Synthesis and characterization of thiolated chitosan beads for removal of Cu(II) and Cd(II) from wastewater

Water, Air, and Soil Pollution

Volumn 224, Issue 12, 2013, Pages

  Yong, Soon Kong ^a,b   Bolan, Nanthi ^a   Lombi, Enzo ^a   Skinner, William ^a  

^a UNIVERSITY OF SOUTH AUSTRALIA   (Australia)

^b UNIVERSITI TEKNOLOGI MARA   (Malaysia)

Author keywords

Chitosan; Crosslink; Heavy metal; Thiourea; Wastewater

Indexed keywords

CHITOSAN; COPPER COMPOUNDS; CROSSLINKING; DYES; HEAVY METALS; MICROPOROUS MATERIALS; THIOUREAS; WASTEWATER; X RAY PHOTOELECTRON SPECTROSCOPY;

BRUNAUER-EMMETT-TELLER SURFACE AREAS; CHEMICAL ADSORPTION; FREUNDLICH ISOTHERM MODEL; HARD-SOFT ACID-BASE; HETEROGENEOUS SURFACE; PSEUDO-SECOND-ORDER KINETIC MODELS; RATE-LIMITING STEPS; SYNTHESIS AND CHARACTERIZATIONS;

CADMIUM COMPOUNDS;

AMINE; CADMIUM DERIVATIVE; CHITOSAN; COPPER COMPLEX; SULFONIC ACID DERIVATIVE; SULFUR DERIVATIVE; THIOLATED CHITOSAN BEAD; UNCLASSIFIED DRUG;

CADMIUM; CHITIN; COPPER; OXIDATION; POLLUTANT REMOVAL; REACTION KINETICS; SORPTION; SULFUR; WASTEWATER; X-RAY SPECTROSCOPY;

ADSORPTION KINETICS; ARTICLE; CHEMICAL INTERACTION; CONTROLLED STUDY; DECOMPOSITION; FREUNDLICH ISOTHERM MODEL; HEAVY METAL REMOVAL; HO PSEUDO SECOND ORDER KINETIC MODEL; INFRARED SPECTROSCOPY; MODEL; OXIDATION; PH; PHYSICAL CHEMISTRY; SYNTHESIS; WASTE WATER; X RAY PHOTOELECTRON SPECTROSCOPY;

EID: 84887592861     PISSN: 00496979     EISSN: 15732932     Source Type: Journal    
DOI: 10.1007/s11270-013-1720-0     Document Type: Article

References (41)

