Aminopolycarboxylic acid functionalized adsorbents for heavy metals removal from water

Water Research

Volumn 47, Issue 14, 2013, Pages 4812-4832

  Repo, Eveliina ^a   Warchoł, Jolanta K ^b   Bhatnagar, Amit ^c   Mudhoo, Ackmez ^d   Sillanpää, Mika ^a  

^a LAPPEENRANTA UNIVERSITY OF TECHNOLOGY   (Finland)

^b RZESZOW UNIVERSITY OF TECHNOLOGY   (Poland)

^c LINNAEUS UNIVERSITY   (Sweden)

^d UNIVERSITY OF MAURITIUS   (Mauritius)

Author keywords

Adsorption; Aminopolycarboxylic acid; Chelating agent; Heavy metals; Surface functionalization; Water treatment

Indexed keywords

ADSORBENTS; AMINO ACIDS; BINDING ENERGY; CHELATION; CHEMICALS REMOVAL (WATER TREATMENT); ETHYLENEDIAMINETETRAACETIC ACID; HEAVY METALS; WATER POLLUTION;

AMINOPOLYCARBOXYLIC ACID; CHELATING AGENT; CHELATING PROPERTIES; CONTAMINATED WATER; FUNCTIONALIZED; HEAVY METAL REMOVAL; IMINODIACETIC ACID; REMOVAL OF METALS; RESEARCH RESULTS; SURFACE FUNCTIONALIZATION;

ADSORPTION;

ADSORBENT; AMINOPOLYCARBOXYLIC ACID; CADMIUM; CARBOXYLIC ACID DERIVATIVE; CHELATING AGENT; CHITOSAN; CHROMIUM; COBALT; CUPRIC ION; DIGLYCINE; EDETIC ACID; LEAD; MELAMINE; MERCURY; METAL CHELATE; NICKEL; NITRILOTRIACETIC ACID; PENTETIC ACID; POLYAMIDOAMINE; POLYETHYLENEIMINE; POLYSTYRENE; POLYVINYL ALCOHOL; POLYVINYLIDENE FLUORIDE; SILICA GEL; SILICON DIOXIDE; UNCLASSIFIED DRUG; WATER; ZINC ION;

ADSORPTION; CARBOXYLIC ACID; CHELATING AGENT; HEAVY METAL; POLLUTANT REMOVAL; REACTION KINETICS; THERMODYNAMICS; WATER TREATMENT;

ADSORPTION; ADSORPTION KINETICS; ELECTRON SPIN RESONANCE; ENVIRONMENTAL IMPACT; HEAVY METAL REMOVAL; INFRARED SPECTROSCOPY; ION PAIR CHROMATOGRAPHY; ISOTHERM; MASS SPECTROMETRY; METAL BINDING; PRIORITY JOURNAL; PROTON TRANSPORT; REVIEW; THERMODYNAMICS; THERMOGRAVIMETRY; WASTE WATER MANAGEMENT; X RAY DIFFRACTION; X RAY PHOTOELECTRON SPECTROSCOPY;

ADSORPTION; AMINOPOLYCARBOXYLIC ACID; CHELATING AGENT; HEAVY METALS; SURFACE FUNCTIONALIZATION; WATER TREATMENT;

ADSORPTION; CHELATING AGENTS; EDETIC ACID; IMINO ACIDS; METALS, HEAVY; NITRILOTRIACETIC ACID; WASTE DISPOSAL, FLUID; WATER PURIFICATION;

EID: 84883291199     PISSN: 00431354     EISSN: 18792448     Source Type: Journal    
DOI: 10.1016/j.watres.2013.06.020     Document Type: Review

References (120)

