Quantitative characterization of the solid acidity of montmorillonite using combined FTIR and TPD based on the NH3 adsorption system

Applied Clay Science

Volumn 80-81, Issue , 2013, Pages 407-412

  Liu, Dong ^a   Yuan, Peng ^a   Liu, Hongmei ^a,b   Cai, Jingong ^c   Tan, Daoyong ^a,b   He, Hongping ^a   Zhu, Jianxi ^a   Chen, Tianhu ^d  

^a GUANGZHOU INSTITUTE OF GEOCHEMISTRY   (China)

^b UNIVERSITY OF CHINESE ACADEMY OF SCIENCES   (China)

^c TONGJI UNIVERSITY   (China)

^d HEFEI UNIVERSITY OF TECHNOLOGY   (China)

Author keywords

FTIR; Heating; Montmorillonite; NH3 adsorption; Solid acidity; TPD

Indexed keywords

ADSORPTION SYSTEM; DEHYDROXYLATIONS; FTIR; INDICATOR METHODS; MONTMORILLONITE INTERLAYER; NEGATIVELY CHARGED; QUANTITATIVE CHARACTERIZATION; SOLID ACIDITIES;

ADSORPTION; ALUMINUM; FOURIER TRANSFORM INFRARED SPECTROSCOPY; HEATING; IONS; SILICON; TEMPERATURE PROGRAMMED DESORPTION;

CLAY MINERALS;

ACIDITY; ADSORPTION; AMMONIA; DEHYDRATION; DEHYDROXYLATION; DESORPTION; FTIR SPECTROSCOPY; HEATING; MONTMORILLONITE;

EID: 84883489153     PISSN: 01691317     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.clay.2013.07.006     Document Type: Article

References (53)

