메뉴 건너뛰기




Volumn 1, Issue 6, 2010, Pages 1003-1007

Thiolate-Protected Au24(SC2H4Ph) 20 nanoclusters: Superatoms or not?

Author keywords

Nanoparticles and nanostructures

Indexed keywords

AU NANOCLUSTERS; ELECTROSPRAY IONIZATION MASS SPECTROMETRY; ELEMENTAL ANALYSIS; HIGHEST OCCUPIED MOLECULAR ORBITAL; LOWEST UNOCCUPIED MOLECULAR ORBITAL; OPTICAL ABSORPTION SPECTRUM; SUPERATOMS; THIOLATES; VALENCE ELECTRON;

EID: 77950175471     PISSN: None     EISSN: 19487185     Source Type: Journal    
DOI: 10.1021/jz100133n     Document Type: Article
Times cited : (116)

References (43)
  • 2
    • 77952083987 scopus 로고    scopus 로고
    • Quantum-sized thiolate protected gold nanoclusters
    • Online early access DOI:10.1039/B9NR00160C
    • Jin, R. Quantum-Sized Thiolate Protected Gold Nanoclusters. Nanoscale [Online early access]. DOI:10.1039/B9NR00160C.
    • Nanoscale
    • Jin, R.1
  • 3
    • 0345977867 scopus 로고
    • Large clusters and colloids. metals in the embryonic state
    • Schmid, G. Large clusters and colloids. Metals in the embryonic state. Chem. Rev. 1992, 92, 1709-1727.
    • (1992) Chem. Rev. , vol.92 , pp. 1709-1727
    • Schmid, G.1
  • 5
    • 27544478678 scopus 로고    scopus 로고
    • Nanosized [pd52(co)36(pet3)14] and [pd66(co)45-(pet3)16] clusters based on a hypothetical pd38 vertex-truncated 3 octahedron
    • Mednikov, E. G.; Ivanov, S. A.; Slovokhotova, I. V.; Dahl, L. F. Nanosized [Pd52(CO)36(PEt3)14] and [Pd66(CO)45-(PEt3)16] Clusters Based on a Hypothetical Pd38 Vertex-Truncated 3 Octahedron. Angew. Chem., Int. Ed. 2005, 44, 6848-6954.
    • (2005) Angew. Chem., Int. Ed. , vol.44 , pp. 6848-6954
    • Mednikov, E.G.1    Ivanov, S.A.2    Slovokhotova, I.V.3    Dahl, L.F.4
  • 6
    • 33845340765 scopus 로고    scopus 로고
    • Supramolecular intercluster compounds consisting of gold clusters and keggin anions
    • Schulz-Dobrick, M.; Jansen, M. Supramolecular Intercluster Compounds Consisting of Gold Clusters and Keggin Anions. Eur. J. Inorg. Chem. 2006, 4498-4502.
    • (2006) Eur. J. Inorg. Chem. , pp. 4498-4502
    • Schulz-Dobrick, M.1    Jansen, M.2
  • 7
    • 28444441584 scopus 로고    scopus 로고
    • Size-controlled synthesis of near-monodisperse gold nanoparticles in the 1-4 nmrange using polymeric stabilizers
    • Hussain, I.; Graham, S.; Wang, Z. X.; Tan, B.; Sherrington, D. C.; Rannard, S. P.; Cooper, A. I.; Brust, M. Size-Controlled Synthesis of Near-Monodisperse Gold Nanoparticles in the 1-4 nmRange Using Polymeric Stabilizers. J. Am. Chem. Soc. 2005, 127, 16398-16399.
    • (2005) J. Am. Chem. Soc. , vol.127 , pp. 16398-16399
    • Hussain, I.1    Graham, S.2    Wang, Z.X.3    Tan, B.4    Sherrington, D.C.5    Rannard, S.P.6    Cooper, A.I.7    Brust, M.8
  • 9
    • 2442584651 scopus 로고    scopus 로고
    • Electrochemistry and optical absorbance and luminescence of molecule-like au38 nanoparticles
