. Hopfenberg and V. T. Stannett, 'Material selection for membranebased gas separations', in D. R. Lloyd (Ed.), Material Science of Synthetic Membranes, ACS Symposium Series 269, American Chemical Society,Washington, DC, USA (1985), pp. 25-46.
88. T. C. Merkel, V. Bondar, K. Nagai, B. D. Freeman and Y. P. Yampolskii, 'Gas sorption, diffusion and permeation in poly(2,2-bis(trifluoromethyl)-4,5-difluoro-1,3-dioxole-co-tetrafluoroethylene)', Macromolecules, 32 (1999), 8427-8440.
89. K. Toi and D. R. Paul, 'Effect of polystyrene molecular weight on the carbon dioxide sorption isotherm',Macromolecules,15(1982),1104-1107.
90. H. Lin, B. D. Freeman, L. G. Toy, V. Bondar, R. P. Gupta, S. J. Pas and A. J. Hill, 'Reverse-selective polymeric membranes for hydrogen purification', Polymer Preprints (American Chemical Society Division of Polymer Chemistry), 45 (1) (2004), 23-24.
91. L. A. Pilato, L. M. Litz, B. Haritay, A. G. Farnham, J. H. Kawakami, P. E. Fritze and J. E. McGrath, 'Polymers for permselective membrane gas separations', Polymer Preprints (American Chemical Society Division of Polymer Chemistry), 161 (1) (1975), 41-46.
92. S. G. Charati, A. Y. Houde and S. S. Kulkarni, 'Transport of gases in aromatic polyesters: correlation withWAXD studies', Journal of Polymer Science, Part B: Polymer Physics, 29 (1991), 921-931.
93. A. Bondi, Physical Properties of Molecular Crystals, Liquids and Gases, JohnWiley & Sons, Inc., New York, NY, USA (1968).
94. J. S. Vrentas and C. M. Vrentas, 'Predictive methods for self-diffusion and mutual diffusion coefficients in polymer-solvent systems', European Polymer Journal, 34 (1998), 797-803.
95. J. L. Duda, Y. C. Ni and J. S. Vrentas, 'An equation relating self-diffusion and mutual diffusion coefficients in polymer-solvent systems', Macromolecules, 12 (1979), 459-462.
96. A. Puleo, N. Muruganandam and D. R. Paul, 'Gas sorption and transport in substituted polystyrenes', Journal of Polymer Science, Part B: Polymer Physics, 27 (1989), 2385-2406.
97. D. H. Weinkauf and D. R. Paul, 'Gas transport properties of thermotropic liquid-crystalline copolyestyers. II. The effects of copolymer composition', Journal of Polymer Science, Part B: Polymer Physics, 30 (1992), 837-849.
98. R. R. Light and R.W. Seymour, 'Effect of sub-Tg relaxations on the gas transport properties of polyesters', Polymer Engineering and Science, 22 (1982), 857-864.
99. D. H. Weinkauf and D. R. Paul, 'Gas transport properties of thermotropic liquid-crystalline copolyesters. I. The effects of orientation and annealing', Journal of Polymer Science, Part B: Polymer Physics, 30 (1992), 813-835.
100. D. H. Weinkauf and D. R. Paul, 'Gas transport properties of liquid crystalline poly(ethylene terephthalate-co-p-oxybenzoate)', Journal of Polymer Science, Part B: Polymer Physics, 29 (1991), 329-340.
101. H. Lin and B. D. Freeman, 'Gas permeation and diffusion in crosslinked poly(ethylene glycol diacrylate)', Macromolecules, 38 (2005), 8394-8407.
102. J. S. McHattie, W. J. Koros and D. R. Paul, 'Gas transport properties in polysulfones. 3. Comparison of tetramethyl-substituted bisphenols', Polymer, 33 (1992), 1701-1711.
103. A. Thran, G. Kroll and F. Faupel, 'Correlation between fractional free volume and diffusivity of gas molecules in glassy polymers', Journal of Polymer Science, Part B: Polymer Physics, 37 (1999), 3344-3358.
