Isotopic variability of mercury in ore, mine-waste calcine, and leachates of mine-waste calcine from areas mined for mercury

Environmental Science and Technology

Volumn 43, Issue 19, 2009, Pages 7331-7336

  Stetson, Sarah J ^a   Gray, John E ^b   Wanty, Richard B ^b   Macalady, Donald L ^a  

^a Department of Metallurgical and Materials Engineering   (United States)

^b DENVER FEDERAL CENTER   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

HG MINING; ISOTOPIC COMPOSITION; ISOTOPIC FRACTIONATIONS; LEACHATES; MINE WATERS; MINOR COMPONENTS; WATER LEACHING;

GROUNDWATER; ISOTOPES; LEACHING; MERCURY (METAL); MINES; MINING; ORES;

MERCURY COMPOUNDS;

MERCURY; MERCURY SULFIDE; RUNOFF;

CINNABAR; HUMAN ACTIVITY; ISOTOPIC ANALYSIS; ISOTOPIC COMPOSITION; ISOTOPIC FRACTIONATION; LEACHATE; MERCURY (ELEMENT); MINE WASTE; ORE BODY; RUNOFF;

ARTICLE; FRACTIONATION; LEACHING; MINING;

INDUSTRIAL WASTE; MERCURY; MERCURY COMPOUNDS; MERCURY ISOTOPES; MINING; UNITED STATES; WATER POLLUTANTS, CHEMICAL;

EID: 70349612508     PISSN: 0013936X     EISSN: 15205851     Source Type: Journal    
DOI: 10.1021/es9006993     Document Type: Article

References (50)