1. Alfarra, A., Frackowiak, E., & Béguin, F. (2004). The HSAB concept as a means to interpret the adsorption of metal ions onto activated carbons. Applied Surface Science, 228(1-4), 84-92.
2. Atia, A. A. (2005). Studies on the interaction of mercury(II) and uranyl(II) with modified chitosan resins. Hydrometallurgy, 80(1-2), 13-22. (Pubitemid 41525681)
3. Atzei, D., De Filippo, D., Rossi, A., Caminiti, R., & Sadun, C. (1995). XPS and LAXS study of 1,3-thiazolidine-2-thione and its complexes with Co(II) and Zn(II). Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 51(1), 11-20.
4. Azlan, K., Wan Saime, W. N., & Lai Ken, L. (2009). Chitosan and chemically modified chitosan beads for acid dyes sorption. Journal of Environmental Sciences, 21(3), 296-302.
5. Benguella, B., & Benaissa, H. (2002). Cadmium removal from aqueous solutions by chitin: kinetic and equilibrium studies. Water Research, 36, 2463-2474. (Pubitemid 34575597)
6. Cárdenas, G., Díaz, V. J., Meléndrez, M., Cruzat, C. C., & García Cancino, A. (2009). Colloidal Cu nanoparticles/chitosan composite film obtained by microwave heating for food package applications. Polymer Bulletin, 62(4), 511-524.
7. Castner, D. G., Hinds, K., & Grainger, D. W. (1996). X-ray photoelectron spectroscopy sulfur 2p study of organic thiol and disulfide binding interactions with gold surfaces. Langmuir, 12(21), 5083-5086. (Pubitemid 126536504)
8. Chatterjee, S., Lee, D. S., Lee, M. W., & Woo, S. H. (2010). Enhanced molar sorption ratio for naphthalene through the impregnation of surfactant into chitosan hydrogel beads. Bioresource Technology, 101(12), 4315-4321.
9. Dahiya, S., Tripathi, R. M., & Hegde, A. G. (2008). Biosorption of lead and copper from aqueous solutions by pre-treated crab and Arca shell biomass. Bioresource Technology, 99(1), 179-187. (Pubitemid 47503761)
10. Dambies, L., Guimon, C., Yiacoumi, S., & Guibal, E. (2000). Characterization of metal ion interactions with chitosan by X-ray photoelectron spectroscopy. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 177(2-3), 203-214.
11. Donia, A. M., Atia, A. A., & Heniesh, A. M. (2008). Efficient removal of Hg(II) using magnetic chelating resin derived from copolymerization of bisthiourea/thiourea/glutaraldehyde. Separation and Purification Technology, 60(1), 46-53. (Pubitemid 351318304)
12. Erve, J. C. L., Amarnath, V., Graham, D. G., Sills, R. C., Morgan, A. L., & Valentine, W. M. (1998). Carbon disulfide and N, N-diethyldithiocarbamate generate thiourea cross-links on erythrocyte spectrin in vivo. Chemical Research in Toxicology, 11(5), 544-549. (Pubitemid 28242500)
13. Gavilan, K. C., Pestov, A. V., Garcia, H. M., Yatluk, Y., Roussy, J., & Guibal, E. (2009). Mercury sorption on a thiocarbamoyl derivative of chitosan. Journal of Hazardous Materials, 165(1-3), 415-426.
14. Gong, H., Yin, M., & Liu, M. (2003). In situ coordination-induced langmuir film formation of water-soluble 2,5-dimercapto-1,3,4-thiadiazole at the air/water interface and the growth of metal sulfide nanostructures in their templated Langmuir - Schaefer films. Langmuir, 19(20), 8280-8286.
15. Goubert-Renaudin, S., Gaslain, F., Marichal, C., Lebeau, B., Schneider, R., & Walcarius, A. (2009). Synthesis of dithiocarbamate-functionalized mesoporous silica-based materials: interest of one-step grafting. New Journal of Chemistry, 33(3), 528-537.
16. Horzum, N., BoyacI, E., Eroǧlu, A. E., Shahwan, T., & Demir, M. M. (2010). Sorption efficiency of chitosan nanofibers toward metal ions at low concentrations. Biomacromolecules, 11(12), 3301-3308.
17. Humeres, E., De, S. E. P., Debacher, N. A., & Aliev, A. E. (2002). Synthesis and coordinating ability of chitosan dithiocarbamate and analogs towards Cu(II) ions. Journal of Physical Organic Chemistry, 15(12), 852-857.
18. Juang, R. S., & Shao, H. J. (2002). A simplified equilibrium model for sorption of heavy metal ions from aqueous solutions on chitosan. Water Research, 36(12), 2999-3008. (Pubitemid 34665435)
19. Kagaya, S., Miyazaki, H., Ito, M., Tohda, K., & Kanbara, T. (2010). Selective removal of mercury(II) from wastewater using polythioamides. Journal of Hazardous Materials, 175(1-3), 1113-1115.
20. Kim, H. J., Graham, D. W., DiSpirito, A. A., Alterman, M. A., Galeva, N., Larive, C. K., et al. (2004). Methanobactin, a copper-acquisition compound from methane-oxidizing bacteria. Science, 305(5690), 1612-1615. (Pubitemid 39296354)
21. Kumar, A., Arienzo, M., Quayle, W., Christen, E., Grocke, S., Fattore, A., et al. (2009). In A. Kumar & E. Christen (Eds.), Developing a systematic approach to winery wastewater management (p. 149). Adelaide: CSIRO.
