In situ NMR observation of the lithium extraction/insertion from LiCoO 2cathode

Electrochimica Acta

Volumn 108, Issue , 2013, Pages 343-349

  Shimoda, Keiji ^a   Murakami, Miwa ^a   Takamatsu, Daiko ^a   Arai, Hajime ^a   Uchimoto, Yoshiharu ^a   Ogumi, Zempachi ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

In situ NMR; Lithium dendrite; Lithium ion battery; Lithium 7; Nuclear magnetic resonance

Indexed keywords

CATHODES; COBALT COMPOUNDS; ELECTRIC BATTERIES; ELECTRODES; EXTRACTION; IONS; LITHIUM ALLOYS; LITHIUM COMPOUNDS; LITHIUM-ION BATTERIES; NUCLEAR MAGNETIC RESONANCE; SECONDARY BATTERIES;

ELECTROCHEMICAL LITHIUM EXTRACTION; LITHIUM DENDRITE; NUCLEAR MAGNETIC RESONANCE(NMR); PORTABLE ELECTRONIC DEVICES; QUANTITATIVE INFORMATION; RECHARGEABLE LITHIUM ION BATTERY; SITU NMR; VOLUMETRIC ENERGY DENSITIES;

LITHIUM;

EID: 84884248309     PISSN: 00134686     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.electacta.2013.06.120     Document Type: Article

References (38)