104. C. Nagel, K. Guenther-Schade, D. Frisch, T. Strunskus and F. Faupel, 'Free volume and transport properties in highly selective polymer membranes', Macromolecules, 35 (2002), 2071-2077.
105. A. Y. Alentiev and Y. P. Yampolskii, 'Meares equation and the role of cohesion energy density in diffusion in polymers', Journal of Membrane Science, 206 (2002), 291-306.
106. A. Singh, B. D. Freeman and I. Pinnau, 'Pure and mixed gas acetone/nitrogen permeation properties of polydimethylsiloxane', Journal of Polymer Science, Part B: Polymer Physics, 32 (1998), 289-301.
107. P. J. Flory and J. J. Rehner, 'Statistical mechanics of cross-linked polymer networks II. Swelling', The Journal of Chemical Physics, 11 (1943), 521-526.
108. G. K. Fleming and W. J. Koros, 'Dilation of polymers by sorption of carbon dioxide at elevated pressures. 1. Silicone rubber and unconditioned polycarbonate', Macromolecules, 19 (1986), 2285-2291.
109. Y. Yang, Y. Huang, D. Wang, H. Liu and C. Hu, 'Sorption and diffusion of ethanol vapor in polybutadiene/acrylonitrile, polybutadiene/styrene and polybutadiene based polyurethanes', European Polymer Journal, 40 (2004), 855-863.
110. J. A. Barrie, 'Water in polymers', in J. Crank and G. S. Park (Eds), Diffusion in Polymers, Academic Press, New York, NY, USA (1968), pp. 259-314.
111. M. G. De Angelis, T. C. Merkel, V. Bondar, B. D. Freeman, F. Doghieri and G. C. Sarti, 'Hydrocarbon and fluorocarbon solubility and dilation in poly(dimethylsiloxane): Comparison of experimental data with predictions of the Sanchez-Lacombe equation of state', Journal of Polymer Science, Part B: Polymer Physics, 37 (1999), 3011-3026.
112. D. R. Paul, 'Gas sorption and transport in glassy polymers', Berichte der Bunsen-Gesellschaft, 83 (1979), 294-302.
113. R. Patterson and Y. P. Yampolskii, 'Solubility of gases in glassy polymers', Journal of Physical Chemistry Reference Data, 28 (1999), 1255-1450.
114. A. Tokarev, K. Friess, J. Machkova, M. Sipek and Y. P. Yampolskii, 'Sorption and diffusion of organic vapors in amorphous Teflon AF2400', Journal of Polymer Science, Part B: Polymer Physics, (2000), Vol. 44(5), (2006) 832-844.
115. W. J. Koros and R. T. Chern, 'Separation of gaseous mixtures using polymer membranes', in R.W. Rousseau (Ed.), Handbook of Separation Progress Technology, John Wiley & Sons, Inc., New York, NY, USA (1987), pp. 862-953.
116. W. J. Koros and D. R. Paul, 'Carbon dioxide sorption in poly(ethylene terephthalate) above and below the glass transition', Journal of Polymer Science, Part B: Polymer Physics, 16 (1978), 1947-1963.
117. V. V. Volkov, A. K. Bokarev, S. G. Durgaryan and N. S. Nametkin, 'Sorption of low-molecularweight compounds in glassy PVTMS in vicinity and below the critical temperature of the solute', Doklady Akademie Nauk SSSR, 282 (1985), 641-644.
118. S. M. Jordan and W. J. Koros, 'Characterization of CO2-induced conditioning of substituted polycarbonates using various ''exchange'' penetrants', Journal of Membrane Science, 51 (1990), 233-247.
119. S. M. Jordan, M. A. Henson andW. J. Koros, 'The effects of carbon dioxide conditioning on the permeation behavior of hollow fiber asymmetric membranes', Journal of Membrane Science, 54 (1990), 103-118.
120. V. Bondar, Y. Kamiya and Y. P. Yampolskii, 'On pressure dependence of the parameters of the dual-mode sorption model', Journal of Polymer Science, Part B: Polymer Physics, 34 (1996), 369-378.
121. A. R. Berens, 'The solubility of vinyl chloride in poly(vinyl chloride)', Die Angewandte Makromolekulare Chemie, 47 (1975), 97-110.