1. Afkhami A., Madrakian T., Amini A., Karimi Z. Effect of the impregnation of carbon cloth with ethylenediaminetetraacetic acid on its adsorption capacity for the adsorption of several metal ions. J. Hazard. Mater. 2008, 150:408-412.
2. Aguilar-Islas A.M., Resing J.A., Bruland K.W. Catalytically enhanced spectrophotometric determination of manganese in seawater by flow-injection analysis with a commercially available resin for on-line preconcentration. Limnol. Oceanogr. Methods 2006, 4:105-113.
3. Asnin L., Kaczmarski K., Guiochon G. Empirical development of a binary adsorption isotherm based on the single-component isotherms in the framework of a two-site model. J. Chromatogr. A 2007, 1138:158-168.
4. Atia A.A., Donia A.M., Abou-El-Enein S.A., Yousif A.M. Effect of chain length of aliphatic amines immobilized on a magnetic glycidyl methacrylate resin towards the uptake behaviour of Hg(II) from aqueous solutions. Sep. Sci. Technol. 2007, 42:1-18.
5. Atia A.A., Donia A.M., Yousif A.M. Removal of some hazardous heavy metals from aqueous solution using magnetic chelating resin with iminodiacetate functionality. Sep. Purif. Technol. 2008, 61:348-357.
6. Atzei D., Ferri T., Sadun C., Sangiorgio P., Caminiti R. Structural characterization of complexes between iminodiacetate blocked on styrene-divinylbenzene matrix (Chelex 100 resin) and Fe(III), Cr(III), Zn(II) in solid phase by energy-dispersive X-ray diffraction. J. Am. Chem. Soc. 2001, 123:2552-2558.
7. Babel S., Kurniawan T.A. Low-cost adsorbents for heavy metals uptake from contaminated water: a review. J. Hazard. Mater. 2003, B97:219-243.
8. Bailey S.E., Olin T.J., Bricka M., Adrian D.D. A review of potentially low-cost sorbents for heavy metals. Water Res. 1999, 33:2469-2479.
9. Baraka A., Hall P.J., Heslop M.J. Melamine-formaldehyde-NTA chelating gel resin: synthesis, characterization and application for copper(II) ion removal from synthetic wastewater. J. Hazard. Mater. 2007, 140:86-94.
10. Baraka A., Hall B.J., Heslop M.J. Preparation and characterization of melamine-formaldehyde-DTPA chelating resin and its use as an adsorbent for heavy metals removal from wastewater. React. Funct. Polym. 2007, 67:585-600.
11. Bari F., Begun N., Jamaludin S.B., Hussin K. Extraction and separation of Cu(II), Ni(II) and Zn(II) by sol-gel silica immobilized with Cyanex 272. Hydrometallurgy 2009, 96:140-147.
12. Barron L., O'Toole M., Diamond D., Nesterenko P.N., Paull B. Separation of transition metals on a poly-iminodiacetic acid grafted polymeric resin column with post-column reaction detection utilising a paired emitter-detector diode system. J. Chromatogr. A 2008, 1213:31-36.
13. Bashir W., Paull B. Determination of trace alkaline earth metals in brines using chelation ion chromatography with an iminodiacetic acid bonded silica column. J. Chromatogr. A 2001, 907:191-200.
14. Biesuz R., Pesavento M., Gonzalo A., Valiente M. Sorption of proton and heavy metal ions on a macroporous chelating resin with an iminodiacetate active group as a function of temperature. Talanta 1998, 47:127-136.
15. Borah J.M., Das M.R., Mahiuddin S. Influence of anions on the adsorption kinetics of salicylate onto [alpha]-alumina in aqueous medium. J. Colloid Interface Sci. 2007, 316:260-267.
16. Bucheli-Witschel M., Egli T. Environmental fate and microbial degradation of aminopolycarboxylic acids. Microbiol. Rev. 2001, 25:69-106.
17. Chen C.-Y., Chen C.-Y. Study on stability constants of polymer-bound iminodiacetate-type chelating agents with some transition-metal ions. J. Appl. Polym. Sci. 2002, 86:1986-1994.
