Mercury isotope fractionation during ore retorting in the Almadén mining district, Spain

Chemical Geology

Volumn 357, Issue , 2013, Pages 150-157

  Gray, John E ^a   Pribil, Michael J ^a   Higueras, Pablo L ^b  

^a DENVER FEDERAL CENTER   (United States)

^b UNIVERSITY OF CASTILLA LA MANCHA   (Spain)

Author keywords

Cinnabar ore; Mass dependent fractionation; Mercury isotopes; Mine waste calcine; Retorting

Indexed keywords

ISOTOPE FRACTIONATION; ISOTOPIC COMPOSITION; ISOTOPIC FRACTIONATIONS; MASS-INDEPENDENT FRACTIONATION; MERCURIES (HG); MINE WASTES; MINING DISTRICT; RETORTING;

EXPERIMENTS; ISOTOPES; MERCURY (METAL);

ORES;

CINNABAR; EXPERIMENTAL STUDY; GEOCHEMISTRY; ISOTOPIC FRACTIONATION; MERCURY (ELEMENT); MINE WASTE; MINING; ORE DEPOSIT;

ALMADEN; CASTILLA-LA MANCHA; CIUDAD REAL [CASTILLA-LA MANCHA]; SPAIN;

EID: 84884250188     PISSN: 00092541     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.chemgeo.2013.08.036     Document Type: Article

References (59)

