Ethanol steam reforming over hydrotalcite-derived Co catalysts doped with Pt and Rh

Topics in Catalysis

Volumn 56, Issue 18-20, 2013, Pages 1660-1671

  Espinal, Raúl ^a   Taboada, Elena ^a   Molins, Elies ^b   Chimentao, Ricardo J ^c   Medina, Francesc ^c   Llorca, Jordi ^a  

^a UNIVERSITAT POLITÈCNICA DE CATALUNYA   (Spain)

^b INSTITUT DE CIÈNCIA DE MATERIALS DE BARCELONA ICMAB CSIC   (Spain)

^c UNIVERSITAT ROVIRA I VIRGILI   (Spain)

Author keywords

Cobalt; Ethanol steam reforming; Hydrogen; Hydrotalcite; Noble metal

Indexed keywords

CARBON DEPOSITION; COBALT NANOPARTICLES; ETHANOL REFORMING; ETHANOL STEAM REFORMING; ETHANOL STEAM REFORMING (ESR); HYDROTALCITES; OPERATIONAL CONDITIONS; STEAM REFORMING OF ETHANOL;

CARBON; CATALYSTS; COBALT; ETHANOL; HYDROGEN; METAL NANOPARTICLES; PHOTOELECTRONS; PLATINUM; PRECIOUS METALS; RHODIUM; X RAY PHOTOELECTRON SPECTROSCOPY;

STEAM REFORMING;

EID: 84887534617     PISSN: 10225528     EISSN: None     Source Type: Journal    
DOI: 10.1007/s11244-013-0100-8     Document Type: Conference Paper

References (64)