18. Chen C.-Y., Chen C.-Y. Stability constants of water-soluble and latex types of chelating polymers containing iminodiacetic acid with some transition-metal ions. Eur. Polym. J. 2003, 39:991-1000.
19. Chen C.-Y., Chiang C.-L., Huang P.-C. Adsorption of heavy metal ions by a magnetic chelating resin containing hydroxyl and iminodiacetate groups. Sep. Purif. Technol. 2006, 50:15-21.
20. de Jong J., Schoemann V., Lannuzel D., Tison J., Mattielli N. High-accuracy determination of iron in seawater by isotope dilution multiple collector inductively coupled plasma mass spectrometry (ID-MC-ICP-MS) using nitrilotriacetic acid chelating resin for pre-concentration and matrix separation. Anal. Chim. Acta 2008, 623:126-139.
21. Demirbas A. Heavy metal adsorption onto agro-based waste materials: a review. J. Hazard. Mater. 2008, 157:220-229.
22. 2 groups. Environ. Sci. Technol. 2005, 39:1366-1377.
23. Dinu M.V., Dragan E.S. Heavy metals adsorption on some iminodiacetate chelating resins as a function of the adsorption parameters. React. Funct. Polym. 2008, 68:1346-1354.
24. Dinu M.V., Dragan E.S., Trochimczuk A.W. Sorption of Pb(II), Cd(II) and Zn(II) by iminodiacetate chelating resins in non-competitive and competitive conditions. Desalination 2009, 249:374-379.
25. Dragan E.S., Dinu M.V., Lisa G., Trochimczuk A.W. Study on metal complexes of chelating resins bearing iminodiacetate groups. Eur. Polym. J. 2009, 45:2119-2130.
26. El-Nahhal I.M., Zaggout F.R., Nassar M.A., El-Ashgar N.M., Maquet J., Babonneau F., Chehimi M.M. Synthesis, characterization and applications of immobilized iminodiacetic acid-modified silica. J. Sol Gel Sci. Technol. 2003, 28:255-265.
27. Flett D.S. Cobalt-nickel separation in hydrometallurgy: a review. Chem. Sustain. Dev. 2004, 12:81-91.
28. Foo K.Y., Hameed B.H. Insights into the modeling of adsorption isotherm systems. Chem. Eng. J. 2010, 156:2-10.
29. Freundlich H.M.F. Over the adsorption in solution. Zeitschrift für Physikalische Chemie 1906, 57:385-470.
30. Gasser M.S., Aly H.F. Kinetic and adsorption mechanism of Cu(II) and Pb(II) on prepared nanoparticle layered double hydroxide intercalated with EDTA. Colloid Surf. A 2009, 336:167-173.
31. Gode F., Pehlivan E. A comparative study of two chelating ion-exchange resins for the removal of chromium(III) from aqueous solution. J. Hazard. Mater. 2003, 100:231-243.
32. Goh K.H., Lim T.T., Dong Z. Application of layered double hydroxides for removal of oxyanions: a review. Water Res. 2008, 42:1343-1368.
33. Gustafsson J.P. Visual MINTEQ Ver 2.53 2007.
34. Gutmann N.H., Spiccia L., Turney T.W. Complexation of Cu(II) and Ni(II) by nitriloacetate intercalated in Zn-Cr layered double hydroxides. J. Mater. Chem. 2000, 10:1219-1224.
35. Hirata S., Kajiya T., Aihara M., Honda H., Shikino O. Determination of rare earth elements in seawater by on-line column preconcentration inductively coupled plasma mass spectrometry. Talanta 2002, 58:1185-1194.
36. Ho Y.S. Second-order kinetic model for the sorption of cadmium onto tree fern: a comparison of linear and non-linear methods. Water Res. 2006, 40:119-125.
37. Ho Y.S., Ng J.C.Y., McKay G. Kinetics of pollutant sorption by biosorbents: review. Sep. Purif. Methods 2000, 29:189-232.
38. Huang J., Ye M., Qu Y., Chu L., Chen R., He Q., Xu D. Pb (II) removal from aqueous media by EDTA-modified mesoporous silica SBA-15. J. Colloid Interface Sci. 2012, 385:137-146. http://dx.doi.org/10.1016/j.jcis.2012.06.054.
39. Hughes M., Rosenberg E. Characterization and applications of poly-acetate modified silica polyamine composites. Sep. Sci. Technol. 2007, 42:261-283.
40. Hughes M.A., Wood J., Rosenberg E. Polymer structure and metal ion selectivity in silica polyamine composites modified with sodium chloroacetate and nitriloacetic acid (NTA) anhydride. Ind. Eng. Chem. Res. 2008, 47:6765-6774.
