Model predictions of toxaphene degradation in the atmosphere over North America

Environmental Toxicology and Chemistry

Volumn 32, Issue 12, 2013, Pages 2663-2671

  Li, R ^a   Jin, J ^a  

^a UTAH STATE UNIVERSITY   (United States)

Author keywords

Chemical transformation; Fate and transport; Long range transport; Pesticide model; Toxaphene degradation

Indexed keywords

ATMOSPHERIC MOVEMENTS; FREE RADICALS; NITROGEN OXIDES; OZONE; PESTICIDES; PHOTOLYSIS; SUN; VOLATILE ORGANIC COMPOUNDS;

ATMOSPHERIC TRANSPORT; CHEMICAL DEGRADATION; CHEMICAL TRANSFORMATIONS; FATE AND TRANSPORT; LONG RANGE TRANSPORT; MULTIMEDIA MODELING; OZONE CONCENTRATION; SPATIAL AND TEMPORAL VARIABILITY;

DEGRADATION;

CAMPHECLOR; HYDROXYL RADICAL; NITROGEN OXIDE; OXYGEN; OZONE; VOLATILE ORGANIC COMPOUND;

ATMOSPHERE; ATMOSPHERIC TRANSPORT; DEGRADATION; NITROGEN OXIDES; OXYGEN; OZONE; PESTICIDE; PHOTOLYSIS; SOLAR RADIATION; SPATIAL DISTRIBUTION; WATER VAPOR;

AEROSOL; ARTICLE; ATMOSPHERE; ATMOSPHERIC DEPOSITION; ATMOSPHERIC TRANSPORT; ATOM; BIODEGRADATION; CHEMICAL ANALYSIS; CHEMICAL INTERACTION; CHEMICAL REACTION; CONTROLLED STUDY; GREENHOUSE GAS; MULTIMEDIA; NORTH AMERICA; OZONE LAYER; PHOTOLYSIS; PREDICTION; PRIORITY JOURNAL; SEASONAL VARIATION; SOIL; SOLAR RADIATION; SPATIAL SOIL VARIABILITY; SUNLIGHT; UNITED STATES; WATER VAPOR;

NORTH AMERICA; UNITED STATES;

CHEMICAL TRANSFORMATION; FATE AND TRANSPORT; LONG-RANGE TRANSPORT; PESTICIDE MODEL; TOXAPHENE DEGRADATION;

ATMOSPHERE; MODELS, CHEMICAL; NITROGEN OXIDES; NORTH AMERICA; PESTICIDE RESIDUES; PESTICIDES; PHOTOLYSIS; REACTIVE OXYGEN SPECIES; SOIL POLLUTANTS; SOLAR ENERGY; SUNLIGHT; TOXAPHENE;

EID: 84887819553     PISSN: 07307268     EISSN: 15528618     Source Type: Journal    
DOI: 10.1002/etc.2344     Document Type: Article

References (40)

