Molecular origin of rapid versus slow intramolecular electron transfer in the catalytic cycle of the multicopper oxidases

Journal of the American Chemical Society

Volumn 135, Issue 33, 2013, Pages 12212-12215

  Heppner, David E ^a   Kjaergaard, Christian H ^a   Solomon, Edward I ^a  

^a STANFORD UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYTIC TURNOVER; COMPUTATIONAL MODEL; INTRAMOLECULAR ELECTRON TRANSFER; ISOTOPE MEASUREMENTS; KINETIC MEASUREMENT; MULTICOPPER OXIDASE; PROTON-COUPLED ELECTRON TRANSFER; REDUCTIVE CLEAVAGE;

ELECTRON TRANSITIONS; ENZYMES; ISOTOPES; PROTONS;

REDUCTION;

COPPER DERIVATIVE; ISOTOPE; OXIDOREDUCTASE; PROTON;

ARTICLE; CATALYSIS; CRYSTALLOGRAPHY; ELECTRON TRANSPORT; KINETICS; REDUCTION;

BIOCATALYSIS; COPPER; ELECTRON TRANSPORT; OXIDOREDUCTASES; QUANTUM THEORY;

EID: 84883066464     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja4064525     Document Type: Article

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