41. Igwe C., Abia A.A. Adsorption kinetics and intraparticulate diffusivities for bioremediation of Co (II), Fe (II) and Cu (II) ions from waste water using modified and unmodified maize cob. Int. J. Phys. Sci. 2007, 2:119-127.
42. Igwe C., Abia A.A. Equilibrium sorption isotherm studies of Cd(II), Pb(II) and Zn(II) ions detoxification from waste water using unmodified and EDTA-modified maize husk. Electr. J. Biotechnol. 2007, 10:536-548.
43. Inoue K., Ohto K., Yoshizuka K., Yamaguchi T., Tanaka T. Adsorption of lead(II) ion on complexane types of chemically modified chitosan. Bull. Chem. Soc. Jpn. 1997, 70:2443-2447.
44. Inoue K., Yoshizuka K., Ohto K. Adsorptive separation of some metal ions by complexing agent types of chemically modified chitosan. Anal. Chim. Acta 1999, 388:209-218.
45. Jal P.K., Patel S., Mishra B.K. Chemical modification of silica surface by immobilization of functional groups for extractive concentration of metal ions. Talanta 2004, 62:1005-1028.
46. Jiang Y., Gao Q., Yu H., Chen Y., Deng F. Intensively competitive adsorption for heavy metal ions by PAMAM-SBA-15 and EDTA-PAMAMSBA-15 inorganic-organic hybrid materials. Micropor. Mesopor. Mater. 2007, 103:316-324.
47. Kameda T., Saito S., Umetsu Y. Mg-Al layered double hydroxide intercalated with ethylene-diaminetetraacetate anion: synthesis and application to the uptake of heavy metal ions from an aqueous solution. Sep. Purif. Technol. 2005, 47:20-26.
48. Karniz Júnior O., Gurgel L.V.A., Freitas R.P., Gil L.F. Adsorption of Cu(II), Cd(II), and Pb(II) from aqueous single metal solutions by mercerized cellulose and mercerized sugarcane bagasse chemically modified with EDTA dianhydride (EDTAD). Carbohydr. Polym. 2009, 77:643-650.
49. Kinniburgh D.G. General purpose adsorption isotherms. Environ. Sci. Technol. 1986, 20:895-904.
50. Kolodynska D. Cu(II), Zn(II), Ni(II), and Cd(II) complexes with HEDP removal from industrial effluents on different ion exchangers. Ind. Eng. Chem. Res. 2010, 49:2388-2400.
51. Kolodynska D., Hubicka H., Hubicki Z. Sorption of heavy metal ions from aqueous solutions in the presence of EDTA on monodisperse anion exchangers. Desalination 2008, 227:150-166.
52. Kumagai H., Inoue Y., Yokoyama T., Suzuki T.M. Chromatographic selectivity of rare earth elements on iminodiacetate-type chelating resins having spacer arms of different lengths: importance of steric flexibility of functional group in a polymer chelating resin. Anal. Chem. 1998, 70:4070-4073.
53. Kumar K.V., Siranesan S. Selection of optimum sorption kinetics: comparison of linear and non-linear method. J. Hazard. Mater. B 2006, 136:277-279.
54. Lagergren S. Zur Theorie Der Sogenannten Adsorption Geloster Stoffe 1898, 1-39. Kungliga Svenska Vetenskapsakademiens, Handlingar 24.
55. Langmuir I. The adsorption of gases on plane surfaces of glass, mica, and platinum. J. Am. Chem. Soc. 1918, 40:1361-1368.
56. Lee K.H., Oshima M., Takayanagi T., Motomizu S. Simultaneous determination of trace elements in river-water samples by ICP-MS in combination with a discrete microsampling technique after enrichment with a chitosan-based chelating resin. Anal. Sci. 2000, 16:731-738.
57. Lee K.H., Muroka Y., Oshima M., Motomizu S. Determination of heavy metals and rare earth elements in environmental samples by ICP-MS after solid phase preconcentration with chelating resin fibers and anion exchanger fibers. Anal. Sci. 2004, 20:183-187.
58. Lee J.M., Boyle E.A., Echegoyen-Sanz Y., Fitzsimmons J.N., Zhang R., Kayser R.A. Analysis of trace metals (Cu, Cd, Pb, and Fe) in seawater using single batch nitrilotriacetate resin extraction and isotope dilution inductively coupled plasma mass spectrometry. Anal. Chim. Acta 2011, 686:93-101.
