Direct electrochemistry and intramolecular electron transfer of ascorbate oxidase confined on l-cysteine self-assembled gold electrode

Bioelectrochemistry

Volumn 95, Issue , 2014, Pages 15-22

  Patil, Bhushan ^a,b   Kobayashi, Yoshiki ^a   Fujikawa, Shigenori ^b,c   Okajima, Takeyoshi ^a   Mao, Lanqun ^d   Ohsaka, Takeo ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

^b INST OF PHYS AND CHEMICAL RESEARCH   (Japan)

^c KYUSHU UNIVERSITY   (Japan)

^d INSTITUTE OF CHEMISTRY   (China)

Author keywords

Ascorbate oxidase; Cysteine; Direct electron transfer; Intramolecular electron transfer; Self assembled monolayer

Indexed keywords

ASCORBATE OXIDASE; CYSTEINE; DIRECT ELECTRON TRANSFER; ELECTRO-CATALYTIC OXIDATION; ELECTROCATALYTIC ACTIVITY; INTRA-MOLECULAR ELECTRON TRANSFER; PHOSPHATE BUFFER SOLUTIONS; THERMODYNAMICS AND KINETICS OF ADSORPTIONS;

AMINO ACIDS; ASCORBIC ACID; ELECTROCATALYSIS; ELECTROCHEMISTRY; GOLD; SELF ASSEMBLED MONOLAYERS;

ELECTRON TRANSITIONS;

ASCORBATE OXIDASE; ASCORBIC ACID; CYSTEINE; GOLD; OXYGEN; PHOSPHATE BUFFERED SALINE; POTASSIUM CHLORIDE; SELF ASSEMBLED MONOLAYER; SILVER CHLORIDE; SUPEROXIDE DISMUTASE;

ACREMONIUM; ADSORPTION KINETICS; ARTICLE; CATALYSIS; CYCLIC POTENTIOMETRY; ELECTROCHEMISTRY; ELECTRODE; ELECTRON TRANSPORT; ENZYME IMMOBILIZATION; OXIDATION; OXIDATION REDUCTION POTENTIAL; PH; PROTEIN PROTEIN INTERACTION; STATIC ELECTRICITY; SURFACE PROPERTY; THERMODYNAMICS;

AA; ANODIC CURRENT; APO FORM OF ASCORBATE OXIDASE FROM ACREMONIUM SP.; APO-ASOM; ASCORBATE OXIDASE; ASCORBIC ACID; AUE; C BULK AA; C SURF AA; C(ASOM); CONCENTRATION OF AA IN THE BULK SOLUTION; CONCENTRATION OF ASOM; CYSTEINE; DIRECT ELECTRON TRANSFER; GOLD ELECTRODE; I(A); INTRAMOLECULAR ELECTRON TRANSFER; LOCAL CONCENTRATION OF AA IN THE VICINITY OF THE ASOM CONFINED ON THE CYS-SAM/AUE; SATURATED SURFACE COVERAGE OF ASOM ON THE ELECTRODE SURFACE; SELF-ASSEMBLED MONOLAYER; SEMIDEHYDROASCORBATE RADICAL; SOD; SUPEROXIDE DISMUTASE; SURFACE COVERAGE OF ASOM ON THE ELECTRODE SURFACE; T1; T2; T3; TYPE 1 COPPER ACTIVE SITE IN THE ASOM; TYPE 2 COPPER ACTIVE SITE IN THE ASOM; TYPE 3 COPPER ACTIVE SITE IN THE ASOM; Γ(ASOM); Γ(S)(ASOM);

ACREMONIUM; ADSORPTION; ASCORBATE OXIDASE; BIOCATALYSIS; CYSTEINE; ELECTROCHEMISTRY; ELECTRODES; ELECTRON TRANSPORT; ENZYMES, IMMOBILIZED; GOLD; HYDROGEN-ION CONCENTRATION; KINETICS; THERMODYNAMICS;

EID: 84887145439     PISSN: 15675394     EISSN: 1878562X     Source Type: Journal    
DOI: 10.1016/j.bioelechem.2013.10.005     Document Type: Article

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