122. A. Y. Alentiev, V. P. Shantarovich, T. C. Merkel, V. Bondar, B. D. Freeman and Y. P. Yampolskii, 'Gas and vapor sorption, permeation, and diffusion in glassy amorphous Teflon AF1600', Macromolecules, 35 (2002), 9513-9522.
123. C. Staudt-Bickel and W. J. Koros, 'Improvement of CO2/CH4 separation characteristics of polyimides by chemical crosslinking', Journal of Membrane Science, 155 (1999), 145-154.
124. R. T. Chern and C. N. Provan, 'Gas-induced plasticization and the permselectivity of poly(tetrabromophenolphthalein) to a mixture of carbon dioxide and methane', Macromolecules, 24 (1991), 2203-2207.
125. S. Zhou and S. A. Stern, 'The effect of plasticization on the transport of gases in and through glassy polymers', Journal of Polymer Science, Part B: Polymer Physics, 27 (2003), 205-222.
126. H. Lin and B. D. Freeman, 'Gas and vapor solubility in crosslinked poly(ethylene glycol diacrylate)', Macromolecules, 38 (2005), 8394-8407.
127. A. A. Armstrong and V. T. Stannett, 'Temperature effects during the sorption and desorption of water vapor in high polymers. I. Fibers, with particular reference to wool', Makromolekulare Chemie, 90 (1966), 145-160.
128. W. J. Koros, D. R. Paul and A. A. Rocha, 'Carbon dioxide sorption and transport in polycarbonate', Journal of Polymer Science, Part B: Polymer Physics, 14 (1976), 687-702.
129. V. T. Stannett, 'The transport of gases in synthetic polymer membranes -a historic perspective', Journal of Membrane Science, 3 (1978), 97-115.
130. H. Lin, E. van Wagner, B. D. Freeman and I. Roman, 'High performance polymer membranes for natural gas sweetening', Advanced Materials, 18 (2006), 39-44.
131. T. S. Chow, 'Molecular interpretation of glass transition temperature of polymer-diluent systems', Macromolecules, 13 (1980), 362-364.
132. I. Pinnau and Z. He, 'Pure-and mixed-gas permeation properties of polydimethylsiloxane for hydrocarbon/methane and hydrocarbon/hydrogen separation', Journal of Membrane Science, 244 (2004), 227-233.
133. I. Pinnau and L. G. Toy, 'Transport of organic vapors through poly(1-trimethylsilyl-1-propyne)', Journal of Membrane Science, 116 (1996), 199-209.
134. R. Ash, R. M. Barrer and P. Sharma, 'Sorption and flow of carbon dioxide and some hydrocarbons in a microporous carbon membrane', Journal of Membrane Science, 1 (1976), 17-32.
135. R. Srinivasan, S. R. Auvil and P. M. Burban, 'Elucidating the mechanism(s) of gas transport in poly [1-(trimethylsilyl)-1-propyne] (PTMSP) membranes', Journal of Membrane Science, 86 (1994), 67-86.
136. S. Y. Lee, B. S. Minhas and M. D. Donohue, 'Effect of gas composition and pressure on permeation through cellulose acetate membranes', AIChE Symposium Series, 84 (1988), 93-101.
137. L. S. White, T. A. Blinka, H. A. Kloczewski and I.-F.Wang, 'Properties of a polyimide gas separation membrane in natural gas streams', Journal of Membrane Science, 103 (1995), 73-82.
138. H. Lin, E. van Wagner, B. D. Freeman, L. G. Toy and P. Ragubuir, 'New membrane materials for CO2/H2 separation and a model for pure and mixed gas permeability', Science, 311 (2006), 639-642.
139. A. Y. Houde, B. Krishnakumar, S. G. Charati and S. A. Stern, 'Permeability of dense (homogeneous) cellulose acetate membranes to methane, carbon dioxide, and their mixtures at elevated pressures', Journal of Applied Polymer Science, 62 (1996), 2181-2192.
