Correlations with and prediction of activation energies of gas permeation and diffusion in glassy polymers

Journal of Membrane Science

Volumn 148, Issue 1, 1998, Pages 59-69

  Yampolskii, Yu ^a   Shishatskii, S ^a   Alentiev, A ^a   Loza, K ^a  

^a TOPCHIEV INSTITUTE OF PETROCHEMICAL SYNTHESIS   (Russian Federation)

Author keywords

Activation energy; Diffusion; Free volume; Gas and vapor permeation

Indexed keywords

ACTIVATION ENERGY; CORRELATION METHODS; DIFFUSION IN SOLIDS; GAS PERMEABLE MEMBRANES; MECHANICAL PERMEABILITY; POLYIMIDES; POLYMERIC GLASS;

ARRHENIUS EQUATION; FREE VOLUME EQUATION;

POLYMERIC MEMBRANES;

POLYMER;

ARTICLE; CHEMICAL ANALYSIS; DIFFUSION COEFFICIENT; ENERGY TRANSFER; GAS DIFFUSION; GAS PERMEABILITY; LOW TEMPERATURE; POLYMERIZATION; PREDICTION; PRIORITY JOURNAL;

EID: 0032538141     PISSN: 03767388     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0376-7388(98)00130-6     Document Type: Article

References (23)

1. D.W. Van Krevelen, Properties of Polymers, 3rd ed., Elsevier, Amsterdam, 1990.
2. J. Bicerano, Prediction of Polymer Properties, Marcel Dekker, New York, 1993.
3. Yampolskii Yu., Shishatskii S. On some regularities of diffusivity and permeability of glass polymers. Dokl. Akad. Nauk SSSR. 318:1991;653.
4. Park J.Y., Paul D.R. Correlation and prediction of gas permeability in glassy polymer membrane materials via a modified free volume based group contribution method. J. Membr. Sci. 125:1997;23.
5. Meares P. Diffusion of gases through polyvinyl acetate. J. Am. Chem. Soc. 76:1954;3415.
6. Teplyakov V., Meares P. Correlation aspects of the selective gas permeability of polymeric materials and membranes. Gas Sep. Puri. 4:1990;65.
7. Hirayama Y., Yoshinaga T., Kususki Y., Nonomiya K., Sakakibara T., Tamari T. Relation of gas permeability with structure of aromatic polyimides. J. Membr. Sci. 111:1996;169.
8. D.R. Paul, Yu. P. Yampolskii (Eds.), Polymeric Gas Separation Membranes, CRC Press, Boca Raton, 1994.
9. Lee W.M. Selection of barrier materials from molecular structure. Polym. Eng. Sci. 20:1980;65.
10. Maeda Y., Paul D.R. Effect of antiplasticization on gas sorption and transport III. Free volume interpretation. J. Polym. Sci., Part B. 25:1987;1005.
11. Barbari T.A., Koros W.J., Paul D.R. Gas transport in polymers based on bisphenol-A. J. Polym. Sci., Part B. 26:1988;709.
12. A. Bondi, Physical Properties of Molecular Crystals, Liquids, and Gases, Wiley, New York, 1968.
13. Teplyakov V.V., Durgaryan S.G. Temperature parameters of gas permeability of polymers. Vysokomol. Soed. A 26:1984;2159.
14. J.E. Leffler, E.M. Grundwald, Rates and Equilibria of Organic Reactions, Wiley, New York, 1963.
15. R. Stryjek, Yu. Yampolskii (Eds.), Chromatography and Thermodynamics. Determination of Physicochemical Parameters, IChF, Warsaw, 1986, p. 185.
16. Brandt W.W., Anysas G.A. Diffusion of gases in fluorocarbon polymers. J. Appl. Polym. Sci. 7:1963;1919.
17. Hirose T., Mizoguchi K., Kamiya Y. Gas transport in poly(vinyl benzoate). J. Appl. Polym. Sci. 30:1985;401.
18. Terada K., Mizoguchi K., Hirose T. Gas transport in poly(vinyl methylbenzoates). J. Polym. Sci., Part B. 30:1992;539.
19. Aguilar-Vega M., Paul D.R. Gas transport properties of polyphenylene ethers. J. Polym. Sci., Part B. 31:1993;1577.
20. Norton F.J. Gas permeation through Lexan polycarbonate resin. J. Appl. Polym. Sci. 7:1963;1649.
21. Costello L.M., Koros W.J. Thermally stable polyimide isomers for membrane-based gas separation at elevated temperatures. J. Polym. Sci., Part B. 33:1995;135.
22. Costello L.M., Koros W.J. Effects of structure on the temperature dependence of gas transport and sorption in a series of polycarbonates. J. Polym. Sci., Part B. 32:1994;701.
23. Tichomirov B.P., Hopfenberg H.B., Stannett V.T., Williams J.L. Permeation, diffusion, and sorption of gases and water in unplasticized polyvinylchloride. Makromol. Chem. 118:1968;177.