59. Li L., Liu F., Jing X., Ling P., Li A. Displacement mechanism of binary competitive adsorption for aqueous divalent metal ions onto a novel IDA-chelating resin: isotherm and kinetic modeling. Water Res. 2011, 45:1177-1188.
60. Liang X.F., Hou W.G., Xu Y.M., Sun G.H., Wang L., Sun Y., Qin X. Sorption of lead ion by layered double hydroxide intercalated with diethylenetriaminepentaacetic acid. Colloid Surf. A 2010, 366:50-57.
61. Lin L.C., Juang R.S. Ion-exchange kinetics of Cu(II) and Zn(II) from aqueous solutions with two chelating resins. Chem. Eng. J. 2007, 132:205-213.
62. Ling P., Liu F., Li L., Jing X., Yin B., Chen K., Li A. Adsorption of divalent heavy metal ions onto IDA-chelating resins: simulation of physicochemical structures and elucidation of interaction mechanisms. Talanta 2010, 81:424-432.
63. Liu F., Li L., Ling P., Jing X., Li C., Li A., You X. Interaction mechanism of aqueous heavy metals onto a newly synthesized IDA-chelating resin: isotherms, thermodynamics and kinetics. Chem. Eng. J. 2011, 173:106-114.
64. Lohan M.C., Aguliar-Islas A.M., Franks R.P., Bruland K.W. Determination of iron and copper in seawater at pH 1.7 with a new commercially available chelating resin, NTA Superflow. Anal. Chim. Acta 2005, 530:121-129.
65. Madadrang C.J., Kim H.Y., Gao G., Wang N., Zhu J., Feng H., Gorring M., Kasner M.L., Hou S. Adsorption behavior of EDTA-graphene oxide for Pb (II) removal. ACS Appl. Mater. Interfaces 2012, 4:1186-1193.
66. Mendes F.D., Martins A.H. Selective sorption of nickel and cobalt from sulphate solutions using chelating resins. Int. J. Miner. Process. 2004, 74:359-371.
67. Motellier S., Pitsch H. Simultaneous analysis of some transition metals at ultra-trace level by ion-exchange chromatography with on-line preconcentration. J. Chromatogr. A 1996, 739:119-130.
68. Muraviev D. Ion Exchange 2000, 267-344. Marcel Dekker, New York, USA.
69. Nagib S., Inoue K., Yamaguchi T., Tamaru T. Recovery of Ni from a large excess of Al generated from spent hydrodesulfurization catalyst using picolylamine type chelating resin and complexane types of chemically modified chitosan. Hydrometallurgy 1999, 51:73-85.
70. Nesterenko P.N., Jones P. Single-column method of chelation ion chromatography for the analysis of trace metals in complex samples. J. Chromatogr. A 1997, 770:129-135.
71. +) during on-line preconcentration and atomic detection of trace metals in natural waters. Anal. Chim. Acta 1997, 351:311-317.
72. Nowack B. Environmental chemistry of aminopolycarboxylate chelating agents. Environ. Sci. Technol. 2002, 36:4009-4016.
73. Nowack B., Sigg L. Adsorption of EDTA and metal-EDTA complexes onto goethite. J. Colloid Interface Sci. 1996, 177:106-121.
74. Nowack B., VanBriesen J.M. Chelating agents in the environment. ACS Symposium Series 2005, 1-18. American Chemical Society, Washington, DC. B. Nowack, J.M. VanBriesen (Eds.).
75. Nörtemann B. Biodegradation of chelating agents: EDTA, DTPA, PDTA, NTA, and EDDS. ACS Symposium Series 910 2005, 150-170. American Chemical Society, Washington, DC. B. Nowack, J.M. VanBriesen (Eds.).
76. Ong S.-T., Lee W.-N., Keng P.-S., Lee S.-L., Hung Y.-T., Ha S.-T. Equilibrium studies and kinetics mechanism for the removal of basic and reactive dyes in both single and binary systems using EDTA modified rice husk. Int. J. Phys. Sci. 2010, 5:582-595.
77. Oshita K., Sabarudin A., Takayanagi T., Oshima M., Motomizu S. Adsorption behavior of uranium(VI) and other ionic species on cross-linked chitosan resins modified with chelating moieties. Talanta 2009, 79:1031-1035.
