Graphene as a new sorbent in analytical chemistry

TrAC - Trends in Analytical Chemistry

Volumn 51, Issue , 2013, Pages 33-43

  Sitko, Rafal ^a   Zawisza, Beata ^a   Malicka, Ewa ^a  

^a UNIVERSITY OF SILESIA   (Poland)

Author keywords

Chemical functionalization; Graphene; Graphene oxide; Magnetic solid phase extraction; Preconcentration; Separation; Solid sorbent; Solid phase extraction; Solid phase microextraction; Trace analysis

Indexed keywords

CHEMICAL MODIFICATION; CHROMATOGRAPHY; EXTRACTION; GRAPHENE; GRAPHENE OXIDE; METAL IONS; METALS; PHASE SEPARATION; SEPARATION; SORBENTS; TRACE ELEMENTS;

CHEMICAL FUNCTIONALIZATION; MAGNETIC SOLID-PHASE EXTRACTIONS; PRE-CONCENTRATION; SOLID SORBENTS; SOLID-PHASE EXTRACTION; SOLID-PHASE MICROEXTRACTION;

TRACE ANALYSIS;

1,2,4 TRICHLOROBENZENE; 2 NAPHTHOL; 2,4,6 TRICHLOROPHENOL; CADMIUM; CARBON NANOTUBE; CHROMIUM; COBALT; COPPER ION; EUROPIUM; GOLD; GRAPHENE; GRAPHENE OXIDE; LEAD; NANOMATERIAL; NANOPARTICLE; NANOSHEET; NAPHTHALENE; PALLADIUM; SORBENT; UNCLASSIFIED DRUG; URANIUM; ZINC ION; ZINC OXIDE;

ADSORPTION; ARTICLE; BINDING AFFINITY; CHEMICAL ANALYSIS; CHROMATOGRAPHY; COMPLEX FORMATION; COVALENT BOND; FOOD ANALYSIS; GAS CHROMATOGRAPHY; HYDROGEN BOND; MAGNETIC SOLID PHASE EXTRACTION; MATERIAL COATING; MOLECULAR INTERACTION; MOLECULAR STABILITY; PRIORITY JOURNAL; REVERSED PHASE HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; SOLID PHASE EXTRACTION; SOLID PHASE MICROEXTRACTION; SPECTROSCOPY; STRUCTURE ACTIVITY RELATION; SURFACE PROPERTY; WATER ANALYSIS;

EID: 84881151034     PISSN: 01659936     EISSN: 18793142     Source Type: Journal    
DOI: 10.1016/j.trac.2013.05.011     Document Type: Review

References (80)

