Adsorptive removal of cadmium and copper from water by mesoporous silica functionalized with N-(aminothioxomethyl)-2-thiophen carboxamide

Journal of Environmental Engineering (United States)

Volumn 139, Issue 10, 2013, Pages 1285-1296

  Georgescu, Irina ^a   Mureşeanu, Mihaela ^b   Cârjǎ, Gabriela ^a   Hulea, Vasile ^c  

^a GHEORGHE ASACHI TECHNICAL UNIVERSITY OF IASI   (Romania)

^b UNIVERSITY OF CRAIOVA   (Romania)

^c CNRS   (France)

Author keywords

Adsorption; Cadmium; Copper; Multifunctional ligand; Organic inorganic hybrid material; SBA 15

Indexed keywords

CHARACTERIZATION TECHNIQUES; COMPLEXATION MECHANISMS; FOURIER TRANSFORM INFRA REDS; NITROGEN ADSORPTION-DESORPTION; NUCLEAR MAGNETIC RESONANCE(NMR); ORGANIC-INORGANIC HYBRID MATERIALS; SBA-15; WASTEWATER PURIFICATION;

ADSORPTION; CADMIUM; CADMIUM COMPOUNDS; CHEMICAL MODIFICATION; COPPER; FOURIER TRANSFORM INFRARED SPECTROSCOPY; GAS ADSORPTION; HYBRID MATERIALS; LIGANDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POSITIVE IONS; THERMOGRAVIMETRIC ANALYSIS; WATER POLLUTION; X RAY DIFFRACTION;

CHEMICALS REMOVAL (WATER TREATMENT);

ADSORPTION; AQUEOUS SOLUTION; CADMIUM; CATION; COPPER; LIGAND; POLLUTANT REMOVAL; PURIFICATION; SEWAGE TREATMENT; SILICA; THERMOGRAVIMETRY;

EID: 84884658893     PISSN: 07339372     EISSN: None     Source Type: Journal    
DOI: 10.1061/(ASCE)EE.1943-7870.0000742     Document Type: Article

References (72)