1. An Assessment of Mercury in the Environment. National Academy of Sciences, National Research Council: Washington, D.C., 1978; p 185.
2. Eisler, R. In Mercury Hazards to Fish, Wildlife, and Invertebrates: A Synoptic Review, Biological Report 85(1.10); U.S. Fish and Wildlife Service: Washington, DC, 1987; p 90.
3. Gray, J. E.; Theodorakos, P. M.; Bailey, E. A.; Turner, R. R. Distribution, speciation, and transport of mercury in stream-sediment, stream-water, and fish collected near abandoned mercury mines in southwestern Alaska, USA. Sci. Total Environ. 2000, 260, 21-33.
4. Rytuba, J. J. Mercury mine drainage and processes that control its environmental impact. Sci. Total Environ. 2000, 260, 57-71.
5. Kim, C. S.; Bloom, N. S.; Rytuba, J. J.; Brown, G. E., Jr. Mercury speciation by X-ray absorption fine structure spectroscopy and sequential chemical extractions: a comparison of speciation methods. Environ. Sci. Technol. 2003, 37, 5102-5108.
6. Brooks, W. E.; Matos, G. R. Mercury Recycling in the United States in 2000, Circular 1196-U; U.S. Geological Survey: Washington, DC, 2005; p 21.
7. Gray, J. E.; Hines, M. E.; Higueras, P. L.; Adatto, I.; Lasorsa, B. K. Mercury speciation and microbial transformations in mine wastes, stream sediments, and surface waters at the Almaden mining district, Spain. Environ. Sci. Technol. 2004, 38, 4285-4292.
8. Gray, J. E. Leaching, Transport, And Methylation of Mercury in and around Abandoned Mercury Mines in the Humboldt River Basin and Surrounding Areas, Nevada, Bulletin B 2210-C; U.S. Geological Survey: Washington, DC, 2003; p 15.
9. Bailey, E. H.; Phoenix, D. A. Quicksilver Deposits in Nevada, Geology and Mining Series No. 41; University of Nevada: Reno, NV, 1944; p 206.
10. Ross, C. P. The quicksilver deposits of the Terlingua region, Texas. Econ. Geol. 1941, 35, 115-142.
11. Mercury Study Report to Congress, I-VIII, EPA-452/R-97-003; U.S. Environmental Protection Agency: Washington, DC, 1997.
12. Kim, C. S.; Brown, G. E., Jr.; Rytuba, J. J. Characterization and speciation of mercury-bearing mine wastes using X-ray absorption spectroscopy. Sci. Total Environ. 2000, 261, 157-168.
13. Rytuba, J. J. Mercury from mineral deposits and potential environmental impact. Sci. Total Environ. 2003, 43, 326-338.
14. Gosar, M.; Pirc, S.; Bidovec, M. Mercury in the Idrijca River sediments as a reflection of mining and smelting activities of the Idrija mercury mine. J. Geochem. Explor. 1997, 58, 125-131. (Pubitemid 27399194)
15. Gray, J. E.; Hines, M. E.; Biester, H. Mercury methylation influenced by areas of past mercury mining in the Terlingua district, Southwest Texas, USA. Appl. Geochem. 2006, 21, 1940-1954. (Pubitemid 44635101)
16. Slowey, A. J.; Brown, G. E., Jr. Transformations of mercury, iron, and sulfur during the reductive dissolution of iron oxyhydroxide by sulfur. Geochim. Cosmochim. Acta 2007, 71, 877-894.
17. Slowey, A. J.; Rytuba, J. J.; Brown, G. E., Jr. Speciation of mercury and mode of transport from placer gold mine tailings. Environ. Sci. Technol. 2005, 39, 1547-1554. (Pubitemid 40387708)
18. Blum, J. D.; Bergquist, B. A. Reporting of variations in the natural isotopic composition of mercury. Anal. Bioanal. Chem. 2007, 388, 353-359. (Pubitemid 46675974)
19. Ridley, W. I.; Stetson, S. J. A review of isotopic composition as an indicator of the natural and anthropogenic behavior of mercury. Appl. Geochem. 2006, 21, 1889-1899. (Pubitemid 44635097)
20. Hintelmann, H.; Lu, S. Y. High precision isotopic ratio measurements of mercury isotopes in cinnabar ores using multicollector inductively coupled plasma mass spectrometry. The Analyst 2003, 128, 635-639.
21. Smith, C. N.; Kesler, S. E.; Bjorn, K.; Blum, J. D. Mercury isotope fractionation in fossil hydrothermal systems. Geology 2005, 33, 825-828.
22. Lamborg, C. A new twist for Mercury. Science 2007, 318, 402-403.
23. Sharp, R. D. Development of the mercury mining industry Trans-Pecos Texas, Mineral Resource Circular 64; Texas Bureau of Economic Geology: Austin, 1980.
24. Avery, D. W.; Moyle, P. R.; Reisenburg, R. M.; Fay, J. M. Preliminary Assessment and Site Inspection, The Mariscal Mine and Mill Site, Big Bend National Park, Brewster County, Texas, U.S. Bureau of Mines, Site Characterization Section; U.S. Bureau of Mines: Washington, DC, 1996.
25. Noble, D. C.; McCormack, J. K.; McKee, E. H.; Silberman, M. L.; Wallace, A. B. Time of mineralization in the evolution of the McDermitt caldera complex, Nevada-Oregon, and the relation of Middle Miocene mineralization in the northern Great Basin to coeval regional basaltic magmatic activity. Econ. Geol. 1988, 83, 859-863.