1. Adams J.M., Mccabe R.W. Clay minerals as catalysts. Developments in Clay Science 2006, vol. 1:541-565. Elsevier, Amsterdam. F. Bergaya, B.K.G. Theng, G. Lagaly (Eds.).
2. Arena F., Dario R., Parmaliana A. A characterization study of the surface acidity of solid catalysts by temperature programmed methods. Applied Catalysis A: General 1998, 170(1):127-137.
3. 2-TPD measurements. Thermochimica Acta 2006, 449(1-2):27-34.
4. Benesi H. Acidity of catalyst surfaces. II. Amine titration using Hammett indicators. Journal of Physical Chemistry 1957, 61(7):970-973.
5. Benjelloun M., Cool P., Linssen T., Vansant E.F. Acidic porous clay heterostructures: study of their cation exchange capacity. Microporous and Mesoporous Materials 2001, 49(1-3):83-94.
6. Bergaya F., Theng B.K.G., Lagaly G. Handbook of Clay Science. Developments in Clay Science 2006, vol. 1. Elsevier, Amsterdam.
7. Billingham J., Breen C., Yarwood J. In situ determination of Bronsted/Lewis acidity on cation-exchanged clay mineral surfaces by ATR-IR. Clay Minerals 1996, 31(4):513-522.
8. Bodoardo S., Chiappetta R., Onida B., Figueras F., Garrone E. Ammonia interaction and reaction with Al-pillared montmorillonite: an IR study. Microporous and Mesoporous Materials 1998, 20(1-3):187-196.
9. Chen T.H., Liu H.B., Li J.H., Chen D., Chang D.Y., Kong D.J., Frost R.L. Effect of thermal treatment on adsorption-desorption of ammonia and sulfur dioxide on palygorskite: change of surface acid-alkali properties. Chemical Engineering Journal 2011, 166(3):1017-1021.
10. 3 on alumina or titania pillared montmorillonite modified with Cu or Co: part II. Temperature programmed studies. Applied Catalysis B: Environmental 2004, 53(1):47-61.
11. Choudary B.M., Chowdari N.S., Kantam M.L. Montmorillonite clay catalyzed tosylation of alcohols and selective monotosylation of diols with p-toluenesulfonic acid: an enviro-economic route. Tetrahedron 2000, 56(37):7291-7298.
12. Conway E., O'malley E. Microdiffusion methods. Ammonia and urea using buffered absorbents. The Biochemical Journal 1942, 36(7-9):655.
13. Corma A., Fornés V., Melo F.V., Herrero J. Comparison of the information given by ammonia T.P.D. and pyridine adsorption-desorption on the acidity of dealuminated HY and LaHY zeolite cracking catalysts. Zeolites 1987, 7(6):559-563.
14. Derkowski A., Drits V.A., McCarty D.K. Rehydration of dehydrated-dehydroxylated smectite in a low water vapor environment. American Mineralogist 2012, 97(1):110-127.
15. Dontsova K.M., Norton L.D., Johnston C.T. Calcium and magnesium effects on ammonia adsorption by soil clays. Soil Science Society of America Journal 2005, 69(4):1225-1232.
16. Emmerich K. Spontaneous rehydroxylation of a dehydroxylated cis-vacant montmorillonite. Clays and Clay Minerals 2000, 48(3):405-408.
17. Emmerich K., Wolters F., Kahr G., Lagaly G. Clay profiling: the classification of montmorillonites. Clays and Clay Minerals 2009, 57(1):104.
18. Ferrage E., Lanson B., Sakharov B.A., Drits V.A. Investigation of smectite hydration properties by modeling experimental X-ray diffraction patterns: part I. Montmorillonite hydration properties. American Mineralogist 2005, 90(8-9):1358-1374.
19. Flego C., Galasso L., Millini R., Kiricsi I. The influence of the composition on the thermal and acid characteristics of multi-component oxide pillared montmorillonite. Applied Catalysis A: General 1998, 168(2):323-331.
20. Flessner U., Jones D., Roziere J., Zajac J., Storaro L., Lenarda M., Pavan M., Jimenez-Lopez A., Rodriguez-Castellon E., Trombetta M. A study of the surface acidity of acid-treated montmorillonite clay catalysts. Journal of Molecular Catalysis A: Chemical 2001, 168(1-2):247-256.
21. Frenkel M. Surface acidity of montmorillonites. Clays and Clay Minerals 1974, 22(5-6):435-441.
22. Fripiat J.J., Leonard A., Uytterho J.B. Structure and properties of amorphous silicoaluminas. 2. Lewis and Bronsted acid sites. Journal of Physical Chemistry 1965, 69(10):3274-3279.
23. Gaillard F., Joly J.P., Peillex E., Romand M. FT-IR and temperature-programmed desorption (TPD) study of the adsorption of probe molecules used to model epoxy resin adhesion to chromium, iron and stainless steel substrates. The Journal of Adhesion 2000, 72(3-4):317-334.
24. Hair M.L., Hertl W. Acidity of surface hydroxyl groups. Journal of Physical Chemistry 1970, 74(1):91-94.
25. He H.P., Yang D., Yuan P., Shen W., Frost R.L. A novel organoclay with antibacterial activity prepared from montmorillonite and Chlorhexidini Acetas. Journal of Colloid and Interface Science 2006, 297(1):235-243.
26. Heller-Kallai L. Clay catalysis in reactions of organic matter. Organo-Clay Complexes and Interactions 2002, 567-613. Marcel Dekker, New York. S. Yariv, H. Cross (Eds.).