1. Abdel-Fattah, T. M., Haggag, S. M. S., and, Mahmoud, M. E. (2011). " Heavy metal ions extraction from aqueous media using nanoporous silica." Chem. Eng. J., 175, 117-123. CMEJAJ 1385-8947 10.1016/j.cej.2011.09.068
2. Aguado, J., Arsuaga, J. M., Arencibia, A., Lindo, M., and, Gascon, V. (2009). " Aqueous heavy metals removal by adsorption on aminefunctionalized mesoporous silica." J. Hazard. Mater., 163 (1), 213-221. JHMAD9 0304-3894 10.1016/j.jhazmat.2008.06.080
3. Airoldi, C. (2008). " A relevante potencialidade dos centros básicos nitrogenado sponíveis em polímeros inorgânicos e biopolímeros na remoção catiônica." Quim. Nova, 31 (1), 144-153. QUNODK 0100-4042 10.1590/S0100-40422008000100026
4. Albert, K., and, Bayer, E. (1991). " Characterization of bonded phases by solid-state NMR spectroscopy." J. Chromatogr. A, 544, 345-370. JCRAEY 0021-9673 10.1016/S0021-9673(01)83995-9
5. Alothman, Z. A., and, Apblett, A. W. (2009). " Preparation of mesoporous silica with grafted chelating agents for uptake of metal ions." Chem. Eng. J., 155 (3), 916-924. CMEJAJ 1385-8947 10.1016/j.cej.2009.09.028
6. Antochshuk, V., and, Jaroniec, M. (2002). " 1-Allyl-3-propylthiourea modified mesoporous silica for mercury removal." Chem. Commun., 2 (3), 258-259. CHCOFS 1364-548X 10.1039/b108789d
7. Carcu, V., Negoiu, M., Rosu, T., and, Serban, S. (2000). " Synthesis, characterization of complexes of N-benzoyl-N'-2-nitro-4-methoxy phenylthiourea with Cu, Ni, Pt, Pd, Cd and Hg." J. Therm. Anal. Calorim., 61 (3), 935-945. JTACF7 1418-2874 10.1023/A:1010163012703
8. Carter, T. G., Yantasee, W., Sangvanich, T., Fryxell, G. E., Johnson, D. W., and, Addleman, R. S. (2008). " New functional materials for heavy metal sorption: 'Supramolecular' attachment of thiols to mesoporous silica substrates." Chem. Commun., (43), 5583-5585.
9. ÇItak, A., Erdem, B., Erdem, S., and, Öksüzoǧlu, R. M. (2012). " Synthesis, characterization and catalytic behavior of functionalized mesoporous SBA-15 with various organo-silanes." J Colloid Interf. Sci., 369 (1), 160-163. 0021-9797 10.1016/j.jcis.2011.11.070
10. Chen, H. T., Trewyn, B. G., Wiench, J. W., Pruski, M., and, Lin, V. S. Y. (2010). " Urea and thiourea-functionalized mesoporous silica nanoparticle catalysts with enhanced catalytic activity for Diels-Alder reaction." Top. Catal., 53 (3-4), 187-191. TOCAFI 1022-5528 10.1007/s11244-009-9423-x
11. Da'na, E., and, Sayari, A. (2012). " Adsorption of heavy metals on amine-functionalized SBA-15 prepared by co-condensation: Applications to real water samples." Desalination, 285, 62-67. DSLNAH 0011-9164 10.1016/j.desal.2011.09.034
12. Dey, R. K., Patnai, T., Singh, V. K., Swain, S. K., de Melo, M. A., Jr., and, Airoldi, C. (2010). " Al-centered functionalized inorganic-organic hybrid sorbent containing N and S donor atoms for effective removal of cadmium." Solid State Sci., 12 (4), 440-447. SSSCFJ 1293-2558 10.1016/j.solidstatesciences.2009.12.005
13. Do, D. D. (1998). Adsorption analysis: Equilibrium and kinetics, Imperial College Press, London.
14. Edzwald, J. K. (1993). " Coagulation in drinking water treatment: Particles, organics and coagulants." Water Sci. Technol., 27 (11), 21-35. WSTED4 0273-1223
15. Estevez-Hernandez, O., Otazo-Sanchez, E., Hidalgo-Hidalgo de Cisneros, J. L., Naranjo-Rodriguez, I., and, Reguera, E. (2005). " A Raman and infrared study of 1-furoyl-3-monosubstituted and 3,3-disubstituted thioureas." Spectrochim. Acta, Part A, 62 (4-5), 964-971. SAMCAS 1386-1425 10.1016/j.saa.2005.04.016