    • Lee, D.; Donkers, R. L.; Wang, G. L.; Harper, A. S.; Murray, R. W. Electrochemistry and Optical Absorbance and Luminescence of Molecule-like Au38 Nanoparticles. J. Am. Chem. Soc. 2004, 126, 6193-6199.
    • (2004) J. Am. Chem. Soc. , vol.126 , pp. 6193-6199
    • Lee, D.1    Donkers, R.L.2    Wang, G.L.3    Harper, A.S.4    Murray, R.W.5
  • 10
    • 25844483822 scopus 로고    scopus 로고
    • Large-scale synthesis of thiolated au25 clusters via ligand exchange reactions of phosphine-stabilized au11 clusters
    • Shichibu, Y.; Negishi, Y.; Tsukuda, T.; Teranishi, T. Large-Scale Synthesis of Thiolated Au25 Clusters via Ligand Exchange Reactions of Phosphine-Stabilized Au11 Clusters. J. Am. Chem. Soc. 2005, 127, 13464-13465.
    • (2005) J. Am. Chem. Soc. , vol.127 , pp. 13464-13465
    • Shichibu, Y.1    Negishi, Y.2    Tsukuda, T.3    Teranishi, T.4
  • 12
    • 38349038607 scopus 로고    scopus 로고
    • Crystal structure,electrochemical and optical properties of [au9(pph3) 8](no3)3
    • Wen, F.; Englert, U.; Gutrath, B.; Simon, U. Crystal Structure, Electrochemical and Optical Properties of [Au9(PPh3)8](NO3)3. Eur. J. Inorg. Chem. 2008, 106-111.
    • (2008) Eur. J. Inorg. Chem. , pp. 106-111
    • Wen, F.1    Englert, U.2    Gutrath, B.3    Simon, U.4
  • 13
    • 52449083026 scopus 로고    scopus 로고
    • An organometallic approach to gold nanoparticles: Synthesis and X-ray structure of co-protected au21fe10, au22fe12, au28fe14, and au34fe14 clusters
    • Int. Ed.
    • Femoni, C.; Iapalucci, M. C.; Longoni, G.; Tiozzo, C.; Zacchini, S. An Organometallic Approach to Gold Nanoparticles: Synthesis and X-ray Structure of CO-Protected Au21Fe10, Au22Fe12, Au28Fe14, and Au34Fe14 Clusters. Angew. Chem., Int. Ed. 2008, 47, 6666-6669.
    • (2008) Angew. Chem. , vol.47 , pp. 6666-6669
    • Femoni, C.1    Iapalucci, M.C.2    Longoni, G.3    Tiozzo, C.4    Zacchini, S.5
  • 14
    • 65649103349 scopus 로고    scopus 로고
    • Large scale synthesis of dodecanethiol stabilized au38 clusters
    • Qian, H.; Zhu, M.; Andersen, U. N.; Jin, R. Facile, Large Scale Synthesis of Dodecanethiol Stabilized Au38 Clusters. J. Phys. Chem. A 2009, 113, 4281-4284.
    • (2009) J. Phys. Chem. A , vol.113 , pp. 4281-4284
    • Qian, H.1    Zhu, M.2    Andersen, U.N.3    Facile, J.R.4
  • 16
    • 65249091397 scopus 로고    scopus 로고
    • Structure and bonding in the ubiquitous icosahedral metallic gold cluster au144(sr)60
    • Lopez-Acevedo, O.; Akola, J.; Whetten, R. L.; Gronbeck, H.; Hakkinen, H. Structure and Bonding in the Ubiquitous Icosahedral Metallic Gold Cluster Au144(SR)60. J. Phys. Chem. C 2009, 113, 5035-5038.
    • (2009) J. Phys. Chem. C , vol.113 , pp. 5035-5038
    • Lopez-Acevedo, O.1    Akola, J.2    Whetten, R.L.3    Gronbeck, H.4    Hakkinen, H.5
  • 17
    • 70349753178 scopus 로고    scopus 로고
    • Thiolate-protected au20(sr) 16 cluster: Prolate au8 core with new [au3(sr)4] staple motif