78. 2+ ions by layered double hydroxides intercalated with the chelating agents diethylenetriaminepentaacetate and meso-2,3-dimercaptosuccinate. Appl. Clay Sci. 2009, 43:125-129.
79. 2+ ions from aqueous solution by Lewatit CNP 80. J. Hazard. Mater. 2007, 140:299-307.
80. Peng H., Wang S., Tang J., Tong G., Huang K. Preparation of chelating polymer grafted magnetic adsorbent and its application for removal of Pb (II) ions. J. Wuhan Univ. Techn. 2011, 26:1108-1113.
81. 2+ from aqueous single metal solutions and electroplating wastewater with wood sawdust and sugarcane bagasse modified with EDTA dianhydride (EDTAD). J. Hazard. Mater. 2010, 176:856-863.
82. 2+ on Zn-Al layered double hydroxide intercalated with EDTA. Appl. Clay Sci. 2006, 32:245-251.
83. Piszczek L., Ignatowicz A., Kielbasa J. Application of cyclic voltammetry for stoichiometry determination of Ni(II), Co(II), and Cd(II) complex compounds with polyaminopolycarboxylic acids. J. Chem. Educ. 1988, 65:171-173.
84. Pitter P., Sýkora V. Biodegradability of ethylenediamine-based complexing agents and related compounds. Chemosphere 2001, 44:823-826.
85. Plazinski W., Rudzinski W., Plazinska A. Theoretical models of sorption kinetics including a surface reaction mechanism: a review. Adv. Colloid Interface Sci. 2009, 152:2-13.
86. Pshinko G.N., Kosorukov A.A., Puzyrnaya L.N., Goncharuk V.V. Layered double hydroxides intercalated with EDTA as effective sorbents for U(VI) recovery from wastewater. Radiochemistry 2011, 53:303-307.
87. Rahmi D., Zhu Y., Fujimori E., Umemura T., Haraguchi H. Multielement determination of trace metals in seawater by ICP-MS with aid of down-sized chelating resin-packed minicolumn for preconcentration. Talanta 2007, 72:600-606.
88. Repo E., Kurniawan T.A., Warchol J.K., Sillanpää M.E.T. Removal of Co(II) and Ni(II) ions from contaminated water using silica gel functionalized with EDTA and/or DTPA as chelating agents. J. Hazard. Mater. 2009, 171:1071-1080.
89. Repo E., Warchol J.K., Kurniawan T.A., Sillanpää M.E.T. Adsorption of Co(II) and Ni(II) by EDTA- and/or DTPA-modified chitosan: kinetic and equilibrium modeling. Chem. Eng. J. 2010, 161:73-82.
90. Repo E., Petrus R., Sillanpää M., Warchol J. Equilibrium studies on the adsorption of Co(II) and Ni(II) by modified silica gels: one-component and binary systems. Chem. Eng. J. 2011, 172:376-385.
91. Repo E., Warchol J.K., Bhatnagar A., Sillanpää M. Heavy metals adsorption by novel EDTA-modified chitosan-silica hybrid materials. J. Colloid Interface Sci. 2011, 358:261-267.
92. Repo E., Malinen L., Koivula R., Harjula R., Sillanpää M. Capture of Co(II) from its aqueous EDTA-chelate by DTPA-modified silica gel and chitosan. J. Hazard. Mater. 2011, 187:122-132.
93. 2+ scavengers: removal kinetics and sorbent stability. J. Colloid Interface Sci. 2009, 331:425-431.
94. Seggiani M., Vitolo S., D'Antone S. Recovery of nickel from Orimulsion fly ash by iminodiacetic acid chelating resin. Hydrometallurgy 2006, 81:9-14.
95. Sharma R.K., Mittal S., Koel M. Analysis of trace amounts of metal ions using silica-based chelating resins: a green analytical method. Crit. Rev. Anal. Chem. 2003, 33:183-197.
96. Shiraishi Y., Nishimura G., Hirai T., Komasawa I. Separation of transition metals using inorganic adsorbents modified with chelating ligands. Ind. Eng. Chem. Res. 2002, 41:5065-5070.
97. Sillanpää M. Environmental fate of EDTA and DTPA. Rev. Environ. Contam. Toxicol. 1997, 152:85-111.
98. Silva V.L., Carvalho R., Freitas M.P., Tormena C.F., Melo W.C. Spectrometric and theoretical investigation of the structures of Cu and Pb/DTPA complexes. Struct. Chem. 2007, 18:605-609.
99. 13C NMR and theoretical investigation. Spectrochim. Acta A 2007, 68:1197-1200.