16. Estevez-Hernandez, O., Otazo-Sanchez, E., Hidalgo-Hidalgo de Cisneros, J. L., Naranjo-Rodriguez, I., and, Reguera, E. (2006). " Novel CdCl 2 and HgCl 2 complexes with 3-monosubstituted and 3,3-disubstituted 1-furoylthioureas: IR and Raman spectra." Spectrochim. Acta, Part A, 64 (4), 961-971. SAMCAS 1386-1425 10.1016/j.saa.2005.09.005
17. Gambino, D., Kremer, E., and, Baran, E. J. (2002). " Infrared spectra of new Re(III) complexes with thiourea derivatives." Spectrochim. Acta Part A, 58 (14), 3085-3092. SAMCAS 1386-1425 10.1016/S1386-1425(02)00106-3
18. Gao, B., Gao, Y., and, Li, Y. (2010). " Preparation and chelation adsorption property of composite chelating material poly(amidoxime)/ SiO 2 towards heavy metal ions." Chem. Eng. J. 158 (3), 542-549. CMEJAJ 1385-8947
19. Gao, Z., Wang, L., Qi, T., Chu, J., and, Zhang, Y. (2007). " Synthesis, characterization, and cadmium(II) uptake of iminodiacetic acid-modified mesoporous SBA-15." Colloids Surf., A, 304 (1), 77-81. CPEAEH 0927-7757 10.1016/j.colsurfa.2007.04.045
20. Grigoropoulou, G., Stathi, P., Karakassides, M. A., Louloudi, M., and, Deligiannakis, Y. (2008). " Functionalized SiO 2 with N-, S-containing ligands for Pb(II) and Cd(II) adsorption." Colloids Surf., A, 320 (1-3), 25-35. CPEAEH 0927-7757 10.1016/j.colsurfa.2008.01.007
21. Hajiaghababaei, L., Badiei, A., Ganjali, M. R., Heydari, S., Khaniani, Y., and, Ziarani, G. M. (2011). " Highly efficient removal and preconcentration of lead and cadmium cations from water and wastewater samples using ethylenediamine functionalized SBA-15." Desalination, 266 (1-3), 182-187. DSLNAH 0011-9164 10.1016/j.desal.2010.08.024
22. Ho, Y. S. (2004). " Citiation review of Lagergren kinetic rate equation on adsorption reactions." Scientometrics, 59 (1), 171-177. SCNTDX 0138-9130
23. Ho, Y. S., and, McKay, G. (1999). " Pseudo-second order model for sorption processes." Process Biochem., 34 (5), 451-465. PRBCAP 0032-9592 10.1016/S0032-9592(98)00112-5
24. Hongjie, W., Jin, K., Huijuan, L., and, Jiuhui, Q. (2009). " Preparation of organically functionalized silica gel as adsorbent for copper ion adsorption." J. Environ. Sci., 21 (11), 1473-1479. 0022-0906 10.1016/S1001-0742(08)62442-0
25. Irving, H., and, Williams, R. J. P. (1948). " Order of stability of metal complexes." Nature, 162 (4123), 746-747. NATUAS 0028-0836 10.1038/162746a0
26. Jal, P. K., Patel, S., and, Mishra, B. K. (2004). " Chemical modification of silica surface by immobilization of functional groups for extractive concentration of metal ions." Talanta, 62 (5), 1005-1028. TLNTA2 0039-9140 10.1016/j.talanta.2003.10.028
27. Jiang, Y., Gao, Q., Yu, H., Chen, Y., and, Deng, F. (2007). " Intensively competitive adsorption for heavy metal ions by PAMAM-SBA-15 and EDTA-PAMAM-SBA-15 inorganic-organic hybrid materials." Microporous Mesoporous Mater., 103 (1-3), 316-324. MIMMFJ 1387-1811 10.1016/j.micromeso. 2007.02.024
28. Kang, T., Park, Y., and, Yi, J. (2004). " Highly selective adsorption of Pt 2 + and Pd 2 + using thiol-functionalized mesoporous silica." Ind. Eng. Chem. Res., 43 (6), 1478-1484. IECRED 0888-5885 10.1021/ie030590k
29. Khodakov, A. Y., Zholobenko, V. L., Bechara, R., and, Durand, D. (2005). " Impact of aqueous impregnation on the long-range ordering and mesoporous structure of cobalt containing MCM-41 and SBA-15 materials." Microporous Mesoporous Mater., 79 (1-3), 29-39. MIMMFJ 1387-1811 10.1016/j.micromeso.2004. 10.013