140. S. V. Dixon-Garrett, K. Nagai and B. D. Freeman, 'Ethylbenzene solubility, diffusivity and permeability in poly(dimethylsiloxane)', Journal of Polymer Science, Part B: Polymer Physics, 38 (2000), 1461-1473.
141. H. Yasuda and T. Hirotsu, 'The effect of glass transition on gas permeability', Journal of Applied Polymer Science, 21 (1977), 105-112.
142. R. M. Barrer, 'Permeability in relation to viscosity and structure of rubber', Transactions of the Faraday Society, 38 (1942), 322-331.
143. G. J. van Amerongen, 'The permeability of different rubbers to gases and its relation to diffusivity and solubility', Journal of Applied Physics, 17 (1946), 972-985.
144. R. Prabhakar, B. D. Freeman and I. Roman, 'Gas and vapor sorption and permeation in poly(2, 2, 4-trifluoro -5-trifluoromethoxy -1, 3-dioxle-cotetrafluoroethylene)', Macromolecules, 37 (2004), 7688-7697.
145. R. Prabhakar, R. Raharjo, L. G. Toy, H. Lin and B. D. Freeman, 'Self-consistent model of concentration and temperature dependence of permeability in rubbery polymers', Industrial and Engineering Chemistry Research, 44 (2005), 1547-1556.
146. Y. P. Yampolskii, S. Shishatskii, A. Y. Alentiev and K. Loza, 'Correlations with and predictions of activation energies of gas permeation and diffusion in glassy polymers', Journal of Membrane Science, 148 (1998), 59-69.
147. S. Glasstone, K. J. Laidler and H. Eyring, The Theory of Rate Processes, McGraw-Hill, New York, NY, USA (1941).
148. S. A. Stern, V. M. Shah and B. J. Hardy, 'Structure-permeability relationship in silicone polymers', Journal of Polymer Science, Part B: Polymer Physics, 25 (1987), 1263-1298.
149. W. J. Koros and G. K. Fleming, 'Membranebased gas separation', Journal of Membrane Science, 83 (1993), 1-80.
150. Y. P. Yampolskii and N. A. Plate, 'Is it possible to predict transport properties of polymers proceeding from chemical structure of the chains?', Polymer Science, 36 (1994), 1599-1609.
151. H. Ohya, V. V. Kudryavtsev and S. I. Semenova, Polyimide Membranes -Applications, Fabrications and Properties, Gordon & Breach, Tokyo, Japan (1996).
152. S. M. Allen, M. Fujii, V. T. Stannett, H. B. Hopfenberg and J. L. Williams, 'The barrier properties of polyacrylonitrile', Journal of Membrane Science, 2 (1977), 153-163.
153. N. A. Plate and Y. P. Yampolskii, 'Relationship between structure and transport properties for high free volume polymeric materials', in D. R. Paul and Y. P. Yampolskii (Eds), Polymeric Gas Separation Membranes, CRC Press, Boca Raton, FL, USA (1994), pp. 155-207.
154. V. S. Khotimskii, V. G. Filippova, I. S. Bryantseva, V. I. Bondar, V. P. Shantarovich and Y. P. Yampolskii, 'Synthesis, transport and sorption properties and free volume of polystyrene derivatives containing Si and F', Journal of Applied Polymer Science, 78 (2000), 1612-1620.
155. E. S. Finkel'shtein, M. L. Gringolts, N. V. Ushakov, V. G. Lakhtin, S. A. Soloviev and Y. P. Yampolskii, 'Synthesis and gas permeation properties of new ROMP polymers from silyl substituted norbornadienes and norbornenes', Polymer, 44 (2003), 2843-2851.
156. E. S. Finkel'shtein, K. L. Makovetskii, Y. P. Yampolskii, E. Portnykh, I. Ostrovskaya and N. Kaliuzhnyi, 'Ring-opening polymerization of norbornenes with organosilicon substituents. Gas permeability of polymers obtained', Makromolekulare Chemie, 192 (1991), 1-9.
157. N. Muruganandam, W. J. Koros and D. R. Paul, 'Gas sorption and transport in substituted polycarbonates', Journal of Polymer Science, Part B: Polymer Physics, 25 (1987), 1999-2026.
