Nitrile-functionalized tertiary amines as highly efficient and reversible SO2 absorbents

Journal of Hazardous Materials

Volumn 264, Issue , 2014, Pages 136-143

  Hong, Sung Yun ^a   Kim, Heehwan ^a   Kim, Young Jin ^a   Jeong, Junkyo ^a   Cheong, Minserk ^a   Lee, Hyunjoo ^b   Kim, Hoon Sik ^a   Lee, Je Seung ^a  

^a Kyung Hee University   (South Korea)

^b Korea Institute of Science and Technology   (South Korea)

Author keywords

Absorbent; Amine; Nitrile; Recycle

Indexed keywords

ABSORPTION; AMINES; ATOMS; ETHANOL; RECYCLING; SULFUR DIOXIDE;

ABSORBENT; ABSORPTION PERFORMANCE; ABSORPTION RATES; ABSORPTION-DESORPTION; COMPUTATIONAL CALCULATIONS; METHYLENE GROUPS; NITRILE;

CYANIDES;

ABSORBENT; ALKANOLAMINE; CARBAMIC ACID; CARBENE; HYDROGEN; NITRILE; OXYGEN; TERTIARY AMINE;

ABSORPTION; COMPUTER SIMULATION; DESORPTION; HYDROGEN; NITRIC ACID; NITROGEN; RECYCLING; SULFUR DIOXIDE;

ABSORPTION; ARTICLE; ATMOSPHERIC PRESSURE; ATOM; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL INTERACTION; COMPARATIVE STUDY; COVALENT BOND; DESORPTION; FLUE GAS; INFRARED SPECTROSCOPY; MOLECULAR WEIGHT; PRESSURE; PROTON NUCLEAR MAGNETIC RESONANCE; PROTON TRANSPORT; SYNTHESIS; VISCOSITY;

ABSORBENT; AMINE; NITRILE; RECYCLE; SO(2);

ADSORPTION; AMINES; NITRILES; SULFUR DIOXIDE;

EID: 84888409937     PISSN: 03043894     EISSN: 18733336     Source Type: Journal    
DOI: 10.1016/j.jhazmat.2013.11.026     Document Type: Article

References (45)