30. Koch, K. R. (2001). " New chemistry with old ligands: N-alkyl- and N,N-dialkyl-N'-acyl(aroyl)thioureas in co-ordination, analytical and process chemistry of the platinum group metals." Coord. Chem. Rev., 216-217, 473-488. CCHRAM 0010-8545 10.1016/S0010-8545(01)00337-X
31. Kosuge, K., and, Singh, P. S. (2001). " Rapid synthesis of Al-containing mesoporous silica hard spheres of 30-50 μm diameter." Chem. Mater., 13 (8), 2476-2482. CMATEX 0897-4756 10.1021/cm000623b
32. Kresge, C. T., Leonowicz, M. E., Roth, W. J., Vartuli, J. C., and, Beck, J. S. (1992). " Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism." Nature, 359 (6397), 710-712. NATUAS 0028-0836 10.1038/359710a0
33. Kurniawan, T. A., Chan, G. Y. S., Lo, W.-H., and, Babel, S. (2006). " Physico-chemical treatment techniques for wastewater laden with heavy metals." Chem. Eng. J., 118 (1-2), 83-98. CMEJAJ 1385-8947 10.1016/j.cej.2006.01.015
34. Lam, K. F., Ho, K. Y., Yeung, K. L., McKaya, G. (2004). " Selective adsorbents from chemically modified ordered mesoporous silica." Stud. Surf. Sci. Catal., 154 (A-C), 2981-2986. SSCTDM 0167-2991 10.1016/S0167-2991(04) 80581-0
35. Maroneze, C. M., Magosso, H. A., Panteleimonov, A. V., Kholin, Y. V., and, Gushikem, Y. (2011). " Surface functionalization of SBA-15 and a nonordered mesoporous silica with a 1,4-diazabicyclo[2.2.2]octane derivative: Study of CuCl2 adsorption from ethanol solution." J. Colloid Interf. Sci., 356 (1), 248-256.
36. Melde, B. J., Johnson, B. J., and, Charles, P. T. (2008). " Mesoporous silicate materials in sensing." Sensors, 8 (8), 5202-5228. SNSRES 0746-9462 10.3390/s8085202
37. Mozolis, V. V., and, Iokubaitite, S. P. (1973). " Preparation of N-substituted thiourea." Russ. Chem. Rev., 42 (7), 587-595. RCRVAB 0036-021X 10.1070/RC1973v042n07ABEH002677
38. Mureseanu, M., Reiss, A., Cioatera, N., Trandafir, I., and, Hulea, V. (2010). " Mesoporous silica functionalized with 1-furoyl thiourea urea for Hg(II) adsorption from aqueous media." J. Hazard. Mater., 182 (1-3), 197-203. JHMAD9 0304-3894 10.1016/j.jhazmat.2010.06.015
39. Mureseanu, M., et al. (2008). " Modified SBA-15 mesoporous silica for heavy metal ions remediation." Chemosphere, 73 (9), 1499-1504. CMSHAF 0045-6535 10.1016/j.chemosphere.2008.07.039
40. Ngeontae, W., Aeungmaitrepirom, W., and, Tuntulani, T. (2007). " Chemically modified silica gel with aminothioamidoanthraquinone for solid phase extraction and preconcentration of Pb(II), Cu(II), Ni(II), Co(II) and Cd(II)." Talanta, 71 (3), 1075-1082. TLNTA2 0039-9140 10.1016/j.talanta. 2006.05.094
41. Nriagu, J. O., and, Pacyna, J. M. (1998). " Quantitative assessment of worldwide contamination of air, water and soil by trace metals." Nature, 333 (6169), 134-139. NATUAS 0028-0836
42. Oliveira, F. J. V. E., da Silva Filho, E. C., Melo, M. A., Jr., and, Airoldi, C. (2009). " Modified coupling agents besed on thiourea, immobilized onto silica. Thermodynamics of copper adsorption." Surf. Sci., 603 (14), 2200-2206. SUSCAS 0039-6028 10.1016/j.susc.2009.04.020
43. Olkhovyk, O., Antochshuk, V., and, Jaroniec, M. (2004). " Benzoylthiorea-modified MCM-48 mesoporous silica for mercury(II) adsorption from aqueous solutions." Colloids Surf., A, 236 (1-3), 69-72. CPEAEH 0927-7757 10.1016/j.colsurfa.2003.12.032
44. Pavia, D. L., Lampmam, G. M., and, Kriz, G. S. (2001). Introduction to spectroscopy, Harcourt College Publishers, New York.