158. C. L. Aitken, W. J. Koros and D. R. Paul, 'Gas transport properties of bisphenol polysulfones', Macromolecules, 25 (1992), 3651-3658.
159. C. L. Aitken, W. J. Koros and D. R. Paul, 'Effect of structural symmetry on gas transport properties of polysulfones', Macromolecules, 25 (1992), 3424-3434.
160. W. J. Koros and G. K. Fleming, 'Membranebased gas separation', Journal of Membrane Science, 83 (1993), 1-80.
161. J. S. McHattie, W. J. Koros, D. R. Paul, 'Gas transport properties of polysulfones. 1. Role of symmetry of methyl group placement on bisphenol', Polymer, 32 (1991), 840-850.
162. M. R. Pixton and D. R. Paul, 'Gas transport of polyarylates part II: Tetrabromination of the bisphenol', Journal of Polymer Science, Part B: Polymer Physics, 33 (1995), 1353-1364.
163. M. Aguilar-Vega and D. R. Paul, 'Gas transport properties of polycarbonates and polysulfones with aromatic substitutions on the bisphenol connector group', Journal of Polymer Science, Part B: Polymer Physics, 31 (1993), 1599-1610.
164. K. Ghosal, R. T. Chern, B. D. Freeman, W. H. Daly and I. I. Negulescu, 'Effect of basic susbtituents on gas sorption and permeation in polysulfone', Macromolecules, 29 (1996), 4360-4369.
165. M. R. Coleman and W. J. Koros, 'Isomeric polyimides based on fluorinated dianhydrides and diamines for gas separation applications', Journal of Membrane Science, 50 (1990), 285-297.
166. T. H. Kim, W. J. Koros, G. R. Husk and K. C. O'Brien, 'Relationship between gas separation properties and chemical structure in a series of aromatic polyimides', Journal of Membrane Science, 37 (1988), 45-62.
167. Y. P. Yampolskii, N. B. Bespalova, E. S. Finkel'shtein, V. Bondar and A. V. Popov, 'Synthesis, gas permeability, and gas sorption properties of fluorine-containing norbornene polymers', Macromolecules, 27 (1994), 2872-2878.
168. R. J. Andrews and E. A. Grulke, 'Glass transition temperatures of polymers, in J. Brandrup, E. H. Immergut, E. A. Grulke, A. Abe and D. R. Bloch (Eds), Polymer Handbook, 4th Edn, JohnWiley& Sons, Inc., New York, NY, USA (1999), pp. VI 193-VI 278.
169. V. T. Stannett and M. Szwarc, 'The permeability of polymer films to gases -a simple relationship', Journal of Polymer Science, 16 (1955), 89-91.
170. M. Salame and S. Steingiser, 'Barrier polymers', Polymer Plastics Technology and Engineering, 8 (1977), 155-175.
171. X.-Y. Wang, P. J. in't Veld, Y. Lu, B. D. Freeman and I. C. Sanchez, 'A molecular simulation study of cavity size distributions and diffusion in para and meta isomers', Polymer, 46 (2005), 9155-9161.
172. A. Morisato, N. R. Mirando, B. D. Freeman and H. B. Hopfenberg, 'The influence of chain configuration and, in turn, chain packing on the sorption and transport properties of poly(tert butyl acetylene)', Journal of Applied Polymer Science, 49 (1993), 2065-2074.
173. Y. P. Yampolskii, E. S. Finkelshtein, K. L. Makovetskii, V. Bondar and V. P. Shantarovich, 'Effects of cis-trans-configurations of the main chains of poly(trimethylsilyl norbornene) on its transport and sorption properties as well as free volume', Journal of Applied Polymer Science, 62 (1996), 349-357.
174. K. Weh, M. Noack, R. Ruhmann, K. Hoffman, P. Toussaint and J. Caro, 'Modification of the transport properties of a polymethacrylate azobenzene membrane by photochemical switching', Chemical Engineering Technology, 21 (1998), 408-412.
175. P. Zoller and D. J. Walsh, Standard Pressure-Volume-Temperature Data for Polymers, Technomic, Lancaster, PA, USA (1995).