    • Pei, Y.; Gao, Y.; Shao, N.; Zeng, X. C. Thiolate-Protected Au20(SR)16 Cluster: Prolate Au8 Core with New [Au3(SR)4] Staple Motif. J. Am. Chem. Soc. 2009, 131, 13619-13621.
    • (2009) J. Am. Chem. Soc. , Issue.131 , pp. 13619-13621
    • Pei, Y.1    Gao, Y.2    Shao, N.3    Zeng, X.C.4
  • 18
    • 70350163200 scopus 로고    scopus 로고
    • What protects the core when the thiolated au cluster is extremely small?
    • Jiang, D.; Chen, W.; Whetten, R. L.; Chen, Z. What Protects the Core When the Thiolated Au Cluster is Extremely Small? J. Phys. Chem. C 2009, 113, 16983-16987.
    • (2009) J. Phys. Chem. , vol.C , Issue.113 , pp. 16983-16987
    • Jiang, D.1    Chen, W.2    Whetten, R.L.3    Chen, Z.4
  • 20
    • 17144403270 scopus 로고    scopus 로고
    • Glutathione-protected gold clusters revisited: Bridging the gap between gold(i)-thiolate complexes and thiolate-protected gold nanocrystals
    • Negishi, Y.; Nobusada, K.; Tsukuda, T. Glutathione-Protected Gold Clusters Revisited: Bridging the Gap between Gold(I)-Thiolate Complexes and Thiolate-Protected Gold Nanocrystals. J. Am. Chem. Soc. 2005, 127, 5261-5270.
    • (2005) J. Am. Chem. Soc. , Issue.127 , pp. 5261-5270
    • Negishi, Y.1    Nobusada, K.2    Tsukuda, T.3
  • 21
    • 68649108909 scopus 로고    scopus 로고
    • Stability of the two au-s binding modes in au25(sg)18 nanoclusters probed by nmr and optical spectroscopy
    • Wu, Z.; Jin, R. Stability of the Two Au-S Binding Modes in Au25(SG)18 Nanoclusters Probed by NMR and Optical Spectroscopy. ACS Nano 2009, 3, 2036-2042.
    • (2009) ACS Nano , vol.3 , pp. 2036-2042
    • Wu, Z.1    Jin, R.2
  • 24
    • 69049086648 scopus 로고    scopus 로고
    • Mass spectrometric identification of au68(sr)34 molecular gold nanoclusters with 34-electron shell closing
    • Dass, A. Mass Spectrometric Identification of Au68(SR)34 Molecular Gold Nanoclusters with 34-Electron Shell Closing. J. Am. Chem. Soc. 2009, 131, 11666-11667.
    • (2009) J. Am. Chem. Soc. , vol.131 , pp. 11666-11667
    • Dass, A.1
  • 25
    • 65949098657 scopus 로고    scopus 로고
    • Atomically monodispersed and fluorescent sub-nanometer gold clusters created by biomolecule-assisted etching of nanometer-sized gold particles and rods
    • Zhou, R.; Shi, M.; Chen, X.; Wang, M.; Chen, H. Atomically Monodispersed and Fluorescent Sub-Nanometer Gold Clusters Created by Biomolecule-Assisted Etching of Nanometer-Sized Gold Particles and Rods. Chem.;Eur. J. 2009, 15, 4944-4951.
    • (2009) Chem.;Eur. J. , vol.15 , pp. 4944-4951
    • Zhou, R.1    Shi, M.2    Chen, X.3    Wang, M.4    Chen, H.5
  • 26
    • 44449094643 scopus 로고    scopus 로고
    • Chiral inversion of gold nanoparticles
    • Gautier, C.; Burgi, T. Chiral Inversion of Gold Nanoparticles. J. Am. Chem. Soc. 2008, 130, 7077-7084.
    • (2008) J. Am. Chem. Soc. , vol.130 , pp. 7077-7084
    • Gautier, C.1    Burgi, T.2
  • 27
    • 27644549143 scopus 로고    scopus 로고