45. Pearson, R. G. (1963). " Hard and soft acids and bases." J. Am. Chem. Soc., 85 (22), 3533-3539. JACSAT 0002-7863 10.1021/ja00905a001
46. Pérez-Quintanilla, D., del Hierro, I., Fajardo, M., and, Sierra, I. (2006 a). " Adsorption of cadmium(II) from aqueous media onto a mesoporous silica chemically modified with 2-mercaptopyrimidine." J. Mater. Chem., 16 (18), 1757-1764. JMACEP 0959-9428 10.1039/b518157g
47. Pérez-Quintanilla, D., del Hierro, I., Fajardo, M., and, Sierra, I. (2006 b). " Mesoporous silica functionalized with 2-mercaptopyridine: Synthesis, characterization and employment for Hg(II) adsorption." Microporous Mesoporous Mater., 89 (1-3), 58-68. MIMMFJ 1387-1811 10.1016/j.micromeso.2005.10.012
48. Pérez-Quintanilla, D., Sánchez, A., del Hierro, I., Fajardo, M., and, Sierra, I. (2009). " Preconcentration of Zn(II) in water samples using a new hybrid SBA-15 based material." J. Hazard. Mater., 166 (2-3), 1449-1458. JHMAD9 0304-3894 10.1016/j.jhazmat.2008.12.065
49. Perrin, D. D., Armaredo, W. L., Perrin, D. R. (1980). Purification of laboratory chemicals, 2nd Ed., Pergamon Press, Oxford, UK.
50. Phillips, R. J., and, Fritz, J. S. (1982). " Extraction of metal ions by N-phenyl-, N-methyl-, and N-unsubstituted hydroxamic acid resins." Anal. Chim. Acta, 139, 237-246. ACACAM 0003-2670 10.1016/S0003-2670(01)94001-2
51. Prado, A. G. S., Arakaki, L. N. H., and, Airoldi, C. (2002). " Adsorption and separation of cations on silica gel chemically modified by homogeneous and heterogeneous routes with the ethylenimine anchored on thiol modified silica gel." Green Chem., 4 (1), 42-46.
52. Puglisi, A., et al. (2009). " Hybrid inorganic-organic materials carrying tertiary amine and thiourea residues tethered on mesoporous silica nanoparticles: synthesis, characterization, and co-operative catalysis." Adv. Synth. Catal., 351 (1-2), 219-229.
53. Qdais, H. A., and, Moussa, H. (2004). " Removal of heavy metals from wastewater by membrane processes: A comparative study." Desalination, 164 (2), 105-110. DSLNAH 0011-9164 10.1016/S0011-9164(04)00169-9
54. Sales, J. A. A., Prado, A. G. S., and, Airoldi, C. (2002). " The incorporation of propane-1,3-diamine into silylant epoxide group through homogeneous and heterogeneous routes." Polyhedron, 21 (25-26), 2647-2651. PLYHDE 0277-5387 10.1016/S0277-5387(02)01253-6
55. Sanchez, C., Boissierè, C., Grosso, D., Laberty, C., and, Nicole, L. (2008). " Design, synthesis, and properties of inorganic and hybrid thin films having periodically organized nanoporosity." Chem. Mater., 20 (3), 682-737. CMATEX 0897-4756 10.1021/cm702100t
56. Shahbazi, A., Younesi, H., and, Badiei, A. (2011). " Functionalized SBA-15 mesoporous silica by melamine-based dendrimer amines for adsorptive characteristics of Pb(II), Cu(II) and Cd(II) heavy metal ions in batch and fixed bed column." Chem. Eng. J., 168 (2), 505-518. CMEJAJ 1385-8947 10.1016/j.cej.2010.11.053
57. Vasiliev, A. N., Golovko, L. V., Trachevsky, V. V., Hall, G. S., and, Khinast, J. G. (2009). " Adsorption of heavy metal cations by organic ligands grafted on porous materials." Microporous Mesoporous Mater., 118 (1-3), 251-257. MIMMFJ 1387-1811 10.1016/j.micromeso.2008.08.026
58. Vilar, V. J. P., Botelho, C. M. S., and, Boaventura, R. A. R. (2006). " Equilibrium and kinetic modeling of Cd(II) biosorption by algae Gelidium and agar extraction algal waste." Water Res., 40 (2), 291-302. WATRAG 0043-1354 10.1016/j.watres.2005.11.008
