Gas solubility, diffusivity, permeability, and selectivity in mixed matrix membranes based on PIM-1 and fumed silica

Industrial and Engineering Chemistry Research

Volumn 52, Issue 31, 2013, Pages 10506-10520

  De Angelis, Maria Grazia ^a   Gaddoni, Riccardo ^a   Sarti, Giulio C ^a  

^a UNIVERSITY OF BOLOGNA   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

FRACTIONAL FREE VOLUME; FREE VOLUME EFFECTS; IDEAL SELECTIVITIES; INTRINSIC MICROPOROSITY; MIXED MATRIX MEMBRANES; SILICA NANOPARTICLES; SOLUBILITY ISOTHERM; VAN DER WAALS VOLUME;

CARBON DIOXIDE; DIFFUSION; FREE VOLUME; METHANE; NANOPARTICLES; POLYMER MATRIX COMPOSITES; SILICA; SOLUBILITY; TRANSPORT PROPERTIES; VAN DER WAALS FORCES;

GAS PERMEABLE MEMBRANES;

EID: 84881470336     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie303571h     Document Type: Article

References (43)

1. Budd, P. M.; Ghanem, B. S.; Makhseed, S.; McKeown, N. B.; Msayib, K. J.; Tattershall, C. E. Polymers of intrinsic microporosity (PIMs): robust, solution-processable, organic nanoporous materials Chem. Commun. 2004, 230
2. Budd, P. M.; McKeown, N. B.; Bader, S. G.; Msayib, K. J.; Fritsch, D.; Starannikova, L.; Belov, N.; Sanfirova, O.; Yampolskii, Y.; Shantarovich, V. Gas permeation parameters and other physicochemical properties of a polymer of intrinsic microporosity: Polybenzodioxane PIM-1 J. Membr. Sci. 2008, 325, 851
3. Budd, P.; McKeown, N. Highly permeable polymers for gas separation membranes Polymer Chemistry 2010, 1, 63
4. Budd, P. M.; McKeown, N. B.; Fritsch, D. Free volume and intrinsic microporosity in polymers J. Mater. Chem. 2005, 15, 1977
5. Harms, S.; Rätzke, K.; Faupel, F.; Chaukura, N.; Budd, P. M.; Egger, W.; Ravelli, L. Aging and free volume in a polymer of intrinsic microporosity (PIM-1) J. Adhes. 2012, 88, 608
6. Robeson, L. M. The upper bound revisited J. Membr. Sci. 2008, 320, 390
7. Khan, M. M.; Filiz, V.; Bengtson, G.; Shishatskiy, S.; Rahman, M. M.; Abetz, V. Functionalized carbon nanotubes mixed matrix membranes of polymers of intrinsic microporosity for gas separation Nanoscale Res. Lett. 2012, 7, 504
8. Liu, C.; Kulprathipanja, S.; Wilson, S. T. High Flux Mixed Matrix Membranes for Separations. US patent 20070209505.
9. Bushell, A. F.; Attfield, M. P.; Mason, C. R.; Budd, P. M.; Yampolskii, Y.; Starannikova, L.; Rebrov, A.; Bazzarelli, F.; Bernardo, P.; Jansen, J. C.; Lanc, M.; Friess, K.; Shantarovich, V.; Gustov, V.; Isaeva, V. Gas permeation parameters of mixed matrix membranes based on the polymer of intrinsic microporosity PIM-1 and the zeolitic imidazolate framework ZIF-8 J. Membr. Sci. 2013, 427, 48
10. Ahn, J.; Chung, W.-J.; Pinnau, I.; Song, J.; Du, N.; Robertson, G. P.; Guiver, M. D. Gas transport behavior of mixed-matrix membranes composed of silica nanoparticles in a polymer of intrinsic microporosity (PIM-1) J. Membr. Sci. 2010, 346, 280
11. De Angelis, M. G.; Sarti, G. C. Gas sorption and permeation in mixed matrix membranes based on glassy polymers and silica nanoparticles Curr. Opin. Chem. Eng. 2012, 1, 148
12. De Angelis, M. G.; Sarti, G. C. Solubility and Diffusivity of Gases in Mixed Matrix Membranes Containing Hydrophobic Fumed Silica: Correlations and Predictions Based on the NELF Model Ind. Eng. Chem. Res. 2008, 47, 5214
13. Ferrari, M. C.; Galizia, M.; De Angelis, M. G.; Sarti, G. C. Gas and Vapor Transport in Mixed Matrix Membranes Based on Amorphous Teflon AF1600 and AF2400 and Fumed Silica Ind. Eng. Chem. Res. 2010, 49, 11920
14. Ferrari, M. C.; Galizia, M.; De Angelis, M. G.; Sarti, G. C. Vapor Sorption And Diffusion In Mixed Matrices Based On Teflon AF 2400" in Membrane Gas Separation; Wiley-VCH: Weinheim, Germany, 2010, 125-142.
15. Merkel, T. C.; He, Z.; Pinnau, I.; Freeman, B. D.; Meakin, P.; Hill, A. J. Sorption and transport in poly (2,2-bis(trifluoromethyl)-4,5-difluoro-1,3- dioxole-co-tetrafluoroethylene) containing nanoscale fumed silica Macromolecules 2003, 36, 8406
16. Merkel, T. C.; Freeman, B. D.; Spontak, R. J.; He, Z.; Pinnau, I.; Meakin, P.; Hill, A. J. Ultrapermeable, reverse-selective nanocomposite membranes Science 2002, 296, 519
