Equilibrium studies on the adsorption of Co(II) and Ni(II) by modified silica gels: One-component and binary systems

Chemical Engineering Journal

Volumn 172, Issue 1, 2011, Pages 376-385

  Repo, Eveliina ^a,c   Petrus, Roman ^b   Sillanpää, Mika ^a,c   Warchoł, Jolanta K ^b  

^a LAPPEENRANTA UNIVERSITY OF TECHNOLOGY   (Finland)

^b RZESZOW UNIVERSITY OF TECHNOLOGY   (Poland)

^c UNIVERSITY OF EASTERN FINLAND   (Finland)

Author keywords

Adsorption isotherm; Chelating agent; Modeling; One component; Two component

Indexed keywords

ACTIVE SITE; ADSORPTION CAPACITIES; ADSORPTION EQUILIBRIA; BINARY SYSTEMS; CHELATING AGENT; EQUILIBRIUM PARAMETERS; EQUILIBRIUM STUDY; GLOBAL MINIMA; HIGH ENERGY; INITIAL GUESS; ITERATION PROCEDURE; MODIFIED SILICA GEL; NI ADSORPTIONS; NON-LINEAR PARAMETERS; OBJECTIVE FUNCTIONS; ONE-COMPONENT; ONE-COMPONENT SYSTEMS; PARAMETER VALUES; REDLICH-PETERSON MODELS; TWO-COMPONENT;

ADSORPTION ISOTHERMS; CHELATION; DRIERS (MATERIALS); GELS; PARAMETER ESTIMATION; SILICA; SILICA GEL; ADSORPTION; MODELS; NICKEL;

ADSORPTION; SILICA GEL;

EID: 79960979426     PISSN: 13858947     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cej.2011.06.019     Document Type: Article

References (44)