59. Walcarius, A., and, Mercier, L. (2010). " Mesoporous organosilica adsorbents: Nanoengineered materials for removal of organic and inorganic pollutants." J. Mater. Chem., 20 (22), 4478-4511. JMACEP 0959-9428 10.1039/b924316j
60. Wu, Z., and, Zhao, D. (2011). " Ordered mesoporous materials as adsorbents." Chem. Commun., 47 (12), 3332-3338. 1364-548X 10.1039/c0cc04909c
61. Xie, F., Lin, X., Wu, X., and, Xie, Z. (2008). " Solid phase extraction of lead (II), copper (II), cadmium (II) and nickel (II) using gallic acid-modified silica gel prior to determination by flame atomic absorption spectrometry." Talanta, 74 (4), 836-843. TLNTA2 0039-9140 10.1016/j.talanta.2007.07.018
62. Xue, X., and, Li, F. (2008). " Removal of Cu(II) from aqueous solution by adsorption onto functionalized SBA-16 mesoporous silica." Microporous Mesoporous Mater., 116 (1-3), 116-122. MIMMFJ 1387-1811 10.1016/j.micromeso.2008.03.023
63. Yang, H., Xu, R., Xue, X., Li, F., and, Li, G. (2008). " Hybrid surfactant-templated mesoporous silica formed in ethanol and its application for heavy metal removal." J. Hazard. Mater., 152 (2), 690-698. JHMAD9 0304-3894 10.1016/j.jhazmat.2007.07.060
64. Yokoi, T., Kubota, Y., and, Tatsumi, T. (2012). " Amino-functionalized mesoporous silica as base catalyst and adsorbent." Appl. Catal. Part A, 421-422, 14-37. ACAGE4 0926-860X 10.1016/j.apcata.2012.02. 004
65. Yu, J.-X., Wang, L.-Y., Chi, R.-A., Zhang, Y.-F., Xu, Z.-G., and, Guo, J. (2013). " Competitive adsorption of Pb 2 + and Cd 2 + on magnetic modified sugarcane bagasse prepared by two simple steps." Appl. Surf. Sci., 268, 163-170. ASUSEE 0169-4332 10.1016/j.apsusc.2012.12.047
66. Yu, P., He, J., and, Guo, C. X. (2008 a). " 9-thiourea cinchona alkaloid supported on mesoporous silica as a hughly enantioselective, recyclable heterogeneous asymmetric catalyst." Chem. Commun., (20), 2355-2357.
67. Yu, P., He, J., Yang, L., Pu, M., and, Guo, X. (2008 b). " Stepwise fabrication and architecture of heterogeneous 9-thiourea epiquinine catalysts with excellent enentioselectivity in the asymmetric Friedel-Crafts reaction of indoles with imines." J. Catal., 260 (1), 81-85. JCTLA5 0021-9517 10.1016/j.jcat.2008.09.006
68. Zhad, H. R. L. Z., Sadeghi, O., Amini, M. M., Tavassoli, N., Banitaba, M. H., and, Davarani, S. S. H. (2011). " Extraction of ultra trace amounts of palladium on 9-acridinylamine functionalized SBA-15 and MCM-41 nanoporous silica sorbents." Sep. Sci. Technol., 46 (4), 648-655. SSTEDS 1520-5754 10.1080/01496395.2010.528501
69. Zhang, L., Goh, S., Hu, X., Crawford, R., and, Yu, A. (2012). " Removal of aqueous toxic Hg(II) by functionalized mesoporous silica materials." J. Chem. Technol. Biotechnol., 87 (10), 1473. JCTBDC 1097-4660 10.1002/jctb.v87.10
70. Zhao, D., Huo, Q., Feng, J., Chmelka, B. F., and, Stucky, G. D. (1998 a). " Nonionic triblock and star diblock copolymer and oligomeric surfactant syntheses of highly ordered, hydrothermally stable, mesoporous silica structures." J. Am. Chem. Soc., 120 (24), 6024-6036. JACSAT 0002-7863 10.1021/ja974025i
71. Zhao, D., et al. (1998 b). " Triblock copolymer synthesis of mesoporous silica with periodic 50 to 300 angstrom pores." Science, 279 (5350), 548-552. SCIEAS 0036-8075 10.1126/science.279.5350.548
72. Zhao, Y., Gao, Q., Tang, T., Xu, Y., and, Wu, D. (2011). " Effective NH 2 -grafting on mesoporous SBA-15 surface for adsorption of heavy metal ions." Mater. Lett., 65 (6), 1045-1047. MLETDJ 0167-577X 10.1016/j.matlet.2010.12.047