    • Large optical activity of gold nanocluster enantiomers induced by a pair of optically active penicillamines
    • Yao, H.; Miki, K.; Nishida, N.; Sasaki, A.; Kimura, K. Large Optical Activity of Gold Nanocluster Enantiomers Induced by a Pair of Optically Active Penicillamines. J. Am. Chem. Soc. 2005, 127, 15536-15543.
    • (2005) J. Am. Chem. Soc. , vol.127 , pp. 15536-15543
    • Yao, H.1    Miki, K.2    Nishida, N.3    Sasaki, A.4    Kimura, K.5
  • 28
    • 75749142622 scopus 로고    scopus 로고
    • Origin of intense chiroptical effects in undecagold subnanometer particles
    • Provorse, M. R.; Aikens, C. M. Origin of Intense Chiroptical Effects in Undecagold Subnanometer Particles. J. Am. Chem. Soc. 2010, 132, 1302-1310.
    • J. Am. Chem. Soc. , vol.2010 , Issue.132 , pp. 1302-1310
    • Provorse, M.R.1    Aikens, C.M.2
  • 29
    • 76149108433 scopus 로고    scopus 로고
    • On the origin of the optical activity displayed by chiral-ligand- protected metallic nanoclusters
    • Sanchez-Castillo, A.; Noguez, C.; Garzon, I. L. On the Origin of the Optical Activity Displayed by Chiral-Ligand-Protected Metallic Nanoclusters. J. Am. Chem. Soc. 2010, 132, 1504-1505.
    • J. Am. Chem. Soc. , vol.2010 , Issue.132 , pp. 1504-1505
    • Sanchez-Castillo, A.1    Noguez, C.2    Garzon, I.L.3
  • 30
    • 70349155912 scopus 로고    scopus 로고
    • Effect of electronic structures of au clusters stabilized by poly(n-vinyl-2-pyrrolidone) on aerobic oxidation catalysis
    • Tsunoyama, H.; Ichikuni, N.; Sakurai, H.; Tsukuda, T. Effect of electronic structures of Au clusters stabilized by poly(N-vinyl-2-pyrrolidone) on aerobic oxidation catalysis. J. Am. Chem. Soc. 2009, 131, 7086-7093.
    • (2009) J. Am. Chem. Soc. , vol.131 , pp. 7086-7093
    • Tsunoyama, H.1    Ichikuni, N.2    Sakurai, H.3    Tsukuda, T.4
  • 31
    • 76349100747 scopus 로고    scopus 로고
    • Atomically precise au25(sr)18 nanoparticles as catalysts for selective hydrogenation of r,?-unsaturated ketones and aldehydes
    • Int. Ed.
    • Zhu, Y.; Qian, H.; Drake, B. A.; Jin, R. Atomically Precise Au25(SR)18 Nanoparticles as Catalysts for Selective Hydrogenation of R,?-Unsaturated Ketones and Aldehydes. Angew. Chem., Int. Ed. 2010, 49, 1295-1298.
    • Angew. Chem. , vol.2010 , Issue.49 , pp. 1295-1298
    • Zhu, Y.1    Qian, H.2    Drake, B.A.3    Jin, R.4
  • 34
    • 38649127545 scopus 로고    scopus 로고
    • Kinetically controlled,high-yield synthesis of au25 clusters
    • Zhu, M.; Lanni, E.; Garg, N.; Bier, M. E.; Jin, R. Kinetically Controlled, High-Yield Synthesis of Au25 Clusters. J. Am. Chem. Soc. 2008, 130, 1138-1139.
    • (2008) J. Am. Chem. Soc. , vol.130 , pp. 1138-1139
    • Zhu, M.1    Lanni, E.2    Garg, N.3    Bier, M.E.4    Jin, R.5
  • 35
    • 58449084180 scopus 로고    scopus 로고
    • One-pot synthesis of atomically monodisperse thiol-functionalized au25 nanoclusters
    • Wu, Z.; Suhan, J.; Jin, R. One-Pot Synthesis of Atomically Monodisperse, Thiol-Functionalized Au25 Nanoclusters. J. Mater. Chem. 2009, 19, 622-626.
