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For details on the X-ray crystal structure determinations see the Supporting Information. CCDC-945709 (for γ-pyrone 12), -CCDC-945710 (for lactone 15), -CCDC-945711 (for iodo-ether 16) and -CCDC-945712 (for diiodide 17) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data-request/cif.
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