1. Jal P.K., Dutta R.K., Sudarshan M., Saha A., Bhattacharyya S.N., Chintalapudi S.N., Mishra B.K. Extraction of metal ions using chemically modified silica gel: a PIXE analysis. Talanta 2001, 55:233-240.
2. Jal P.K., Patel S., Mishra B.K. Chemical modification of silica surface by immobilization of functional groups for extractive concentration of metal ions. Talanta 2004, 62:1005-1028.
3. Venkatesan K.A., Sukumaran V., Antony M.P., Vasudeva Rao P.R. Extraction of uranium by amine, amide and benzamide grafted covalently on silica gel. J. Radioanal. Nucl. Chem. 2004, 260:443-450.
4. Sarkar A.R., Datta P.K., Sarkar M. Sorption recovery of metal ions using silica gel modified with salicylaldoxime. Talanta 1996, 43:1857-1862.
5. Garg B.S., Sharma R.K., Bist J.S., Bhojak N., Mittal S. Separation and preconcentration of metal ions and their estimation in vitamin. Talanta 1999, 48:49-55.
6. Kim J.S., Park J.C., Yi J. Zinc ion removal from aqueous solutions using modified silica impregnated with 2-ethylhexyl-2-ethylhexyl phosphonic acid. Sep. Sci. Technol. 2000, 35:1901-1916.
7. El-Nahhal I.M., Zaggout F.R., Nassar M.A., El-Ashgar N.M., Maquet J., Babonneau F., Chehimi M.M. Synthesis, characterization and applications of immobilized iminodiacetic acid-modified silica. J. Sol-Gel Sci. Technol. 2003, 28:255-265.
8. Repo E., Kurniawan T.A., Warchol J.K., Sillanpää M.E.T. Removal of Co(II) and Ni(II) ions from contaminated water using silica gel functionalized with EDTA and/or DTPA as chelating agents. J. Hazard. Mater. 2009, 171:1071-1080.
9. Kursunlu A.N., Guler E., Dumrul H., Kocyigit O., Gubbuk I.H. Chemical modification of silica gel with synthesized new Schiff base derivates and sorption studies of cobalt (II) and nickel (II). Appl. Surf. Sci. 2009, 255:8798-8803.
10. Shiraishi Y., Nishimura G., Hirai T., Komasawa I. Separation of transition metals using inorganic adsorbents modified with chelating ligands. Ind. Eng. Chem. Res. 2002, 41:5065-5070.
11. Ruthven D.M. Principles of Adsorption and Adsorption Process 1984, Wiley-Interscience, New York, p. 108.
12. Seidel-Morgenstern A., Guiochon G. Modelling of the competitive isotherms and the chromatographic separation of two enantiomers. Chem. Eng. Sci. 1993, 48:2787-2797.
13. Limousin G., Gaudet J.-P., Charlet L., Szenknect S., Barthe V., Krimissa M. Sorption isotherms: a review on physical bases, modeling and measurement. Appl. Geochem. 2007, 22:249-275.
14. Kinniburgh D.G. General purpose adsorption isotherms. Environ. Sci. Technol. 1986, 20:895-904.
15. Ho Y.S., Porter J.F., McKay G. Equilibrium isotherm studies for the sorption of divalent metal ions onto peat: copper, nickel and lead single component systems. Water Air Soil Pollut. 2002, 141:1-33.
16. Allen S.J., Mckay G., Porter J.F. Adsorption isotherm models for basic dye adsorption by peat in single and binary component systems. J. Colloid. Interface Sci. 2004, 280:322-333.
17. Kumar K.V., Porkodi K. Relation between some two- and three-parameter isotherm models for the sorption of methylene blue onto lemon peel. J. Hazard. Mater. 2006, 138:633-635.
18. Seferlis P., Hrymak A.N. Sensitivity analysis for chemical process optimization. Comput. Chem. Eng. 1996, 20:1177-1200.
19. Misaelides P., Zamboulis D., Sarridis P., Warchoł J., Godelitsas A. Chromium (VI) uptake by polyhexamethylene-guanidine-modified natural zeolitic materials. Micropor. Mesopor. Mater. 2008, 108:162-167.
20. Kumar K.V., Sivanesan S. Prediction of optimum sorption isotherm: comparison of linear and non-linear method. J. Hazard. Mater. 2005, B126:198-201.
21. Kumar D., Singh A., Gaur J.P. Mono-component versus binary isotherm models for Cu(II) and Pb(II) sorption form binary metal solution by the green alga Pithophora oedogoni. Bioresour. Technol. 2008, 97:8280-8287.
22. Myers A.L., Prausnitz J.M. Prediction of the adsorption isotherm by the principle of corresponding states. Chem. Eng. Sci. 1965, 20:549-556.
23. Al-Asheh S., Banat F., Al-Omari R., Duvnjak Z. Predictions of binary sorption isotherms for the sorption of heavy metals by pine bark using single isotherm data. Chemosphere 2000, 41:659-665.
24. Apiratikul R., Pavasant P. Sorption isotherm model for binary component sorption of copper, cadmium, and lead ions using dried green macroalga, Caulerpa lentillifera. Chem. Eng. J. 2006, 119:135-145.
25. Papageorgiou S.K., Katsaros F.K., Kouvelos E.P., Kanellopoulos N.K. Prediction of binary adsorption isotherms of Cu2+, Cd2+ and Pb2+ on calcium alginate beads from single adsorption data. J. Hazard. Mater. 2009, 162:1347-1354.
26. Xiao B., Thomas K.M. Competitive adsorption of aqueous metal ions on an oxidized nanoporous activated carbon. Langmuir 2004, 20:4566-4578.
27. Vieira R.S., Guibal E., Silva E.A., Beppu M.M. Adsorption and desorption of binary mixtures of copper and mercury on natural and crosslinked chitosan membranes. Adsorption 2007, 13:603-611.
28. Al-Duri B. A review in equilibrium in single and multicomponent liquid adsorption systems. Rev. Chem. Eng. 1995, 11:101-143.
29. Pagnanelli F., Trifoni M., Beolchini F., Esposito A., Toro L., Veglio F. Equilibrium biosorption studies in single and multi-metal systems. Process. Biochem. 2001, 37:115-124.
30. Asnin L., Kaczmarski K., Guiochon G. Empirical development of a binary adsorption isotherm based on the single-component isotherms in the framework of a two-site model. J. Chromatogr. A 2007, 1138:158-168.
31. Guiochon G., Felinger A., Shirazi D.G., Katti A.M. Fundamentals of Preparative and Nonlinear Chromatography 2006, Elsevier, NY.
32. Redlich O., Peterson D.L. A useful adsorption isotherm. Z. Phys. Chem. 1959, 63:1024-1026.
33. Marquardt D.W. An algorithm for least-square optimization of non linear parameter. J. Soc. Ind. Appl. Math. 1963, 11:431-441.
34. Chapra S.C., Canale R.P. Numerical Methods for Engineers 1990, McGraw Hill International, USA. 2nd ed.
35. Kumar K.V., Sivanesan S. Equilibrium data, isotherm parameters and process design for partial and complete isotherm of methylene blue onto activated carbon. J. Hazard. Mater. 2006, B134:237-244.
36. Chutkowski M., Petrus R., Warchol J., Koszelnik P. Sorption equilibrium of heavy metals removal from aqueous solutions statistical verification of mathematical models. Przem. Chem. 2008, 87:436-438.
37. Zhang F., Reynolds A.C., Oliver D.S. An initial guess for the Levenberg-Marquardt algorithm for conditioning a stochastic channel to pressure data. Math. Geol. 2003, 35:67-88.
38. Cernik M., Borkovec M., Westall J.C. Regularized least-squares methods for the calculation of discrete and continuous affinity distributions for heterogeneous sorbents. Environ. Sci. Technol. 1995, 29:413-425.
39. Foo K.Y., Hameed B.H. Insight into the modeling of adsorption isotherm systems. Chem. Eng. J. 2010, 156:2-10.
40. Repo E., Malinen L., Koivula R., Harjula R., Sillanpää M. Capture of Co(II) from its aqueous EDTA-chelate by DTPA-modified silica gel and chitosan. J. Hazard. Mater. 2011, 187:122-132.
41. Petrus R., Warchol J.K. Heavy metal removal by clinoptilolite. An equilibrium study in multi-component systems. Water Res. 2005, 39:819-830.
42. Antoniadis V., Tsadilas C.D., Ashworth D.J. Monometal and competitive adsorption of heavy metals by sewage sludge-amended soil. Chemosphere 2007, 68:489-494.
43. Kaczmarski K., Zhou D., Gubernak M., Guiochon G. Equivalent models of indanol isomers adsorption on cellulose tribenzoate. Biotechnol. Prog. 2003, 19:455-463.
44. Triantafyllou S., Christodolou E., Neou-Syngouna P. Removal of nickel and cobalt from aqueous solutions by Na-activated bentonite. Clays Clay Miner. 1999, 47:567-572.