26. Gray, J. E.; Crock, J. G.; Fey, D. L. Environmental geochemistry of abandoned mercury mines in west-central Nevada, USA. Appl. Geochem. 2002, 17, 1069-1079. (Pubitemid 34674202)
27. Bloom, N. S.; Fitzgerald, W. F. Determination of volatile mercury species at the picogram level by low-temperature gas chromatography with cold-vapour atomic fluorescence detection. Anal. Chim. Acta 1988, 208, 151-161.
28. Ghosh, S.; Xu, Y.; Humayun, M.; Odom, L. Mass-independent fractionation of mercury isotopes in the environment. Geochem. Geophys. Geosyst. 2008, 9(3), Q03004, DOI: 10.1029/2007-GC001827.
29. Foucher, D.; Hintelmann, H. High-precision measurement of mercury isotope ratios in sediments using cold-vapor generation multi-collector inductively coupled plasma mass spectrometry. Anal. Bioanal. Chem. 2006, 384, 1470-1478.
30. Jackson, T. A.; Whittle, D. M.; Evans, M. S.; Muir, D. C. G. Evidence for mass-independent and mass-dependent fractionation of the stable isotopes of mercury by natural processes in aquatic ecosystems. Appl. Geochem. 2008, 23, 547-571.
31. Stetson, S. J. Analytical Methods for the Evaluation of Environmental Contamination by Perchlorate and Mercury. Ph.D. Dissertation, Colorado School of Mines, Golden, Colorado, 2009.
32. Test Methods for Evaluating Solid Waste, 3rd ed.; U.S. Environmental Protection Agency: Washington, DC, 1986; Vol HI and II (SW-846).
33. Smith, C. N.; Kesler, S. E.; Blum, J. D.; Rytuba, J. J. Isotope geochemistry of mercury in source rocks, mineral deposits and spring deposits of the California Coast Ranges, USA. Earth. Planet. Sci. Lett. 2008, 269, 399-407.
34. Yates, R. G.; Thompson, G. A. Geology and Quicksilver Deposits of the Terlingua District, Texas, Professional Paper 312; U.S. Geological Survey: Washington, DC, 1959; p 114.
35. Barnes, H. L., Geochemistry of Hydrothermal Ore Deposits. 3rd ed.; John Wiley and Sons: New York, 1997; p 972.
36. Schauble, E. A. Applying stable isotope fractionation theory to new systems. Rev. Mineral. Geochem. 2004, 55, 65-111.
37. Sherman, L. S.; Blum, J. D.; Nordstrom, D. K.; McCleskey, R. B.; Barkay, T.; Vetriani, C. Mercury isotopic composition of hydrothermal systems in the Yellowstone Plateau volcanic field and Guaymas Basin sea-floor rift. Earth. Planet. Sci. Lett. 2009, 279, 86-96.
38. Yang, l.; Sturgeon, R. E. Isotopic fractionation of mercury induced by reduction and ethylation. Anal. Bioanal. Chem. 2009, 393, 377-385.
39. Bergquist, B. A.; Blum, J. D. Mass-dependent and -independent fractionation of Hg isotopes by photoreduction in aquatic systems. Science 2007, 318, 417-420.
40. Hillebrand, W. F.; Schaller, W. T. The Mercury Minerals from Terlingua, Texas, Bulletin 405; U.S. Geological Survey: Washington, DC, 1909.
41. Kritee, K.; Blum, J. D.; Johnson, M. W.; Bergquist, B. A.; Barkay, T. Mercury stable isotope fractionation during reduction of Hg(II) and Hg(0) by mercury resistant microorganisms. Environ. Sci. Technol. 2007, 41, 1889-1895. (Pubitemid 46449217)
42. Kritee, K.; Blum, J. D.; Barkay, T. Mercury stable isotope fractionation during reduction of Hg(II) by different microbial pathways. Environ. Sci. Technol. 2008, 42, 9171-9177.
43. Zheng, W.; Foucher, D.; Hintelmann, H. Mercury isotope fractionation during volatilization of Hg(0) from solution into the gas phase. J. Anal. At. Spectrom. 2007, 22, 1097-1104. (Pubitemid 47311272)
44. Sonke, J. E.; Zambardi, T.; Toutain, J. P. Indirect gold trap-MC-ICP-MS coupling for Hg stable isotope analysis using a syringe injection interface. J. Anal. At. Spectrom. 2008, 23, 569-573.
45. Estrade, N.; Carignan, J.; Sonke, J. E.; Donard, O. F. X. Mercury isotope fractionation during liquid-vapor evaporation experiments. Geochim. Cosmochim. Acta 2009, 73, 2693-2711.
46. Schauble, E. A. Role of nuclear volume in driving equilibrium stable isotope fractionation of mercury, thallium, and other very heavy elements. Geochim. Cosmochim. Acta 2007, 71, 2170-2189.
47. Biester, H.; Gosar, M.; Muller, G. Mercury speciation in tailings of the Idrija mercury mine. J. Geochem. Explor. 1999, 65, 195-204. (Pubitemid 29388718)
48. Gray, J. E.; Hines, M. E.; Biester, H.; Larsorsa, B. K. Mercury methylation in mine wastes collected from abandoned mercury mines in the USA. J. Phys. IV 2003, 107, 573-576.
49. Foucher, D.; Ogrinc, N.; Hintelmann, H. Tracing mercury contamination from the Idrija mining region (Slovenia) to the Gulf of Trieste using Hg isotope ratio measurements. Environ. Sci. Technol. 2009, 43, 33-39.
50. Slowey, A. J.; Johnson, S. B.; Rytuba, J. J.; Brown, G. E., Jr. Role of organic acids in promoting colloidal transport of mercury from mine tailings. Environ. Sci. Technol. 2005, 39, 7869-7874.