1. 2. Science 1992, 258:117-120.
2. Izquierdo J.F., Fité C., Cunill F., Iborra M., Tejero J. Kinetic study of the reaction between sulfur dioxide and calcium hydroxide at low temperature in a fixed-bed reactor. J. Hazard. Mater. 2000, 76:113-123.
3. Molina M.J., Molina L.T. Megacities and atmospheric pollution. J. Air Waste Manage. Assoc. 2004, 54:644-680.
4. 4 sorbents. Chem. Eng. J. 2005, 114:171-177.
5. Dahlan I., Lee K.T., Kamaruddin A.H., Mohamed A.R. Evaluation of various additives on the preparation of rice husk ash (RHA)/CaO-based sorbent for flue gas desulfurization (FGD) at low temperature. J. Hazard. Mater. 2009, 161:570-574.
6. 2 removal from flue gas in the semidry FGD process with a powder-particle spouted bed. Chem. Eng. Sci. 2000, 55:4643-4652.
7. Wu S., Sumie N., Su C., Sasaoka E. Preparation of macroporous lime from natural lime by swelling method with water and acetic acid mixture for removal of sulfur dioxide at high-temperature. Ind. Eng. Chem. Res. 2002, 41:1352-1356.
8. 2 capture characteristics of three limestones in a fluidized-bed reactor. Energy Fuels 2006, 20:1621-1628.
9. Ortiz F.J.G. A simple realistic modeling of full-scale wet limestone FGD units. Chem. Eng. J. 2010, 165:426-439.
10. Heisel M.P., Belloni A.E. Options available in the Solinox vent gas purification process. Gas Sep. Purif. 1991, 5:111-113.
11. Demyanovich R.J., Lynn S. Prediction of infinite dilution activity coefficients of sulfur dioxide in organic solvents. J. Solution Chem. 1991, 20:693-701.
12. 2 capture based on a polyethylene glycol-loaded mesoporous molecular sieve. Energy Environ. Sci. 2009, 2:878-882.
13. Haertel G.H. Low-volatility polar organic solvents for sulfur dioxide, hydrogen sulfide, and carbonyl sulfide. J. Chem. Eng. Data 1985, 30:57-61.
14. Kohl A.L., Nielsen R. Gas Purification 1997, Gulf Publishing Co., New York. 5th ed.
15. 2 by aqueous solutions. J. Phys. Chem. A 2000, 104:7502-7510.
16. 2 absorption by an ionic liquid. Angew. Chem. Int. Ed. 2004, 43:2415-2417.
17. 2 by ionic liquids. Chem. Commun. 2006, 4027-4029.
18. Ando R.A., Siqueira L.J.A., Bazito F.C., Torresi R.M., Santos P.S. The sulfur dioxide-1-butyl-3-methylimidazolium bromide interaction: drastic changes in structural and physical properties. J. Phys. Chem. B 2007, 111:8717-8719.
19. Barrosse-Antle L.E., Silvester D.S., Aldous L., Hardacre C., Compton R.G. Electroreduction of sulfur dioxide in some room-temperature ionic liquids. J. Phys. Chem. C 2008, 112:3398-3404.
20. 2 capture by tunable azole-based ionic liquids through multiple-site chemical absorption. J. Am. Chem. Soc. 2011, 133:11916-11919.
21. 2 absorption/activation and subsequent utilization by polyethylene glycol-functionalized Lewis basic ionic liquids. Phys. Chem. Chem. Phys. 2012, 14:15832-15839.
22. Kwong K.V., Meissner R.E., Ahmed S., Wendt C.J. Application of amines for treating flue gas from coal-fired power plants. Environ. Prog. 1991, 10:211-215.
23. 2 removed by organic amine salt. Chem. Eng. News 1991, 69:7-8.
24. 2-anhydrous amines equilibrium. Rev. Chim. 2000, 51:687-696.
25. Brasoveanu D., Mihai M., Untea I., Belcu M. Sulphur dioxide absorption in organic bases. Interphase equilibrium in monoethanolamide, cyclohexylamine and morpholine. Rev. Chim. 2000, 51:959-965.
26. 2 into a blended aqueous AMP/ammonia solution. Korean J. Chem. Eng. 2011, 28:170-177.
27. 2 in thermochemical processes to produce hydrogen. Int. J. Hydrogen Energy 2008, 33:6031-6036.
28. 2 absorbents. Energy Environ. Sci. 2011, 4:1802-1806.
29. Frisch M.J. Gaussian 03, Revision C.02 2004, Gaussian Inc., Wallingford.
30. 2-binding organic liquid. Energy Environ. Sci. 2010, 3:111-113.
31. 2 capture in amine-based aqueous solution: role of the gas-solution interface. Angew. Chem. Int. Ed. 2011, 50:10178-10181.
32. 2O-alkanolamine systems: an NMR study. Ind. Eng. Chem. Res. 2005, 44:9894-9903.
33. 2 solubility in ionic liquids. J. Phys. Chem. B 2006, 110:15059-15062.
34. 2 in the TMGL from molecular dynamics simulation. J. Phys. Chem. B 2007, 111:10461-10467.
35. Siqueira L.J.A., Ando R.A., Bazito F.F.C., Torresi R.M., Santos P.S., Ribeiro M.C.C. Shielding of ionic interactions by sulfur dioxide in an ionic liquid. J. Phys. Chem. B 2008, 112:6430-6435.
36. 2 and the mechanism of the absorption. J. Phys. Chem. B 2010, 114:2175-2179.
37. 2: an electron spectroscopic study. J. Am. Chem. Soc. 1989, 111:5058-5063.
38. 2: Ionic liquids with o-alkylxanthate, o-alkylthiocarbonyl, and o-alkylsulfite anions. Chem. Eur. J. 2009, 15:7619-7627.
39. Wagner E.L., Hornig D.F. The vibrational spectra of molecules and complex ions in crystals IV. Ammonium bromide and deutero-ammonium bromide. J. Chem. Phys. 1950, 18:305-312.
40. Mureinik R.J., Robb W. The infrared spectra of the dihydrochloride salts of ethylenediamine and some substituted ethylenediamines. Spectrochim. Acta A 1968, 24:377-384.
41. 4Br-ammonium bromide to 55GPa. Solid State Commun. 2006, 140:202-207.
42. Pavia D.L., Lampman G.M., Kriz G.S., Vyvyan J.R. Introduction to Spectroscopy 2009, Cengage Leaning, Belmont. 4th ed.
43. Hisatsune I.C., Heicklen J. Infrared spectroscopic study of ammonia-sulfur dioxide-water solid state system. Can. J. Chem. 1975, 53:2646-2656.
44. 2 gas-triggered switches. J. Chem. Soc. Dalton Trans. 2000, 3797-3804.
45. Byrd W.E. Amine-sulfur dioxide complexes. Solid-liquid-gas equilibria and infrared spectra of complexes with N,N-dimethylanilines. Inorg. Chem. 1962, 1:762-768.