17. Merkel, T. C.; Freeman, B. D.; Spontak, R. J.; He, Z.; Pinnau, I.; Meakin, P.; Hill, A. J. Sorption, transport, and structural evidence for enhanced free volume in poly(4-methyl-2-pentyne)/fumed silica nanocomposite membranes Chem. Mater. 2003, 15, 109
18. Merkel, T. C.; He, Z.; Pinnau, I.; Freeman, B. D.; Meakin, P.; Hill, A. J. Effect of nanoparticles on gas sorption and transport in poly(1- trimethylsilyl-1-propyne) Macromolecules 2003, 36, 6844
19. Kelman, S. D.; Raharjo, R. D.; Bielawski, C. W.; Freeman, B. D. The influence of crosslinking and fumed silica nanoparticles on mixed gas transport properties of poly[1-(trimethylsilyl)-1-propyne] Polymer 2008, 49, 3029
20. Gomes, D.; Nunes, S. P.; Peinemann, K.-V. Membranes for gas separation based on poly(1-trimethylsilyl-1-propyne)-silica nanocomposites J. Membr. Sci. 2005, 246, 13
21. Pinnau, I.; He, Z. Filled superglassy membrane. US Patent 6,316,684 B1 (2001).
22. He, Z.; Pinnau, I.; Morisato, A. Nanostructured poly(4-methyl-2-pentyne)/ silica hybrid membranes for gas separation Desalination 2002, 146, 11
23. van Krevelen, W. Properties of Polymers; Elsevier: Amsterdam, The Netherlands, 1990.
24. Hölck, O.; Böhning, M.; Heuchel, M.; Siegert, M. R.; Hofmann, D. Gas sorption isotherms in swelling glassy polymers-detailed atomistic simulations J. Membr. Sci. 2013, 428, 523
25. Thomas, S.; Pinnau, I.; Du, N.; Guiver, M. D. Pure- and mixed-gas permeation properties of a microporous spirobisindane-based ladder polymer (PIM-1) J. Membr. Sci. 2009, 333, 125
26. Larsen, G. S.; Lin, P.; Siperstein, F. R.; Colina, C. M. Methane adsorption in PIM-1 Adsorption 2011, 17, 21
27. Doghieri, F.; Sarti, G. C. Non equilibrium lattice fluids-A predictive model for the solubility in glassy polymers Macromolecules 1996, 29, 7885
28. De Angelis, M. G.; Sarti, G. C. Solubility of gases and liquids in glassy polymers Annu. Rev. Chem. Biomol. Eng. 2011, 2, 97
29. Giacinti Baschetti, M.; De Angelis, M. G.; Doghieri, F.; Sarti, G. C. Solubility of Gases in Polymeric Membranes, in Chemical Engineering: Trends and Developments; Galan, M. A; d. Valle, E. M., Eds.; Wiley: Chichester (UK), 2005; pp 41-61.
30. Sanchez, I. C.; Lacombe, R. H. Statistical thermodynamics of polymer solutions Macromolecules 1978, 11, 1145
31. 2 mixtures at elevated pressures J. Polym. Sci., Part B: Polym. Phys. 1987, 25, 2497
32. Jordan, S.; Koros, W. J. Free volume distribution model of gas sorption and dilation in glassy polymers Macromolecules 1995, 28, 2228
33. Fleming, G. K.; Koros, W. J. Carbon dioxide conditioning effects on sorption and volume dilation behavior for bisphenol A-polycarbonate Macromolecules 1990, 23, 1353
34. Sarti, G. C.; De Angelis, M. G. Calculation of the solubility of liquid solutes in glassy polymers AIChE J. 2012, 58, 292
35. Maxwell, C. Treatise on Electricity and Magnetism; Oxford University Press: London, 1873.
36. Cohen, M. H.; Turnbull, D. J. Molecular transport in liquids and glasses J. Chem. Phys. 1959, 31, 1164
37. Thran, A.; Kroll, G.; Faupel, F. Correlation between fractional free volume and diffusivity of gas molecules in glassy polymers J. Polym. Sci., Part B: Polym. Phys. 1999, 37, 3344
38. Minelli, M.; Friess, K.; Vopička, O.; De Angelis, M. G. Modeling gas and vapor sorption in a polymer of intrinsic microporosity (PIM), Fluid Phase Equilib. 2013, 347, 35.
39. Galizia, M.; De Angelis, M. G.; Sarti, G. C. Sorption of hydrocarbons and alcohols in addition-type poly(trimethyl silyl norbornene) and other high free volume glassy polymers. II: NELF model predictions J. Membr. Sci. 2012, 405-406, 201
40. Budd, P. M.; Msayib, K. J.; Tattershall, C. E.; Ghanem, B. S.; Reynolds, K. J.; McKeown, N. B.; Fritsch, D. Gas separation membranes from polymers of intrinsic microporosity J. Membr. Sci. 2005, 251, 263
41. Minelli, M.; Campagnoli, S.; De Angelis, M. G.; Doghieri, F.; Sarti, G. C. Predictive model for the solubility of fluid mixtures in glassy polymers Macromolecules 2011, 44, 4852
42. De Angelis, M. G.; Sarti, G. C.; Doghieri, F. Correlations between penetrant properties and infinite dilution gas solubility in glassy polymers: NELF model derivation Ind. Eng. Chem. Res. 2007, 46, 7645
43. De Angelis, M. G.; Sarti, G. C.; Doghieri, F. NELF model prediction of the infinite dilution gas solubility in glassy polymers J. Membr. Sci. 2007, 289, 106