1. Li R, Scholtz MT, Yang F, Sloan JJ. 2011. A multimedia fate and chemical transport modeling system for pesticides: I. Model development and implementation. Environ Res Lett 6:1-9.
2. James RR, Hites RA. 2002. Atmospheric transport of toxaphene from the southern United States to the Great Lakes region. Environ Sci Technol 36:3474-3481.
3. Kern S, Fenner K, Singer HP, Schwarzenbach RP, Hollender J. 2009. Identification of transformation products of organic contaminants in natural waters by computer-aided prediction and high-resolution mass spectrometry. Environ Sci Technol 43:7039-7046.
4. Balmer M, Goss K, Schwarzenbach R. 2000. Photolytic transformation of organic pollutants on soil surfaces-An experimental approach. Environ Sci Technol 34:1240-1245.
5. Jones W, Ananyeva N. 2001. Correlations between pesticide transformation rate and microbial respiration activity in soil of different ecosystems. Biol Fertility Soils 33:477-483.
6. Leistra M, Smelt J. 2001. An appraisal of methods for measurement of pesticide transformation in the groundwater zone. Pest Manag Sci 57:333-340.
7. Nielsen MKK, Holtze MS, Svensmark B, Juhler RK. 2007. Demonstrating formation of potentially persistent transformation products from the herbicides bromoxynil and ioxynil using liquid chromatography-tandem mass spectrometry (LC-MS/MS). Pest Manag Sci 63:141-149.
8. Samsonov YN. 2007. Physicochemical transformation and photochemical reactions in high-disperse substance state: Chemical decomposition in aerosols and thin films made from pesticide fipronil (Adonis). J Atmos Chem 56:127-147.
9. Vink J, Schraa C, van der Zee S. 1999. Nutrient effects on microbial transformation of pesticides in nitrifying surface waters. Environ Toxicol 14:329-338.
10. Sinclair C, Boxall A. 2003. Assessing the ecotoxicity of pesticide transformation products. Environ Sci Technol 37:4617-4625.
11. Guicherit R, Bakker D, de Voogt P, van den Berg F, van Dijk H, van Pul W. 1999. Environmental risk assessment for pesticides in the atmosphere; The results of an international workshop. Water Air Soil Pollut 115:5-19.
12. MacLeod M, Mackay D. 2004. Modeling transport and deposition of contaminants to ecosystems of concern: A case study for the Laurentian Great Lakes. Environ Pollut 128:241-250.
13. Ma JM, Venkatesh S, Li YF, Daggupaty S. 2005. Tracking toxaphene in the North American Great Lakes Basin. 1. Impact of toxaphene residues in United States soils. Environ Sci Technol 39:8123-8131.
14. Li R. 2012. Modeling of pesticide emissions from agricultural ecosystems. J Geophys Res-Atmos 117:1-13.
15. Li R, Scholtz MT, Yang F, Sloan JJ. 2011. A multimedia fate and chemical transport modeling system for pesticides: II. Model evaluation. Environ Res Lett 6:1-8.
16. Maruya K, Wakeham S, Vetter W, Francendese L. 2000. Prominent chlorobornane residues in estuarine sediments contaminated with toxaphene. Environ Toxicol Chem 19:2198-2203.
17. Khalifa S, Mon T, Engel J, Casida J. 1974. Isolation of 2, 2, 5-endo, 6-exo, 8, 9, 10-heptachlorobornane and an octachloro toxicant from technical toxaphene. J Agric Food Chem 22:653-657.
18. Lee G, Hughes R, Veith G. 1977. Evidence for partial degradation of toxaphene in aquatic environment. Water Air Soil Pollut 8:479-484.
19. Turner W, Khalifa S, Casida J. 1975. Toxaphene Toxicant-a-Mixture of 2, 2, 5-endo, 6-exo, 8, 8, 9, 10-octachlorobornane and 2, 2, 5-endo, 6-exo, 8, 9, 9, 10-octachlorobornane. J Agric Food Chem 23:991-994.
20. Turner W, Engel J, Casida J. 1977. Toxaphene components and related compounds-Preparation and toxicity of some heptachlorobornanes, octachlorobornanes, and nonachlorobornanes, hexachlorobornenes and heptachlorobornenes, and a hexachlorobornadiene. J Agric Food Chem 25:1394-1401.
21. Saleh M, Turner W, Casida J. 1977. Polychloroborane components of toxaphene-Structure-toxicity relations and metabolic reductive dechlorination. Science 198:1256-1258.
22. US Environmental Protection Agency. 2006. More information is needed on toxaphene degradation products. EPA 2006/P/00007. Technical Report. Washington, DC.
23. Pleim J, Xiu A. 2003. Development of a land surface model. Part II: Data assimilation. J Appl Meteorol 42:1811-1822.
24. Xiu A, Pleim J. 2001. Development of a land surface model. Part I: Application in a mesoscale meteorological model. J Appl Meteorol 40:192-209.
25. Otte TL, Pleim JE. 2010. The Meteorology-Chemistry Interface Processor (MCIP) for the CMAQ modeling system: Updates through MCIPv3.4.1. Geosci Model Dev 3:243-256.
26. Scholtz MT, Voldner E, McMillan AC, Van Heyst BJ. 2002. A pesticide emission model (PEM) Part I: Model development. Atmos Environ 36:5005-5013.
27. Scholtz MT, Voldner E, Van Heyst BJ, McMillan AC, Pattey E. 2002. A pesticide emission model (PEM) Part II: Model evaluation. Atmos Environ 36:5015-5024.
28. Houyoux M, Vukovich J, Coats C, Wheeler N, Kasibhatla P. 2000. Emission inventory development and processing for the Seasonal Model for Regional Air Quality (SMRAQ) Project RID A-2574-2010. J Geophys Res-Atmos 105:9079-9090.
29. Byun DW, Schere KL. 2006. Review of the governing equations, computational algorithms, and other components of the Models-3 Community Multiscale Air Quality (CMAQ) Modeling System. Appl Mech Rev 56:51-77.
30. Gipson GL, Young JO. 1999. Gas-phase chemistry. In Byun DW, Ching JKS, eds Science Algorithms of the EPA Models-3 Community Multiscale Air Quality (CMAQ) Modeling System. US Environmental Protection Agency, Research Triangle Park, NC, USA, pp 8-1-28.
31. US National Library of Medicine. 2004. Toxnet: Toxicology Data Network. [cited 2004 January 8]. Available from: http://toxnet.nlm.nih.gov/index.html.
32. US Environmental Protection Agency. 2005. The 1999 National Emission Inventory (NEI), version 3. [cited 2005 April 26]. Available from: ftp://ftp.epa.gov/EmisInventory/99neiv3_ida.
33. Vetter W. 1993. Toxaphene: Theoretical aspects of the distribution of chlorinated boranes including symmetrical aspects. Chemosphere 26:1079-1084.
34. Kentarchos A, Roelofs G. 2003. A model study of stratospheric ozone in the troposphere and its contribution to tropospheric OH formation. J Geophys Res-Atmos 108:8517.
35. Roelofs G, Kentarchos A, Trickl T, Stohl A, Collins W, Crowther R, Hauglustaine D, Klonecki A, Law K, Lawrence M, von Kuhlmann R, van Weele M. 2003. Intercomparison of tropospheric ozone models: Ozone transport in a complex tropopause folding event. J Geophys Res-Atmos 108:8529.
36. 3 levels. Tellus Ser B-Chem Phys Meteorol 49:38-55.
37. Boylan JW, Russell AG. 2006. PM and light extinction model performance metrics, goals, and criteria for three-dimensional air quality models. Atmos Environ 40:4946-4959.
38. Li R. 2013. Modeling of temporal patterns and sources of atmospherically transported and deposited pesticides in ecosystems of concern: A case study of toxaphene in the Great Lakes. J Geophys Res Atmos 118:1-12.
39. Aspelin AL. 2003. Pesticide Usage in the United States: Trends During the 20th Century. Center for Integrated Pest Management, North Carolina State University, Raleigh, NC, USA.
40. van Zelm R, Huijbregts MAJ, van de Meent D. 2010. Transformation products in the life cycle impact assessment of chemicals. Environ Sci Technol 44:1004-1009.