100. Sohrin Y., Urushihara S., Nakatsuka S., Kono T., Higo E., Minami T., Norisuye K., Umetani S. Multielemental determination of GEOTRACES key trace metals in seawater by ICPMS after preconcentration using an ethylenediaminetriacetic acid chelating resin. Anal. Chem. 2008, 80:6267-6273.
101. Song L., Zhao X., Fu J., Wang X., Sheng Y., Liu X. DFT investigation of Ni (II) adsorption onto MA-DTPA/PVDF chelating membrane in the presence of coexistent cations and organic acids. J. Hazard. Mater. 2012, 199-200:433-439.
102. Sucholeiki I. New developments in solid phase synthesis supports. Mol. Divers. 1999, 4:25-30.
103. Sugrue E., Nesterenko P., Paull B. Ion exchange properties of monolithic and particle type iminodiacetic acid modified silica. J. Sep. Sci. 2004, 27:921-930.
104. Tarasov K.A., O'Hare D., Isupov V.P. Solid state chelation of metal ions by ethylenediaminetetraacetate intercalated in a layer double hydroxide. Inorg. Chem. 2003, 42:1919-1927.
105. Tikhonov V.E., Radigina L.A., Yamskov Y.A. Metal-chelating chitin derivatives via reaction of chitosan with nitrilotriacetic acid. Carbohydr. Res. 1996, 290:33-41.
106. Trivedi P., Axe L. Predicting divalent metal sorption to hydrous Al, Fe, and Mn oxides. Environ. Sci. Technol. 2001, 35:1779-1784.
107. Wan Ngah W.S., Hanafiah M.A.K.M. Removal of heavy metal ions from wastewater by chemically modified plant wastes as adsorbents: a review. Bioresour. Technol. 2008, 99:3935-3948.
108. Wang C.C., Chang C.Y., Chen C.Y. Study on metal ion adsorption of bifunctional chelating/ion-exchange resins. Macromol. Chem. Phys. 2001, 202:882-890.
109. Wang C.C., Chen C.Y., Chang C.Y. Synthesis of chelating resins with iminodiacetic acid and its wastewater treatment application. J. Appl. Polym. Sci. 2002, 84:1353-1362.
110. Wang L., Yang L., Li Y., Zhang Y., Ma X., Ye Z. Study on adsorption mechanism of Pb(II) and Cu(II) in aqueous solution using PS-EDTA resin. Chem. Eng. J. 2010, 163:364-372.
111. Warchoł J. Equilibrium Study on Sorption of Ionic Species in Liquid-solid Systems 2012, Polish Academy of Science, Łódź, (in polish).
112. Warnken K.W., Tang D., Gill G.A., Santschi P.H. Performance optimization of a commercially available iminodiacetate resin for the determination of Mn, Ni, Cu, Cd and Pb by on-line preconcentration inductively coupled plasma-mass spectrometry. Anal. Chim. Acta 2000, 423:265-276.
113. Willie S.N., Sturgeon R.E. Determination of transition and rare earth elements in seawater by flow injection inductively coupled plasma time-of-flight mass spectrometry. Spectrochim. Acta B 2001, 56:1707-1716.
114. Yang L., Li Y., Wang L., Zhang Y., Ma X., Ye Z. Preparation and adsorption performance of a novel bipolar PS-EDTA resin in aqueous phase. J. Hazard. Mater. 2010, 180:98-105.
115. Yang L., Li Y., Jin X., Ye Z., Ma X., Wang L., Liu Y. Synthesis and characterization of a series of chelating resins containing amino/imino-carboxyl groups and their adsorption behavior for lead in aqueous phase. Chem. Eng. J. 2011, 168:115-124.
116. 2+ by EDTAD-modified biomass of baker's yeast. Bioresour. Technol. 2008, 99:2588-2593.
117. 2+ removal by PVA/EDTA resin in polluted water. J. Hazard. Mater. 2010, 178:1046-1054.
118. Zhao X., Song L., Fu J., Tang P., Liu F. Adsorption characteristics of Ni(II) onto MA-DTPA/PVDF chelating membrane. J. Hazard. Mater. 2011, 189:732-740.
119. Zhao X., Song L., Zhang Z., Wang R., Fu J. Adsorption investigation of MA-DTPA chelating resin for Ni(II) and Cu(II) using experimental and DFT methods. J. Mol. Struct. 2011, 986:68-74.
120. Zeldowitsch J. Adsorption site energy distribution. Acta Phys. Chim URSS 1934, 1:961-973.