Correlations between penetrant properties and infinite dilution gas solubility in glassy polymers: NELF model derivation

Industrial and Engineering Chemistry Research

Volumn 46, Issue 23, 2007, Pages 7645-7656

  De Angelis, Maria Grazia ^a   Sarti, Giuio C ^a   Doghieri, Ferruccio ^a  

^a UNIVERSITY OF BOLOGNA   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

CORRELATION METHODS; POLYMETHYL METHACRYLATES; SOLUBILITY; SORPTION;

EQUILIBRIUM THERMODYNAMICS; NONEQUILIBRIUM LATTICE FLUID (NELF);

GASES;

CORRELATION METHODS; GASES; POLYMETHYL METHACRYLATES; SOLUBILITY; SORPTION;

EID: 36349008214     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie070304v     Document Type: Article

References (32)

1. van Amerongen, G. J. Influence of structure of elastomers on their permeability to gases. J. Polym. Sci. 1950, 5, 307-332.
2. van Krevelen, D. W. Properties of Polymers: Their Correlation with Chemical Structure; their Numerical Estimation and Prediction from Additive Group Contributions, 3rd ed.; Elsevier: Amsterdam, 1990.
3. Michaels, A. S.; Bixler, H. J. Solubility of gases in polyethylene. J. Polym. Sci. 1961, 50, 393-412.
4. Barrer, R. M.; Skirrow, G. Transport and equilibrium phenomena in gas-elastomer systems. II. Equilibrium phenomena. J Polym. Sci. 1948, 5, 564-575.
5. Korosy, F. Two Rules Concerning Solubility of Gases and Crude Data on Solubility of Krypton. Trans. Faraday Soc. 1937, 33, 416-425.
6. Kamiya, Y.; Naito, Y.; Terada, K.; Mizoguchi, K. Volumetric Properties and Interaction Parameters of Dissolved Gases in Poly(dimethylsiloxane) and Polyethylene. Macromolecules 2000, 33, 3111-3119.
7. Ghosal, K.; Chern, R. Y.; Freeman, B. D.; Savariar, R. The effect of aryl nitration on gas sorption and permeation in polysulfone. J. Polym. Sci., Part B: Polym. Phys. 1995, 33, 657-666.
8. Toi, K.; Morel, G.; Paul, D. R. Gas sorption and transport in poly-(phenylene oxide) and comparisons with other glassy polymers. J. Appl. Polym. Sci. 1982, 27, 2997-3005.
9. Serad, G. E.; Freeman, B. D.; Stewart, M. E.; Hill, A. J. Gas and vapor sorption and diffusion in poly(ethylene terephthalate). Polymer 2001, 42, 6929-6943.
10. De Angelis, M. G.; Sarti, G. C.; Doghieri, F. NELF model prediction of the infinite dilution gas solubility in glassy polymers. J. Membr. Sci. 2007, 289, 106-122.
11. Bondar, V. I.; Freeman, B. D.; Yampolskii, Yu. P. Sorption of Gases and Vapors in an Amorphous Glassy Perfluorodioxole Copolymer. Macromolecules 1999, 32, 6163-6171.
12. Stern, S. A.; Mullhaupt, J. T.; Gareis, P. J. The effect of pressure on the permeation of gases and vapors through polyethylene. Usefulness of the corresponding states principle. AIChE J. 1969, 15, 64-73.
13. Suwandi, M. S.; Stern, S. A. Transport of heavy organic vapors through silicone rubber. J. Polym. Sci., Polym. Phys. Ed. 1973, 1, 663-681.
14. Stull, D. R.; Westrum, E. F.; Sinke, G. C. The Chemical Thermodynamics of Organic Compounds; Wiley: New York, 1969
15. Y. Yampolskii, D. Wiley, C. Maher, Novel correlation for solubility of gases in polymers: effect of molecular surface area of gases. J. Appl. Polym. Sci. 2000, 76, 552-560.
16. Gee, G. Some thermodynamic properties of high polymers and their molceular interpretation. Q. Rev. (London) 1947, 1, 265-298.
17. Sanchez, I. C.; Lacombe, R. H. An elementary molecular theory of classical fluids. Pure fluids. J. Phys. Chem. 1976, 80, 2352-2362.
18. Lacombe, R. H.; Sanchez, I. C. Statistical thermodynamics of fluid mixtures. J. Phys. Chem. 1976, 80, 2568-2580.
19. Sanchez, I. C.; Lacombe, R. H. Statistical Thermodynamics of Polymer Solutions. Macromolecules 1978, 11, 1145-1156.
20. Doghieri, F.; Sarti, G. C. Nonequilibrium Lattice Fluids: A Predictive Model for the Solubility in Glassy Polymers. Macromolecules 1996, 29, 7885-7896.
21. Doghieri, F.; Sarti, G. C. Predicting the low pressure solubility of gases and vapors in glassy polymers by the NELF model. J. Membr. Sci. 1998, 147, 73-86.
22. Sarti, G. C.; Doghieri, F. Predictions of the solubility of gases in glassy polymers based on the NELF model. Chem. Eng. Sci. 1998, 53, 3435-3447.
23. Doghieri, F.; Canova, M.; Sarti, G. C. ACS Symp. Ser. 1999, 733, 179-193.
24. Giacinti Baschetti, M.; Doghieri, F.; Sarti, G. C. Solubility in Glassy Polymers: Correlations through the Nonequilibrium Lattice Fluid Model. Ind. Eng. Chem. Res. 2001, 40, 3027-3037.
25. Doghieri, F.; Quinzi, M.; Rethwisch, D. G.; Sarti, G. C. ACS Symp. Ser. 2004, 876, 74-90.
26. Giacinti Baschetti, M.; De Angelis, M. G.; Doghieri, F.; Sarti, G. C. In Chemical Engineering: Trends and Developments; Galan, M. A., Martín del Valle, E., Eds.; Wiley: Chichester, U.K., 2005; pp 41-61.
27. Prausnitz, J. M. Regular solution theory for gas-liquid solutions. AIChE J. 1958, 4, 269-272.
28. Prausnitz, J. M.; Shair, F. H. A thermodynamic correlation of gas solubilities. AIChE J. 1961, 7, 682-687.
29. Astarita, G. Thermodynamics; Plenum Press: New York, 1989.
30. Bondi, A. Physical properties of molecular crystals, liquids and gases; John Wiley & Sons, Inc.: New York, 1968.
31. Rodgers, P. A. Pressure-volume-temperature relationships for polymeric liquids: a review of equations of state and their characteristic parameters for 56 polymers. J. Appl. Polym. Sci. 1993, 48, 1061-1080.
32. Sanchez, I. C.; Panayiotou, C. In Models for Thermodynamic and Phase Equilibria Calculations; Sandler, S. I., Ed.; Marcel Dekker: New York, 1994.