    • (2009) J. Mater. Chem. , vol.19 , pp. 622-626
    • Wu, Z.1    Suhan, J.2    Jin, R.3
  • 36
    • 42949162912 scopus 로고    scopus 로고
    • Correlating the crystal structure of a thiol-protected au25 cluster and optical properties
    • Zhu, M.; Aikens, C. M.; Hollander, F. J.; Schatz, G. C.; Jin, R. Correlating the Crystal Structure of A Thiol-Protected Au25 Cluster and Optical Properties. J. Am. Chem. Soc. 2008, 130, 5883-5885.
    • (2008) J. Am. Chem. Soc. , vol.130 , pp. 5883-5885
    • Zhu, M.1    Aikens, C.M.2    Hollander, F.J.3    Schatz, G.C.4    Jin, R.5
  • 37
    • 53149083360 scopus 로고    scopus 로고
    • Conversion of anionic [au25(sch2ch2ph)18]-cluster to charge neutral cluster via air oxidation
    • Zhu, M.; Eckenhoff, W. T.; Pintauer, T.; Jin, R. Conversion of Anionic [Au25(SCH2CH2Ph)18]-Cluster to Charge Neutral Cluster via Air Oxidation. J. Phys. Chem. C 2008, 112, 14221-14224.
    • (2008) J. Phys. Chem.C , vol.112 , pp. 14221-14224
    • Zhu, M.1    Eckenhoff, W.T.2    Pintauer, T.3    Jin, R.4
  • 38
    • 67650564479 scopus 로고    scopus 로고
    • Thiolate-capped au20 clusters with a large energy gap of 2.1 ev
    • Zhu, M.; Qian, H.; Jin, R. Thiolate-Capped Au20 Clusters with a Large Energy Gap of 2.1 eV. J. Am. Chem. Soc. 2009, 131, 7220-7221.
    • (2009) J. Am. Chem. Soc. , vol.131 , pp. 7220-7221
    • Zhu, M.1    Qian, H.2    Jin, R.3
  • 39
    • 71949121666 scopus 로고    scopus 로고
    • Controlling nanoparticles with atomic precision: The case of au144(sch2ch2ph)60
    • Qian, H.; Jin, R. Controlling Nanoparticles with Atomic Precision: The Case of Au144(SCH2CH2Ph)60. Nano Lett. 2009, 9, 4083-4087.
    • (2009) Nano Lett. , Issue.9 , pp. 4083-4087
    • Qian, H.1    Jin, R.2
  • 40
    • 73249114014 scopus 로고    scopus 로고
    • Size-focusing synthesis,optical and electrochemical properties of monodisperse au38(sc2h4ph)24 nanoclusters
    • Qian, H.; Zhu, Y.; Jin, R. Size-Focusing Synthesis, Optical and Electrochemical Properties of Monodisperse Au38(SC2H4Ph)24 Nanoclusters. ACS Nano 2009, 3, 3795-3803.
    • (2009) ACS Nano , vol.3 , pp. 3795-3803
    • Qian, H.1    Zhu, Y.2    Jin, R.3
  • 41
    • 37549016040 scopus 로고    scopus 로고
    • Electrospray ionization mass spectrometry of uniform and mixed monolayer nanoparticles: Au25[s(ch2)2ph]18 and au25[s(ch2)2ph]18-x-(sr) x
    • Tracy, J. B.; Crowe,M. C.; Parker, J. F.; Hampe,O.; Fields-Zinna, C. A.; Dass, A.; Murray, R. W. Electrospray Ionization Mass Spectrometry of Uniform and Mixed Monolayer Nanoparticles: Au25[S(CH2)2Ph]18 and Au25[S(CH2)2Ph]18-x-(SR) x. J. Am. Chem. Soc. 2007, 129, 16209-16215.
    • (2007) J. Am. Chem. Soc. , Issue.129 , pp. 16209-16215
    • Tracy, J.B.1    Crowem., C.2    Parker, J.F.3    Hampe, O.4    Fields-Zinna, C.A.5    Dass, A.6    Murray, R.W.7


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.