1. Bailey E.A., Gray J.E., Theodorakos P.M. Mercury in vegetation and soils at abandoned mercury mines in southwestern Alaska, USA. Geochem. Explor. Environ. Anal. 2002, 2(3):275-285.
2. Bergquist B.A., Blum J.D. The odds and evens of mercury isotopes: applications of mass-dependent and mass-independent isotope fractionation. Elements 2009, 5(6):353-357.
3. Bernaus A., Gaona X., Esbrí J.M., Higueras P., Falkenberg G., Valiente M. Microprobe techniques for speciation analysis and geochemical characterization of mine environments: the mercury district of Almadén in Spain. Environ. Sci. Technol. 2006, 40:4090-4095.
4. Berzas Nevado J.J., Garcia Bermejo L.F., Rodriguez Martin-Doimeadios R.C. Distribution of mercury in the aquatic environment at Almadén, Spain. Environ. Pollut. 2003, 122:261-271.
5. Biswas A., Blum J.D., Bergquist B.A., Keeler G.J., Xie Z. Natural mercury isotope variation in coal deposits and organic soils. Environ. Sci. Technol. 2008, 42:8303-8309.
6. Blum J.D., Bergquist B.A. Reporting of variations in the natural isotopic composition of mercury. Anal. Bioanal. Chem. 2007, 388(2):353-359.
7. Carignan J., Estrade N., Sonke J.E., Donard O.F.X. Odd isotope deficits in atmospheric Hg measured in lichens. Environ. Sci. Technol. 2009, 43:5660-5664.
8. Das R., Bizimis M., Wilson A.M. Tracing mercury seawater vs. atmospheric inputs in a pristine SE USA salt marsh system: mercury isotope evidence. Chem. Geol. 2013, 336:50-61.
9. Esbrí J.M., Bernaus A., Ávila M., Kocman D., García-Noguero E.M., Guerrero B., Gaona X., Álvarez R., Perez-Gonzalez G., Valiente M., Higueras P., Horvat M., Loredo J. XANES speciation of mercury in three mining districts - Almadén, Asturias (Spain), Idria (Slovenia). J. Synchrotron Radiat. 2010, 17:179-186.
10. Estrade N., Carignan J., Sonke J.E., Donard O.F.X. Measuring Hg isotopes in bio-geo-environmental reference materials. Geostand. Geoanal. Res. 2009, 34:79-83.
11. Estrade N., Carignan J., Sonke J.E., Donard O.F.X. Mercury isotope fractionation during liquid-vapor evaporation experiments. Geochim. Cosmochim. Acta 2009, 73:2693-2711.
12. Feng X., Qiu G. Mercury pollution in Guizhou, Southwestern China - an overview. Sci. Total. Environ. 2008, 400:227-237.
13. Ferrara R., Maserti B.E., Andersson M., Edner H., Ragnarson P., Svanberg S., Hernandez A. Atmospheric mercury concentrations and fluxes in the Almadén district (Spain). Atmos. Environ. 1998, 32(22):3897-3904.
14. Fitzgerald W.F., Engstrom D.R., Mason R.P., Nater E.A. The case for atmospheric mercury contamination in remote areas. Crit. Rev. Environ. Sci. Technol. 1998, 32(1):1-7.
15. Foucher D., Hintelmann H. High-precision measurement of mercury isotope ratios in sediments using cold-vapor generation multi-collector inductively coupled plasma mass spectrometry. Anal. Bioanal. Chem. 2006, 384:1470-1478.
16. García-Sánchez A., Murciego A., Álvarez-Ayuso E., Regina I.S., Rodríguez-González M.A. Mercury in soils and plants in an abandoned cinnabar mining area (SW Spain). J. Hazard. Mater. 2009, 168:1319-1324.
17. Gehrke G.E., Blum J.D., Marvin DiPasquale M. Sources of mercury to San Francisco Bay surface sediment as revealed by mercury stable isotopes. Geochim. Cosmochim. Acta 2011, 75:691-705.
18. Ghosh S., Xu Y., Humayun M., Odom L. Mass-independent fractionation of mercury isotopes in the environment. Geochem. Geophys. Geosyst. 2008, 9(3):Q03004. 10.1029/2007GC001827.
19. Ghosh S., Schauble E.A., Lacrampe Couloume G., Blum J.D., Bergquist B.A. Estimation of nuclear volume dependent fractionation of mercury isotopes in equilibrium liquid-vapor evaporation experiments. Chem. Geol. 2013, 336:5-12.
20. Gosar M., Pirc S., Bidovec M. Mercury in the Idrijca River sediments as a reflection of mining and smelting activities of the Idrija mercury mine. J. Geochem. Explor. 1997, 58:125-131.
21. Gosar M., Šajn R., Biester H. Binding of mercury in soils and attic dust in the Idrija mercury mine area (Slovenia). Sci. Total. Environ. 2006, 369:150-162.