1. Picó Y., Fernández M., Ruiz M.J., Font G. Current trends in solid-phase-based extraction techniques for the determination of pesticides in food and environment. J. Biochem. Biophys. Meth. 2007, 70:117-131.
2. Jiang X., Huang K., Deng D., Xia H., Hou X., Zheng C. Nanomaterials in analytical atomic spectrometry. Trends Anal. Chem. 2012, 39:38-59.
3. Lemos V.A., Teixeira L.S.G., de A.Bezerra M., Spinola Costa A.C., Castro J.T., Cardoso L.A.M., de Jesus D.S., Santos E.S., Baliza P.X., Santos L.N. New materials for solid-phase extraction of trace elements. Appl. Spectrosc. Rev. 2008, 43:303-334.
4. Lucena R., Simonet B.M., Cárdenas S., Valcárcel M. Potential of nanoparticles in sample preparation. J. Chromatogr. A 2011, 1218:620-637.
5. Pyrzynska K. Carbon nanostructures for separation, preconcentration and speciation of metal ions. Trends Anal. Chem. 2010, 29:718-727.
6. Valcarcel M., Cardenas S., Simonet B.M., Moliner-Martinez Y., Lucena R. Carbon nanostructures as sorbent materials in analytical processes. Trends Anal. Chem. 2008, 27:34-43.
7. Novoselov K.S., Geim A.K., Morozov S.V., Jiang D., Zhang Y., Dubonos S.V., Grigorieva I.V., Firsov A.A. Electric field in atomically thin carbon films. Science 2004, 306:666-669.
8. Zhu Y., Murali S., Cai W., Li X., Suk J.W., Potts J.R., Ruoff R.S. Graphene and graphene oxide: synthesis, properties, and applications. Adv. Mater. 2010, 22:3906-3924.
9. Hummers W.S., Offeman R.E. Preparation of graphitic oxide. J. Am. Chem. Soc. 1958, 80:1339.
10. Marcano D.C., Kosynkin D.V., Berlin J.M., Sinitskii A., Sun Z., Slesarev A., Alemany L.B., Lu W., Tour J.M. Improved synthesis of graphene oxide. ACS Nano 2010, 4:4806-4814.
11. Stoller M.D., Park S.J., Zhu Y.W., An J.H., Ruoff R.S. Graphene-based ultracapacitors. Nano Lett. 2008, 8:3498-3502.
12. He H., Klinowski J., Forster M. A new structural model for graphite oxide. Chem. Phys. Lett. 1998, 287:53-56.
13. Liu Q., Shi J., Jiang G. Application of graphene in analytical sample preparation. Trends Anal. Chem. 2012, 37:1-11.
14. Pérez-López B., Merkoçi A. Carbon nanotubes and graphene in analytical sciences. Microchim. Acta 2012, 179:1-16.
15. Kuila T., Bose S., Mishra A.K., Khanra P., Kim N.H., Lee J.H. Chemical functionalization of graphene and its applications. Prog. Mater. Sci. 2012, 57:1061-1105.
16. Georgakilas V., Otyepka M., Bourlinos A.B., Chandra V., Kim N., Kemp K.C., Hobza P., Zboril R., Kim K.S. Functionalization of graphene: covalent and non-covalent approaches, derivatives and applications. Chem. Rev. 2012, 112:6156-6214.
17. Gao Y., Li Y., Zhang L., Huang H., Hu J., Shah S.M., Su X. Adsorption and removal of tetracycline antibiotics from aqueous solution by graphene oxide. J. Colloid Interf. Sci. 2012, 368:540-546.
18. Ma J.C., Dougherty D.A. The cation- interaction. Chem. Rev. 1997, 97:1303-1324.
19. Pei Z., Li L., Sun L., Zhang S., Shan X.-Q., Yang S., Wen B. Adsorption characteristics of 1,2,4-trichlorobenzene, 2,4,6-trichlorophenol, 2-naphthol and naphthalene on graphene and graphene oxide. Carbon 2013, 51:156-163.
20. Yang X., Li J., Wen T., Ren X., Huang Y., Wang X. Adsorption of naphthalene and its derivatives on magnetic graphene composites and the mechanism investigation. Colloid. Surface. A 2013, 422:118-125.
21. Yang S.-T., Chen S., Chang Y., Cao A., Liu Y., Wang H. Removal of methylene blue from aqueous solution by graphene oxide. J. Colloid Interf. Sci. 2011, 359:24-29.
22. Li Y., Du Q., Liu T., Peng X., Wang J., Sun J., Wang Y., Wu S., Wang Z., Xia Y., Xia L. Comparative study of methylene blue dye adsorption onto activated carbon, graphene oxide, and carbon nanotubes. Chem. Eng. Res. Des. 2013, 91:361-368.
23. Wang C., Feng C., Gao Y., Ma X., Wu Q., Wang Z. Preparation of a graphene-based magnetic nanocomposite for the removal of an organic dye from aqueous solution. Chem. Eng. J. 2011, 173:92-97.
24. Li N., Zheng M., Chang X., Ji G., Lu H., Xue L., Pan L., Cao J. Preparation of magnetic CoFe2O4-functionalized graphene sheets via a facile hydrothermal method and their adsorption properties. J. Solid State Chem. 2011, 184:953-958.
25. Fan L., Luo C., Sun M., Li X., Lu F., Qiu H. Preparation of novel magnetic chitosan/graphene oxide composite as effective adsorbents toward methylene blue. 2012, 114:703-706.
26. Zhao G., Li J., Ren X., Chen C., Wang X. Few-layered graphene oxide nanosheets as superior sorbents for heavy metal ion pollution management. Environ. Sci. Technol. 2011, 45:10454-10462.
27. 2+ removal. J. Colloid Interf. Sci. 2010, 351:122-127.