1. J.N. Reimers, J.R. Dahn, Electrochemical and in situ X-ray diffraction studiesof lithium intercalation in LixCoO2, Journal of the Electrochemical Society 139(1992) 2091.
2. G.G. Amatucci, J.M. Tarascon, L.C. Klein, CoO2, the end member of the LixCoO2solid solution, Journal of the Electrochemical Society 143 (1996) 1114.
3. Z. Chen, Z. Lu, J.R. Dahn, Staging phase transitions in LixCoO2, Journal of the Electrochemical Society 149 (2002) A1604.
4. Z. Chen, J.R. Dahn, Methods to obtain excellent capacity retention in LiCoO2cycled to 4.5 V, Electrochimica Acta 49 (2004) 1079.
5. N. Sharma, V.K. Peterson, M.M. Elcombe, M. Avdeev, A.J. Studer, N. Blagojevic, R. Yusoff, N. Kamarulzaman, Structural changes in a commercial lithium-ion battery during electrochemical cycling: an in situ neutron diffraction study, Journal of Power Sources 195 (2010) 8258.
6. I. Nakai, K. Takahashi, Y. Shiraishi, T. Nakagome, F. Nishikawa, Study of the Jahn-Teller distortion in LiNiO2, a cathode material in a rechargeable lithiumbattery, by in situ X-ray absorption fine structure analysis, Journal of Solid StateChemistry 140 (1998) 145.
7. Y. Koyama, H. Arai, Z. Ogumi, I. Tanaka, Y. Uchimoto, Co K-edge XANES ofLiCoO2and CoO2with a variety of structures by supercell density functionalcalculations with a core hole, Physical Review B 85 (2012) 075129.
8. B. Ouyang, X. Cao, H.W. Lin, S. Slane, S. Kostov, M. denBoer, S.G. Greenbaum,Lithium-7 NMR studies of Li1-xCoO2battery cathodes, Materials Research Society Symposium Proceedings 369 (1995) 59.
9. P. Mustarelli, V. Massarotti, M. Bini, D. Capsoni, Transferred hyperfine interac-tion and structure in LiMn2O4and Li2MnO3coexisting phases: A XRD and7LiNMR-MAS study, Physical Review B 55 (1997) 12018.
10. M. Ménétrier, I. Saadoune, S. Levasseur, C. Delmas, The insulator-metal transition upon lithium deintercalation from LiCoO2: electronic properties and7LiNMR study, Journal of Materials Chemistry 9 (1999) 1135.
11. S. Levasseur, M. Ménétrier, E. Suard, C. Delmas, Evidence for structural defect sin non-stoichimetric HT-LiCoO2: electrochemical, electronic properties and7LiNMR studies, Solid State Ionics 128 (2000) 11.
12. K. Guérin, M. Ménétrier, A. Février-Bouvier, S. Flandrois, B. Simon, P. Biensan,A7Li NMR study of a hard carbon for lithium-ion rechargeable batteries, Solid State Ionics 127 (2000) 187.
13. Y.J. Lee, C.P. Grey, Determining the lithium local environments in the lithiummanganates LiZn0.5Mn1.5O4and Li2MnO3by analysis of the6Li MAS NMR spinning sideband manifolds, The Journal of Physical Chemistry B 106 (2002) 3576.
14. M.C. Tucker, M.M. Doeff, T.J. Richardson, R. Fiñones, J.A. Reimer, E.J. Cairns,7Li and31P Magic angle spinning nuclear magnetic resonance of LiFePO4-typematerials, Electrochemical and Solid-State Letters 5 (2002) A95.
15. P. Azaïs, L. Duclaux, A.-M. Faugère, F. Béguin, Reactive milling of graphite with lithium: application to lithium batteries, Applied Physics Letters 81 (2002) 775. (Pubitemid 34924022)
16. C.P. Grey, N. Dupré, NMR studies of cathode materials for lithium-ion recharge-able batteries, Chemical Reviews 104 (2004) 4493.
17. B.M. Meyer, N. Leifer, S. Sakamoto, S.G. Greenbaum, C.P. Grey, High field multinuclear NMR investigation of the SEI layer in lithium rechargeable batteries, Electrochemical and Solid-State Letters 8 (2005) A145.
18. K. Gotoh, M. Maeda, A. Nagai, A. Goto, M. Tansho, K. Hashi, T. Shimizu, H. Ishida, Properties of a novel hard-carbon optimized to large size Li ion secondary battery studied by7Li NMR, Journal of Power Sources 162 (2006) 1322.
19. J. Cabana, J. Shirakawa, G. Chen, T.J. Richardson, C.P. Grey, MAS NMR study of the metastable solid solutions found in the LiFePO4/FePO4system, Chemistryof Materials 22 (2010) 1249.
20. L.J.M. Davis, I. Heinmaa, B.L. Ellis, L.F. Nazar, G.R. Goward, Influence of particle size on solid solution formation and phase interfaces in Li0.5FePO4revealed by31P and7Li solid state NMR spectroscopy, Physical Chemistry Chemical Physics13 (2011) 5171.
21. B. Key, M. Morcrette, J.-M. Tarascon, C.P. Grey, Pair distribution function analysis and solid state NMR studies of silicon electrodes for lithium ion batteries: understanding the (de)lithiation mechanisms, Journal of the American Chemical Society 133 (2011) 503.
22. M. Murakami, H. Yamashige, H. Arai, Y. Uchimoto, Z. Ogumi, Association of paramagnetic species with formation of LiF at the surface of LiCoO2, Electrochimica Acta 78 (2012) 49.
23. H. Hain, M. Scheuermann, R. Heinzmann, L. Wünsche, H. Hahn, S. Indris, Study of local structure and Li dynamics in Li4+xTi5O12(0 ≤ x ≤ 5) using6Li and7LiNMR spectroscopy, Solid State Nuclear Magnetic Resonance 42 (2012) 9.
24. R.E. Gerald II, J. Sanchez, C.S. Johnson, R.J. Klingler, J.W. Rathke, In situ nuclear magnetic resonance investigations of lithium ions in carbon electrode materials using a novel detector, Journal of Physics: Condensed Matter 13 (2001) 8269.
25. M. Letellier, F. Chevallier, C. Clinard, E. Frackowiak, J.-N. Rouzaud, F. Béguin,M. Morcrette, J.-M. Tarascon, The first in situ7Li nuclear magnetic resonance study of lithium insertion in hard-carbon anode materials for Li-ion batteries, The Journal of Chemical Physics 118 (2003) 6038.
26. M. Letellier, F. Chevallier, F. Béguin, E. Frackowiak, J.-N. Rouzaud, The first in situ7Li NMR study of the reversible lithium insertion mechanism in disorganisedcarbons, Journal of Physical Chemistry of Solids 65 (2004) 245.
27. M. Letellier, F. Chevallier, F. Béguin, In situ7Li NMR during lithium electro chemical insertion into graphite and a carbon/carbon composite, Journal of Physical Chemistry of Solids 67 (2006) 1228.
28. M. Letellier, F. Chevallier, M. Morcrette, In situ7Li nuclear magnetic resonance observation of the electrochemical intercalation of lithium in graphite; 1stcycle, Carbon 45 (2007) 1025.
29. B. Key, R. Bhattacharyya, M. Morcrette, V. Seznéc, J.-M. Tarascon, C.P. Grey, Real-time NMR investigations of structural changes in silicon electrodes for lithium-ion batteries, Journal of the American Chemical Society 131 (2009)9239.
30. R. Bhattacharyya, B. Key, H. Chen, A.S. Best, A.F. Hollenkamp, C.P. Grey, In situ NMR observation of the formation of metallic lithium microstructures in lithium batteries, Nature Materials 9 (2010) 504.
31. F. Poli, J.S. Kshetrimayum, L. Monconduit, M. Letellier, New cell design for in-situ NMR studies of lithium-ion batteries, Electrochemical Communications 13(2011) 1293.
32. B. Key, R. Bhattacharyya, H. Chen, C.P. Grey, In-situ solid state NMR studies on high rate lithium-ion batteries, in: The 214th ECS Meeting Abstract, 2008,#1210.
33. C. Kittel, Introduction to Solid State Physics, 8th edn, John Wiley, New York,2004.
34. N.M. Trease, L. Zhou, H.J. Chang, B.Y. Zhu, C.P. Grey, In situ NMR of lithium ion batteries: bulk susceptibility effects and practical considerations, Solid State Nuclear Magnetic Resonance 42 (2012) 62.
35. T. Ohzuku, A. Ueda, Solid-state redox reactions of LiCoO2(R-3m) for 4 Volt secondary lithium cells, Journal of the Electrochemical Society 141 (1994)2972.
36. R.E. Gerald II, R.J. Klingler, G. Sandí, C.S. Johnson, L.G. Scanlon, J.W. Rathke,7LiNMR study of intercalated lithium in curved carbon lattices, Journal of PowerSources 89 (2000) 237.
37. S. Chandrashekar, N.M. Trease, H.J. Chang, L.-S. Du, C.P. Grey, A. Jerschow,7LiMRI of Li batteries reveals location of microstructural lithium, Nature Materials11 (2012) 311.
38. S.F. Amalraj, D. Aurbach, The use of in situ techniques in R&D of Li and Mg rechargeable batteries, Journal of Solid State Electrochemistry 15 (2011) 877.