22. Lasko, C. L., Pesic, B. M., & Oliver, D. J. (1993). Enhancement of the metal-binding properties of chitosan through synthetic addition of sulfur- and nitrogen-containing compounds. Journal of Applied Polymer Science, 48(9), 1565-1570.
23. Muzzarelli, R., Tanfani, F., Mariotti, S., & Emanuelli, M. (1982). Preparation and characteristic properties of dithiocarbamate chitosan, a chelating polymer. Carbohydrate Research, 104(2), 235-243.
24. Nunthanid, J., Laungtana-anan, M., Sriamornsak, P., Limmatvapirat, S., Puttipipatkhachorn, S., Lim, L. Y., et al. (2004). Characterization of chitosan acetate as a binder for sustained release tablets. Journal of Controlled Release, 99(1), 15-26. (Pubitemid 39165730)
25. Osifo, P. O., Webster, A., van der Merwe, H., Neomagus, H. W. J. P., van der Gun, M. A., & Grant, D. M. (2008). The influence of the degree of cross-linking on the adsorption properties of chitosan beads. Bioresource Technology, 99(15), 7377-7382.
26. Ozturk, I. I., Hadjikakou, S. K., Hadjiliadis, N., Kourkoumelis, N., Kubicki, M., Tasiopoulos, A. J., et al. (2009). New antimony(III) bromide complexes with thioamides: synthesis, characterization, and cytostatic properties. Inorganic Chemistry, 48(5), 2233-2245.
27. Pearson, R. G. (1963). Hard and soft acids and bases. Journal of the American Chemical Society, 85(22), 3533-3539.
28. Popuri, S. R., Vijaya, Y., Boddu, V. M., & Abburi, K. (2009). Adsorptive removal of copper and nickel ions from water using chitosan coated PVC beads. Bioresource Technology, 100(1), 194-199.
29. Renault, F., Sancey, B., Badot, P. M., & Crini, G. (2009). Chitosan for coagulation/flocculation processes - an eco-friendly approach. European Polymer Journal, 45(5), 1337-1348.
30. Rengaraj, S., Yeon, J.-W., Kim, Y., Jung, Y., Ha, Y.-K., & Kim, W.-H. (2007). Adsorption characteristics of Cu(II) onto ion exchange resins 252H and 1500H: kinetics, isotherms and error analysis. Journal of Hazardous Materials, 143(1-2), 469-477. (Pubitemid 46560243)
31. Rieley, H., Kendall, G. K., Zemicael, F. W., Smith, T. L., & Yang, S. (1998). X-ray studies of self-assembled monolayers on coinage metals. 1. Alignment and photooxidation in 1,8-octanedithiol and 1-octanethiol on Au. Langmuir, 14(18), 5147-5153. (Pubitemid 128612846)
32. Sankararamakrishnan, N., & Sanghi, R. (2006). Preparation and characterization of a novel xanthated chitosan. Carbohydrate Polymers, 66(2), 160-167. (Pubitemid 44427912)
33. Sankararamakrishnan, N., Dixit, A., Iyengar, L., & Sanghi, R. (2006). Removal of hexavalent chromium using a novel cross linked xanthated chitosan. Bioresource Technology, 97(18), 2377-2382. (Pubitemid 44093235)
34. Skinner, W. M., Prestidge, C. A., & Smart, R. S. C. (1996). Irradiation effects during XPS studies of Cu(II) activation of zinc sulphide. Surface and Interface Analysis, 24(9), 620-626. (Pubitemid 126601239)
35. Sousa, K. S., Silva Filho, E. C., & Airoldi, C. (2009). Ethylenesulfide as a useful agent for incorporation into the biopolymer chitosan in a solvent-free reaction for use in cation removal. Carbohydrate Research, 344(13), 1716-1723.
36. Van Zwieten, M., Stovold, G., & Van Zwieten, L. (2007). Alternatives to copper for disease control in the Australian organic industry (p. 82). Canberra: Rural Industries Research and Development Corporation.
37. Vold, I. M. N., Vårum, K. M., Guibal, E., & Smidsrød, O. (2003). Binding of ions to chitosan - selectivity studies. Carbohydrate Polymers, 54(4), 471-477.
38. Wan Ngah, W. S., Ariff, N., & Hanafiah, M. (2010a). Preparation, characterization, and environmental application of crosslinked chitosan-coated bentonite for tartrazine adsorption from aqueous solutions. Water, Air, & Soil Pollution, 206(1), 225-236.
39. Wan Ngah, W. S., Ariff, N. F. M., Hashim, A., & Hanafiah, M. A. K. M. (2010b). Malachite green adsorption onto chitosan coated bentonite beads: isotherms, kinetics and mechanism. CLEAN - Soil, Air, Water, 38(4), 394-400.
40. Wang, L., Xing, R., Liu, S., Cai, S., Yu, H., Feng, J., et al. (2010). Synthesis and evaluation of a thiourea-modified chitosan derivative applied for adsorption of Hg(II) from synthetic wastewater. International Journal of Biological Macromolecules, 46(5), 524-528.
41. Yong, S. K., Bolan, N. S., Lombi, E., Skinner, W., & Guibal, E. (2012). Sulfur-containing chitin and chitosan derivatives as trace metal adsorbents: a review. Critical Reviews in Environmental Science and Technology. doi: 10.1080/10643389.2012.671734.