1. Haryanto A, Fernando S, Murali N, Adhikari S (2005) Current status of hydrogen production techniques by steam reforming of ethanol: a review. Energy Fuels 19:2098
2. Vaidya PD, Rodrigues AE (2006) Insight into steam reforming of ethanol to produce hydrogen for fuel cells. Chem Eng J 117:39
3. Ni M, Leung DCY, Leung MKH (2007) A review on reforming bio-ethanol for hydrogen production. Int J Hydrog Energy 32:3238
4. Kolb G (2008) Fuel processing for fuel cells. Wiely-VCH, Weinheim, pp 1-434
5. Llorca J (2010) Microreactors for the generation of hydrogen from ethanol. In: Lee WH, Cho VG (eds) Handbook of sustainable energy. Nova Publishers, New York, pp 693-699
6. 2 nanoparticles. Nat Chem 3:489
7. Casanovas A, Saint-Gerons M, Griffon F, Llorca J (2008) Autothermal generation of hydrogen from ethanol in a microreactor. Int J Hydrog Energy 33:1827
8. Deluga GA, Salge JR, Schmidt LD, Verykios XE (2004) Renewable hydrogen from ethanol by autothermal reforming. Science 303:993
9. Frusteri F, Freni S (2007) Bio-ethanol, a suitable fuel to produce hydrogen for a molten carbonate fuel cell. J Power Sources 173:200
10. Idriss H, Scott M, Llorca J, Chan SC, Chiu W, Sheng PY, Yee Y, Blackford MA, Pas SJ, Hill AJ, Alamgir FM, Rettew R, Petersburg C, Senanayake SD, Barteau MA (2008) A phenomenological study of the metal-oxide interface: the role of catalysis in hydrogen production from renewable resources. ChemSusChem 1:905
11. Frusteri F, Freni S, Chiodo V, Spadaro L, Blasi ODi, Bonura G, Cavallaro S (2004) Steam reforming of bio-ethanol on alkali-doped Ni/MgO catalysts: hydrogen production for MC fuel cell. Appl Catal A 270:1
12. 4 during ethanol steam-re-forming. Activation process for hydrogen production. Chem Mater 16:3573
13. Garcia VM, Lopez E, Serra M, Llorca J (2009) Dynamic modeling of a three-stage low-temperature ethanol reformer for fuel cell application. J Power Sources 192:208
14. Song H, Zhang L, Ozkan US (2010) Investigation of the reaction network in ethanol steam reforming over supported cobalt catalysts. Ind Eng Chem Res 49:8984
15. Haga F, Nakajima T, Miya H, Mishima S (1997) Catalytic properties of supported cobalt catalysts for steam reforming of ethanol. Catal Lett 48:223
16. Cavallaro S, Mondello N, Freni S (2001) Hydrogen produced from ethanol for internal reforming molten carbonate fuel cell. J Power Sources 102:198
17. Llorca J, Homs N, Sales J, de la Piscina PR (2002) Efficient production of hydrogen over supported cobalt catalysts from ethanol steam reforming. J Catal 209:306
18. Kaddouri A, Mazzocchia C (2004) A study of the influence of the synthesis conditions upon the catalytic properties of Co/SiO2 or Co/Al2O3 catalysts used for ethanol steam reforming. Catal Commun 5:339
19. Batista MS, Santos RKS, Assaf EM, Assaf JM, Ticianelli EA (2004) High efficiency steam reforming of ethanol by cobalt-based catalysts. J Power Sources 134:27
20. Llorca J, Homs N, de la Piscina PR (2004) In situ DRIFT-mass spectrometry study of the ethanol steam-reforming reaction over carbonyl-derived Co/ZnO catalysts. J Catal 227:556
21. Llorca J, Dalmon JA, de la Piscina PR, Homs N (2003) In situ magnetic characterisation of supported cobalt catalysts under steam-reforming of ethanol. Appl Catal A 243:261
22. Llorca J, de la Piscina PR, Dalmon JA, Sales J, Homs N (2003) CO-free hydrogen from steam-reforming of bioethanol over ZnO-supported cobalt catalysts - effect of the metallic precursor. Appl Catal B 43:355
23. Dominguez M, Taboada E, Idriss H, Molins E, Llorca J (2010) Fast and efficient hydrogen generation catalyzed by cobalt talc nanolayers dispersed in silica aerogel. J Mater Chem 20:4875
24. Bayram B, Soykal II, von Deak D, Miller JT, Ozkan US (2011) Ethanol steam reforming over Co-based catalysts: investigation of cobalt coordination environment under reaction conditions. J Catal 284:77
25. Llorca J, Homs N, Sales J, Fierro JLG, de la Piscina PR (2004) Effect of sodium addition on the performance of Co-ZnO-based catalysts for hydrogen production from bioethanol. J Catal 222:470
26. Kim KS, Seo HR, Lee SY, Ahn JG, Shin WC, Lee YK (2010) TPR and EXAFS studies on Na-promoted Co/ZnO catalysts for ethanol steam reforming. Top Catal 53:615
27. Song H, Ozkan US (2009) Ethanol steam reforming over Co-based catalysts: role of oxygen mobility. J Catal 261:66
28. Song H, Bao X, Hadad CM, Ozkan US (2011) Adsorption/desorption behavior of ethanol steam reforming reactants and intermediates over supported cobalt catalysts. Catal Lett 141:43
29. 2 catalyst. J Catal 268:268
30. Vargas JC, Libs S, Roger AC, Kiennemann A (2005) Study of Ce-Zr-Co fluorite-type oxide as catalysts for hydrogen production by steam reforming of bioethanol. Catal Today 107-08:417
31. Song H, Zhang LZ, Watson RB, Braden D, Ozkan US (2007) Investigation of bio-ethanol steam reforming over cobalt-based catalysts. Catal Today 129:346
