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J. S. Beck J. C. Vartuli W. J. Roth M. E. Leonowicz C. T. Kresge K. D. Schmitt C. T.-W. Chu D. H. Olson E. W. Sheppard S. B. McCullen J. B. Higgins J. L. Schlenker J. Am. Chem. Soc. 1992 114 10834 10842
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19
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55849117614
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MCM-41 was first dispersed in toluene by stirring. Water was added, resulting in immediate flocculation of the silica followed by dispersal over 2-3 h of stirring. Trichlorophenylsilane was then added and stirred overnight. The resulting solution was translucent in appearance. Isopropyl alcohol (IPA) was added and the solid filtered, washed with IPA and vacuum dried in an oven at 40 °C
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MCM-41 was first dispersed in toluene by stirring. Water was added, resulting in immediate flocculation of the silica followed by dispersal over 2-3 h of stirring. Trichlorophenylsilane was then added and stirred overnight. The resulting solution was translucent in appearance. Isopropyl alcohol (IPA) was added and the solid filtered, washed with IPA and vacuum dried in an oven at 40 °C
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21
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55849083436
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-1 up to 600 °C and capillary temperature of 100 °C
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-1 up to 600 °C and capillary temperature of 100 °C
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22
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55849116613
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Phenyl-SAMMS was added to a solution of BM, 1,3-BMMB or 1,4-BMMB dissolved in dichloromethane in a sealed vessel, placed on an orbital shaker and mixed overnight. After mixing, the vessel was uncapped and the solvent was evaporated followed by overnight vacuum drying at 40 °C. Chemisorbed ligand loadings are equal to either 2: 1 or 1: 1 phenyl moieties of the functionalized silica to BMMB molecules and are designated as low or high loading, respectively
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Phenyl-SAMMS was added to a solution of BM, 1,3-BMMB or 1,4-BMMB dissolved in dichloromethane in a sealed vessel, placed on an orbital shaker and mixed overnight. After mixing, the vessel was uncapped and the solvent was evaporated followed by overnight vacuum drying at 40 °C. Chemisorbed ligand loadings are equal to either 2: 1 or 1: 1 phenyl moieties of the functionalized silica to BMMB molecules and are designated as low or high loading, respectively
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-
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23
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55849121445
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Degradation and oxidation of 1,4-BMMB occurred due to trace levels of oxygen contamination present in the TGA purge gas resulting in the observation of a large carbon dioxide peak
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Degradation and oxidation of 1,4-BMMB occurred due to trace levels of oxygen contamination present in the TGA purge gas resulting in the observation of a large carbon dioxide peak
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-
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25
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55849138942
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-1 (metal ion to sorbent), which is typically used under saturation conditions
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-1 (metal ion to sorbent), which is typically used under saturation conditions
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-
-
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26
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55849115896
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All analyses performed in either duplicate or triplicate with variances greater than 10% discarded
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All analyses performed in either duplicate or triplicate with variances greater than 10% discarded
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