27. Heller-kallai L. Thermally modified clay minerals. Developments in Clay Science 2006, vol. 1:289-296. Elsevier, Amsterdam. F. Bergaya, B.K.G. Theng, G. Lagaly (Eds.).
28. Hetényi M. Simulated thermal maturation of type I and III kerogens in the presence and absence of calcite and montmorillonite. Organic Geochemistry 1995, 23(2):121-127.
29. Janek M., Lagaly G. Proton saturation and rheological properties of smectite dispersions. Applied Clay Science 2001, 19(1-6):121-130.
30. Kaufhold S., Stanjek H., Ner D.P., Dohrmann R. The acidity of surface groups of dioctahedral smectites. Clay Minerals 2011, 46(4):583-592.
31. Komadel P., Madejová J. Acid activation of clay minerals. Developments in Clay Science 2006, vol. 1:263-281. Elsevier, Amsterdam. F. Bergaya, B.K.G. Theng, G. Lagaly (Eds.).
32. Lambert J.F., Poncelet G. Acidity in pillared clays: origin and catalytic manifestations. Topics in Catalysis 1997, 4(1-2):43-56.
33. Larter S., Douglas A. Pyrolysis methods in organic geochemistry: an overview. Journal of Analytical and Applied Pyrolysis 1982, 4(1):1-19.
34. Liu D., Yuan P., Liu H.M., Cai J.G., Qin Z.H., Tan D.Y., Zhou Q., He H.P., Zhu J.X. Influence of heating on the solid acidity of montmorillonite: a combined study by DRIFT and Hammett indicators. Applied Clay Science 2011, 52(4):358-363.
35. Madejova J., Komadel P. Baseline studies of the clay minerals society source clays: infrared methods. Clays and Clay Minerals 2001, 49(5):410-432.
36. Morrow B., Cody I. Infrared studies of reactions on oxide surfaces. 5. Lewis acid sites on dehydroxylated silica. Journal of Physical Chemistry 1976, 80(18):1995-1998.
37. Mortland M.M., Raman K.V. Surface acidity of smectites in relation to hydration exchangeable cation and structure. Clays and Clay Minerals 1968, 16(5):393-398.
38. Mortland M.M., Uytterhoeven J., Fripiat J.J., Chaussidon J. Interaction between ammonia and expanding lattices of montmorillonite and vermiculite. Journal of Physical Chemistry 1963, 67(2):248-258.
39. Newman A.C.D. Chemistry of Clays and Clay Minerals 1987, Wiley-Interscience, New York.
40. Okada K., Arimitsu N., Kameshima Y., Nakajima A., MacKenzie K.J.D. Solid acidity of 2:1 type clay minerals activated by selective leaching. Applied Clay Science 2006, 31(3-4):185-193.
41. +-bearing and saturated clay minerals: a review of the study of layer charge. Applied Clay Science 2006, 34(1-4):22-30.
42. Quaschning V., Deutsch J., Druska P., Niclas H.J., Kemnitz E. Properties of modified zirconia used as Friedel-Crafts-acylation catalysts. Journal of Catalysis 1998, 177(2):164-174.
43. +-montmorillonite clay catalysts by FT-IR spectroscopy: correlation with esterification activity. Catalysis Communications 2007, 8(3):241-246.
44. Ravindra Reddy C., Bhat Y.S., Nagendrappa G., Jai Prakash B.S. Brøsted and Lewis acidity of modified montmorillonite clay catalysts determined by FT-IR spectroscopy. Catalysis Today 2009, 141(1-2):157-160.
45. Russell J.D. Infra-red study of reactions of ammonia with montmorillonite and saponite. Transactions of the Faraday Society 1965, 61(514P):2284-2294.
46. Singh B., Patial J., Sharma P., Agarwal S.G., Qazi G.N., Maity S. Influence of acidity of montmorillonite and modified montmorillonite clay minerals for the conversion of longifolene to isolongifolene. Journal of Molecular Catalysis A: Chemical 2007, 266(1-2):215-220.
47. Stevens R. A system for calculating analyses of micas and related minerals to end members. Bulletin. Geological Survey of United States of America 1945, 950:101-119.
48. Tanabe K. New Solid Acids and Bases: Their Catalytic Properties 1989, Elsevier, Amsterdam. first ed.
49. Temuujin J., Senna M., Jadambaa T., Burmaa D., Erdenechimeg S., Mackenzie K.J.D. Characterization and bleaching properties of acid-leached montmorillonite. Journal of Chemical Technology and Biotechnology 2006, 81(4):688-693.
50. Tyagi B., Chudasama C.D., Jasra R.V. Characterization of surface acidity of an acid montmorillonite activated with hydrothermal, ultrasonic and microwave techniques. Applied Clay Science 2006, 31(1-2):16-28.
51. Walling C. The acid strength of surfaces. Journal of the American Chemical Society 1950, 72(3):1164-1168.
52. Wei Z., Michael Moldowan J., Dahl J., Goldstein T.P., Jarvie D.M. The catalytic effects of minerals on the formation of diamondoids from kerogen macromolecules. Organic Geochemistry 2006, 37(11):1421-1436.
53. Xu W.Z. Vibrational Probe Studies of Sorbed Water, Structural Hydroxyl Groups and Surface Acidity on Montmorillonite by FTIR/Gravimetric Method 1997, Purdue Univ., West Lafayette.