32. Avila-Neto CN, Liberatori JWC, da Silva AM, Zanchet D, Hori CE, Noronha FB, Bueno JMC (2012) Understanding the stability of Co-supported catalysts during ethanol reforming as addressed by in situ temperature and spatial resolved XAFS analysis. J Catal 287:124
33. Rybak P, Tomaszewska B, Machocki A, Grzegorczyk W, Denis A (2011) Conversion of ethanol over supported cobalt oxide catalysts. Catal Today 176:14
34. Song H, Ozkan US (2010) Changing the oxygen mobility in Co/ceria catalysts by Ca incorporation: implications for ethanol steam reforming. J Phys Chem A 114:3796
35. 2 catalysts prepared by impregnation and coprecipitation for ethanol steam reforming. Appl Catal A 366:252
36. 2 as ethanol steam reforming catalysts. Catal Lett 132:422
37. Wang H, Ye JL, Liu Y, Li YD, Qin YN (2007) Steam reforming of ethanol over Co3O4/CeO2 catalysts prepared by different methods. Catal Today 129:305
38. Benito M, Padilla R, Serrano-Lotina A, Rodríguez L, Brey JJ, Daza L (2009) The role of surface reactions on the active and selective catalyst design for bioethanol steam reforming. J Power Sources 192:158
39. Martono E, Hyman MP, Vohs JM (2011) Reaction pathways for ethanol on model Co/ZnO(0001) catalysts. Phys Chem Chem Phys 13:9880
40. Karim AM, Su Y, Engelhard MH, King DL, Wang Y (2011) ACS Catal 1:279
41. Hyman MP, Vohs JM (2011) Reaction of ethanol on oxidized and metallic cobalt surfaces. Surf Sci 605:383
42. Busca G, Costantino U, Montanari T, Ramis G, Resini C, Sisani M (2010) Nickel versus cobalt catalysts for hydrogen production by ethanol steam reforming: Ni-Co-Zn-Al catalysts from hydrotalcite-like precursors. Int J Hydrog Energy 35:5356
43. Espinal R, Taboada E, Molins E, Chimentao RJ, Medina F, Llorca J (2012) Cobalt hydrotalcite for the steam reforming of ethanol with scarce carbon production. RSC Adv 2:2946
44. Da Costa-Serra JF, Chica A (2011) Bioethanol steam reforming on Co/ITQ-18 catalyst: effect of the crystalline structure of the delaminated zeolite ITQ-18. Int J Hydrog Energy 36:3862
45. Espinal R, Taboada E, Molins E, Chimentao RJ, Medina F, Llorca J (2012) Cobalt hydrotalcites as catalysts for bioethanol steam reforming. The promoting effect of potassium on catalyst activity and long-term stability. Appl Catal B 127:59
46. Sekine Y, Kazama A, Izutsu Y, Matsukata M, Kikuchi E (2009) Steam reforming of ethanol over cobalt catalysts modified with a small amount of iron. Catal Lett 132:329
47. Casanovas A, Roig M, de Leitenburg C, Trovarelli A, Llorca J (2010) Ethanol steam reforming and water gas shift over Co/ZnO catalytic honeycombs doped with Fe, Ni, Cu, Cr and Na. Int J Hydrog Energy 35:7690
48. 3 for steam reforming of ethanol. Appl Catal A 383:96
49. 3, and Fe- and Mn-promoted Co/ZnO catalysts. J Power Sources 169:158
50. Casanovas A, de Leitenburg C, Trovarelli A, Llorca J (2009) Ethanol steam reforming and water gas shift reaction over Co-Mn/ZnO catalysts. Chem Eng J 154:267
51. Domínguez M, Taboada E, Molins E, Llorca J (2012) Co-Fe-Si aerogel catalytic honeycombs for low temperature ethanol steam reforming. Catalysts 2:386
52. 3 catalysts: effect of addition of small quantities of noble metals. J Power Sources 175:482
53. Profeti LPR, Ticianelli EA, Assaf EM (2009) Ethanol steam reforming for production of hydrogen on magnesium aluminate-supported cobalt catalysts promoted by noble metals. Appl Catal A 360:17
54. Casanovas A, de Leitenburg C, Trovarelli A, Llorca J (2008) Catalytic monoliths for ethanol steam reforming. Catal Today 138:187
55. Casanovas A, Dominguez M, Ledesma C, Lopez E, Llorca J (2009) Catalytic walls and micro-devices for generating hydrogen by low temperature steam reforming of ethanol. Catal Today 143:32
56. Llorca J, Casanovas A, Trifonov T, Rodriguez A, Alcubilla R (2008) First use of macroporous silicon loaded with catalyst film for a chemical reaction: a microreformer for producing hydrogen from ethanol steam reforming. J Catal 255:228
57. López E, Irigoyen A, Trifonov T, Rodríguez A, Llorca J (2010) A million-channel reformer on a fingertip: moving down the scale in hydrogen production. Int J Hydrog Energy 35:3472
58. Domínguez M, Cristiano G, López E, Llorca J (2011) Ethanol steam reforming over cobalt talc in a plate microreactor. Chem Eng J 177:280
59. 2 catalysts. Catal Commun 3:565
60. Romero-Sarria F, Vargas JC, Roger AC, Kiennemann A (2008) Hydrogen production by steam reforming of ethanol. Catal Today 133-135:149-153
61. 2 catalyst. Appl Catal A 383:33
62. Llorca J, Ramírez de la Piscina P, Sales J, Homs N (2001) Direct production of hydrogen from ethanolic aqueous solutions over oxide catalysts. Chem Commun 641:642
63. 3 catalysts: effect of addition of small quantities of noble metals. J Power Sources 482:489
64. Nogués J, Schuller I (1999) Exchange bias. J Magn Magn Mater 192:203