22. Gratz L.E., Keeler G.J., Blum J.D., Sherman L.S. Isotopic composition and fractionation of mercury in Great Lakes precipitation and ambient air. Environ. Sci. Technol. 2010, 44(20):7764-7770.
23. Gray J.E., Theodorakos P.M., Bailey E.A., Turner R.R. Distribution, speciation, and transport of mercury in stream-sediment, stream-water, and fish collected near abandoned mercury mines in southwestern Alaska, USA. Sci. Total. Environ. 2000, 260(1-3):21-33.
24. Gray J.E., Greaves I.A., Bustos D.M., Krabbenhoft D.P. Mercury and methylmercury contents in mine-waste calcine, water, and sediment collected from the Palawan Quicksilver Mine, Philippines. Environ. Geol. 2003, 43:298-307.
25. Gray J.E., Hines M.E., Higueras P.L., Adatto I., Lasorsa B.K. Mercury speciation and microbial transformations in mine wastes, stream sediments, and surface waters at the Almadén mining district, Spain. Environ. Sci. Technol. 2004, 38(16):4285-4292.
26. Gray J.E., Plumlee G.S., Morman S.A., Higueras P.L., Crock J.G., Lowers H.A., Witten M.L. In vitro studies evaluating leaching of mercury from mine waste calcine using simulated human body fluids. Environ. Sci. Technol. 2010, 44:4782-4788.
27. Gray J.E., Pribil M.J., Van Metre P.C., Borrok D.M., Thapalia A. Identification of contamination in a lake sediment core using Hg and Pb isotopic compositions, Lake Ballinger, Washington, USA. Appl. Geochem. 2013, 29:1-12.
28. Hernandez A., Jebrak M., Higueras P., Oyarzun R., Morata D., Munha J. The Almadén mercury mining district, Spain. Miner. Deposita 1999, 34:539-548.
29. Higueras P., Oyarzun R., Lunar R., Sierra J., Parras J. The Las Cuevas deposit, Almadén district (Spain): an unusual case of deep-seated advanced argillic alteration related to mercury mineralization. Miner. Deposita 1999, 34(2):211-214.
30. Higueras P., Oyarzun R., Biester H., Lillo J., Lorenzo S. A first insight into mercury distribution and speciation in soils from the Almadén mining district, Spain. J. Geochem. Explor. 2003, 80:95-104.
31. Higueras P., Oyarzun R., Lillo J., Sánchez-Hernández J.C., Molina J.A., Esbrí J.M., Lorenzo S. The Almadén district (Spain): anatomy of one of the world's largest Hg-contaminated sites. Sci. Total. Environ. 2006, 236(1-3):112-124.
32. Higueras P., Esbrí J.M., Oyarzun R., Llanos W., Martínez-Coronado A., Lillo J., López-Berdonces M.A., García-Noguero E.M. Industrial and natural sources of gaseous elemental mercury in the Almadén district (Spain): an updated report on this issue after the ceasing of mining and metallurgical activities in 2003 and major land reclamation works. Environ. Res. 2013, 125:197-208.
33. Hintelmann H., Lu S.Y. High precision isotopic ratio measurements of mercury isotopes in cinnabar ores using multi-collector inductively coupled plasma mass spectrometry. Analyst 2003, 128:635-639.
34. Hudson R.J.M., Gherini S.A., Fitzgerald W.F., Porcella D.B. Anthropogenic influences on the global mercury cycle: a model-based analysis. Water Air Soil Pollut. 1995, 80:265-272.
35. Kim C.S., Brown G.E., Rytuba J.J. Characterization and speciation of mercury-bearing mine wastes using X-ray absorption spectroscopy. Sci. Total. Environ. 2000, 261:157-168.
36. Kim C.S., Bloom N.S., Rytuba J.J., Brown G.E. Mercury speciation by X-ray absorption fine structure spectroscopy and sequential chemical extractions: a comparison of speciation methods. Environ. Sci. Technol. 2003, 37(22):5102-5108.
37. Kocman D., Horvat M., Pirrone N., Cinnirella S. Contribution of contaminated sites to the global mercury budget. Environ. Res. 2013, 125:160-170.
38. Lamborg C.H., Fitzgerald W.F., O'Donnell J., Torgersen T. A non-steady-state compartmental model of global-scale mercury biogeochemistry with interhemispheric atmospheric gradients. Geochim. Cosmochim. Acta 2002, 66:1105-1118.
39. Lin Y., Larssen T., Vogt R.D., Feng X. Identification of fractions of mercury in water, soil and sediment from a typical Hg mining area in Wanshan, Guizhou province, China. Appl. Geochem. 2010, 25:60-68.
40. Llanos W., Kocman D., Higueras P., Horvat M. Mercury emission and dispersion models from soils contaminated by cinnabar mining and metallurgy. J. Environ. Monit. 2011, 13:3460-3468.
