Selective hydrogenation of polyunsaturated fatty acids using alkanethiol self-assembled monolayer-coated Pd/Al2O3 catalysts

ACS Catalysis

Volumn 3, Issue 9, 2013, Pages 2041-2044

  Kahsar, Karl R ^a   Schwartz, Daniel K ^a   Medlin, J Will ^a  

^a University of Colorado at Boulder   (United States)

Author keywords

palladium; polyunsaturated fatty acids; selective hydrogenation; self assembled monolayers

Indexed keywords

CONSUMPTION RATES; DEGREE OF SATURATIONS; OXIDATIVE STABILITY; PARTIAL HYDROGENATION; PRODUCT STREAMS; REACTION SELECTIVITY; SELECTIVE HYDROGENATION; SELF-ASSEMBLED;

CATALYST SELECTIVITY; HYDROGENATION; MONOUNSATURATED FATTY ACIDS; OLEIC ACID; ORGANIC POLYMERS; PALLADIUM; POLYUNSATURATED FATTY ACIDS; REACTION KINETICS; SATURATED FATTY ACIDS; SELF ASSEMBLED MONOLAYERS;

CATALYST ACTIVITY;

EID: 84883873760     PISSN: 21555435     EISSN: None     Source Type: Journal    
DOI: 10.1021/cs4004563     Document Type: Article

References (32)

1. Torborg, C.; Beller, M. Adv. Synth. Catal. 2009, 351, 3027
2. Behrens, M. Angew. Chem. Int. Ed. 2010, 49, 2095
3. Nohair, B.; Especel, C.; Lafaye, G.; Marécot, P.; Hoang, L. C.; Barbier, J. J. Mol. Catal. A: Chem. 2005, 229, 117
4. Gill, I.; Valivety, R. Trends Biotechnol. 1997, 15, 401
5. Steen, E. J.; Kang, Y.; Bokinsky, G.; Hu, Z.; Schirmer, A.; McClure, A.; del Cardayre, S. B.; Keasling, J. D. Nature 2010, 463, 559
6. Ravasio, N.; Zaccheria, F.; Gargano, M.; Recchia, S.; Fusi, A.; Poli, N.; Psaro, R. Appl. Catal., A 2002, 233, 1
7. Jurg, J. W.; Eisma, E. Science 1964, 144, 1451
8. Ramos, M. J.; Fernández, C. M.; Casas, A.; Rodríguez, L.; Pérez, á. Bioresour. Technol. 2009, 100, 261
9. Verziu, M.; Cojocaru, B.; Hu, J.; Richards, R.; Ciuculescu, C.; Filip, P.; Parvulescu, V. I. Green Chem. 2007, 10, 373
10. Kim, H.-J.; Kang, B.-S.; Kim, M.-J.; Park, Y. M.; Kim, D.-K.; Lee, J.-S.; Lee, K.-Y. Catal. Today 2004, 93-95, 315
11. Carvalho, M. S.; Lacerda, R. A.; Leao, J. P. B.; Scholten, J. D.; Neto, B. A. D.; Suarez, P. A. Z. Catal. Sci. Technol. 2011, 1, 480
12. Knothe, G. Fuel Process. Technol. 2007, 88, 669
13. Mittelbach, M.; Gangl, S. J. Am. Oil Chem. Soc. 2001, 78, 573
14. Moser, B. R.; Haas, M. J.; Winkler, J. K.; Jackson, M. A.; Erhan, S. Z.; List, G. R. Eur. J. Lipid Sci. Technol. 2007, 109, 17
15. Dunn, R. O. Fuel Process. Technol. 2005, 86, 1071
16. Karavalakis, G.; Stournas, S.; Karonis, D. Fuel 2010, 89, 2483
17. Veldsink, J. W.; Bouma, M. J.; Schoon, N. H.; Beenackers, A. Catal. Rev.-Sci. Eng. 1997, 39, 253
18. Bernas, A.; Myllyoja, J.; Salmi, T.; Murzin, D. Y. Appl. Catal., A 2009, 353, 166
19. Yang, R.; Su, M.; Li, M.; Zhang, J.; Hao, X.; Zhang, H. Bioresour. Technol. 2010, 101, 5903
20. Sadeghmoghaddam, E.; Gaieb, K.; Shon, Y. S. Appl. Catal., A 2011, 405, 137
21. Snelders, D. J. M.; Yan, N.; Gan, W.; Laurenczy, G.; Dyson, P. J. ACS Catal. 2011, 2, 201
22. Kahsar, K. R.; Schwartz, D. K.; Medlin, J. W. Appl. Catal., A 2012, 445-446, 102
23. Taguchi, T.; Isozaki, K.; Miki, K. Adv. Mater. 2012, 24, 6462
24. Kwon, S. G.; Krylova, G.; Sumer, A.; Schwartz, M. M.; Bunel, E. E.; Marshall, C. L.; Chattopadhyay, S.; Lee, B.; Jellinek, J.; Shevchenko, E. V. Nano Lett. 2012, 12, 5382
25. Marshall, S. T.; O'Brien, M.; Oetter, B.; Corpuz, A.; Richards, R. M.; Schwartz, D. K.; Medlin, J. W. Nat. Mater. 2010, 9, 853
26. Ulman, A.; Eilers, J. E.; Tillman, N. Langmuir 1989, 5, 1147
27. Love, J. C.; Wolfe, D. B.; Haasch, R.; Chabinyc, M. L.; Paul, K. E.; Whitesides, G. M.; Nuzzo, R. G. J. Am. Chem. Soc. 2003, 125, 2597
28. Schoenbaum, C. A.; Schwartz, D. K.; Medlin, J. W. J. Catal. 2013, 303, 92
29. Marshall, S. T.; Horiuchi, C. M.; Zhang, W. Y.; Medlin, J. W. J. Phys. Chem. C 2008, 112, 20406
30. Marshall, S. T.; Schwartz, D. K.; Medlin, J. W. Langmuir 2011, 27, 6731
31. Bayrak, Y. Microporous Mesoporous Mater. 2006, 87, 203
32. Makosch, M.; Lin, W.-I.; Bumbálek, V.; Sá, J.; Medlin, J. W.; Hungerbühler, K.; van Bokhoven, J. A. ACS Catal. 2012, 2, 2079