41. Martínez-Coronado A., Oyarzun R., Esbrí J.M., Llanos W., Higueras P. Sampling high to extremely high Hg concentrations at the Cerco de Almadenejos, Almadén mining district (Spain): the old metallurgical precinct (1794 to 1861AD) and surrounding areas. J. Geochem. Explor. 2011, 109:70-77.
42. Mason R.P., Fitzgerald W.F., Morel F.M.M. The biogeochemical cycling of elemental mercury; anthropogenic influences. Geochim. Cosmochim. Acta 1994, 58(15):3191-3198.
43. Porcella D.B. Mercury in the environment: biogeochemistry. Mercury Pollution 1994, 3-19. CRC Press, Boca Raton. C.J. Watras, J.W. Huckabee (Eds.).
44. Rimondi V., Gray J.E., Costagliola P., Vaselli O., Lattanzi P. Concentration, distribution, and translocation of mercury and methylmercury in mine-waste, sediment, soil, water, and fish collected near the Abbadia San Salvatore mercury mine, Monte Amiata district, Italy. Sci. Total. Environ. 2012, 414:318-327.
45. Rolison J.M., Landing W.M., Luke W., Cohen M., Salters V.J.M. Isotopic composition of species-specific atmospheric Hg in a coastal environment. Chem. Geol. 2013, 336:37-49.
46. Rytuba J.J. Mercury mine drainage and processes that control its environmental impact. Sci. Total. Environ. 2000, 260(1-3):57-71.
47. Schauble E.A. Role of nuclear volume in driving equilibrium stable isotope fractionation of mercury, thallium, and other very heavy elements. Geochim. Cosmochim. Acta 2007, 71:2170-2189.
48. Sherman L.S., Blum J.D., Nordstrom D.K., McCleskey R.B., Barkay T., Vetriani C. Mercury isotopic composition of hydrothermal systems in the Yellowstone Plateau volcanic field and Guaymas Basin sea-floor rift. Earth Planet. Sci. Lett. 2009, 279:86-96.
49. Sherman L.S., Blum J.D., Johnson K.P., Keeler G.J., Barres J.A., Douglas T.A. Mass-independent fractionation of mercury isotopes in Arctic snow driven by sunlight. Nat. Geosci. 2010, 3:173-177.
50. Smith C.N., Kesler S.E., Bjorn K., Blum J.D. Mercury isotope fractionation in fossil hydrothermal systems. Geology 2005, 33(10):825-828.
51. Smith C.N., Kesler S.E., Blum J.D., Rytuba J.J. Isotope geochemistry of mercury in source rocks, mineral deposits and spring deposits of the California Coast Ranges, USA. Earth Planet. Sci. Lett. 2008, 269:399-407.
52. Sonke J.E., Zambardi T., Toutain J.-P. Indirect gold trap-MC-ICP-MS coupling for Hg stable isotope analysis using a syringe injection interface. J. Anal. At. Spectrom. 2008, 23(4):569-573.
53. Sonke J.E., Schäfer J., Chmeleff J., Audry S., Blanc G., Dupré B. Sedimentary mercury stable isotope records of atmospheric and riverine pollution from two major European heavy metal refineries. Chem. Geol. 2010, 279:90-100.
54. Stetson S.J. Analytical Methods for the Evaluation of Environmental Contamination by Perchlorate and Mercury 2009, (Ph.D. Dissertation Thesis), Colorado School of Mines, Golden, Colorado, (162 pp.).
55. Stetson S.J., Gray J.E., Wanty R.B., Macalady D.L. Isotopic variability of mercury in ore, mine-waste calcine, and leachates of mine-waste calcine from areas mined for mercury. Environ. Sci. Technol. 2009, 43:7331-7336.
56. Sun R., Heimbürger L.E., Sonke J.E., Liu G., Amouroux D., Berail S. Mercury stable isotope fractionation in six utility boilers of two large coal-fired power plants. Chem. Geol. 2013, 336:103-111.
57. Yin R., Feng X., Wang J., Li P., Liu J., Zhang Y., Chen J., Zheng L., Hu T. Mercury speciation and mercury isotope fractionation during ore roasting process and their implication to source identification of downstream sediment in the Wanshan mercury mining area, SW China. Chem. Geol. 2013, 336:72-79.
58. Young E.Y., Galy A., Nagahara H. Kinetic and equilibrium mass-dependent isotope fractionation laws in nature and their geochemical and cosmochemical consequence. Geochim. Cosmochim. Acta 2002, 66:1095-1104.
59. Zambardi T., Sonke J.E., Toutain J.P., Sortino F., Shinohara H. Mercury emissions and stable isotopic compositions at Vulcano Island (Italy). Earth Planet. Sci. Lett. 2009, 277:236-243.