28. Wu W., Yang Y., Zhou H., Ye T., Huang Z., Liu R., Kuang Y. Highly Efficient removal of Cu(II) from aqueous solution by using graphene oxide. Water Air Soil Poll. 2013, 224:1372-1379.
29. 4 nanoparticles. ACS Appl. Mater. Inter. 2012, 4:4991-5000.
30. Fan L., Luo C., Sun M., Qiu H. Synthesis of graphene oxide decorated with magnetic cyclodextrin for fast chromium removal. J. Mater. Chem. 2012, 22:24577-24583.
31. Liu L., Li C., Bao C., Jia Q., Xiao P., Liu X., Zhang Q. Preparation and characterization of chitosan/graphene oxide composites for the adsorption of Au(III) and Pd(II). Talanta 2012, 93:350-357.
32. Zhao G., Ren X., Gao X., Tan X., Li J., Chen C., Huang Y., Wang X. Removal of Pb(ii) ions from aqueous solutions on few-layered graphene oxide nanosheets. Dalton Trans. 2011, 40:10945-10952.
33. Zhao G., Wen T., Yang X., Yang S., Liao J., Hu J., Shao D., Wang X. Preconcentration of U(vi) ions on few-layered graphene oxide nanosheets from aqueous solutions. Dalton Trans. 2012, 41:6182-6188.
34. Li Z., Chen F., Yuan L., Liu Y., Zhao Y., Chai Z., Shi W. Uranium(VI) adsorption on graphene oxide nanosheets from aqueous solutions. Chem. Eng. J. 2012, 210:539-546.
35. Sun Y., Wang Q., Chen C., Tan X., Wang X. Interaction between Eu(III) and graphene oxide nanosheets investigated by batch and extended X-ray absorption fine structure spectroscopy and by modeling techniques. Environ. Sci. Technol. 2012, 46:6020-6027.
36. Sitko R., Turek E., Zawisza B., Malicka E., Talik E., Heimann J., Gagor A., Feist B., Wrzalik R. Adsorption of divalent metal ions from aqueous solutions using graphene oxide. Dalton Trans. 2013, 42:5682-5689.
37. Sitko R., Zawisza B., Malicka E. Modification of carbon nanotubes for preconcentration, separation and determination of trace-metal ions. Trends Anal. Chem. 2012, 37:22-31.
38. Madadrang C.J., Kim H.Y., Gao G., Wang N., Zhu J., Feng H., Gorring M., Kasner M.L., Hou S. Adsorption behavior of EDTA-graphene oxide for Pb(II) removal. ACS Appl. Mater. Inter. 2012, 4:1186-1193.
39. 2. Mater. Chem. Phys. 2012, 136:538-544.
40. Ren Y., Yan N., Wen Q., Fan Z., Wei T., Zhang M., Ma J. Graphene/δ-MnO2 composite as adsorbent for the removal of nickel ions from wastewater. Chem. Eng. J. 2011, 175:1-7.
41. Liu M., Chen C., Hu J., Wu X., Wang X. Synthesis of magnetite/graphene oxide composite and application for cobalt(II) removal. J. Phys. Chem. C 2011, 115:25234-25240.
42. Chandra V., Park J., Chun Y., Lee J.W., Hwang I.-C., Kim K.S. Water-dispersible magnetite-reduced graphene oxide composites for arsenic removal. ACS Nano 2010, 4:3979-3986.
43. 2 nanocomposites. Chem. Eng. J. 2012, 187:45-52.
44. Fan L., Luo C., Sun M., Li X., Qiu H. Highly selective adsorption of lead ions by water-dispersible magnetic chitosan/graphene oxide composites. Colloid. Surface. B 2013, 103:523-529.
45. Huang K.-J., Jing Q.-S., Wei C.-Y., Wu Y.-Y. Spectrofluorimetric determination of glutathione in human plasma by solid-phase extraction using graphene as adsorbent. Spectrochim. Acta Part A 2011, 79:1860-1865.
46. Huang K.-J., Yu S., Li J., Wu Z.-W., Wei C.-Y. Extraction of neurotransmitters from rat brain using graphene as a solid-phase sorbent, and their fluorescent detection by HPLC. Microchim. Acta 2012, 176:327-335.
47. Wu J., Chen L., Mao P., Lu Y., Wang H. Determination of chloramphenicol in aquatic products by graphene-based SPE coupled with HPLC-MS/MS. J. Sep. Sci. 2012, 35:3586-3592.
48. Liu Q., Shi J., Zeng L., Wang T., Cai Y., Jiang G. Evaluation of graphene as an advantageous adsorbent for solid-phase extraction with chlorophenols as model analytes. J. Chromatogr. A 2011, 1218:197-204.
49. Liu Q., Shi J., Sun J., Wang T., Zeng L., Jiang G. Graphene and graphene oxide sheets supported on silica as versatile and high-performance adsorbents for solid-phase extraction. Angew. Chem. Int. Ed. 2011, 50:5913-5917.
50. Zhang H., Low W.P., Lee H.K. Evaluation of sulfonated graphene sheets as sorbent for micro-solid-phase extraction combined with gas chromatography-mass spectrometry. J. Chromatogr. A 2012, 1233:16-21.
51. Wu X., Hong H., Liu X., Guan W., Meng L., Ye Y., Ma Y. Graphene-dispersive solid-phase extraction of phthalate acid esters from environmental water. Sci. Total Environ. 2013, 444:224-230.
52. Wang Y., Gao S., Zang X., Li J., Ma J. Graphene-based solid-phase extraction combined with flame atomic absorption spectrometry for a sensitive determination of trace amounts of lead in environmental water and vegetable samples. Anal. Chim. Acta 2012, 716:112-118.
53. Chang Q., Song S., Wang Y., Li J., Ma J. Application of graphene as a sorbent for preconcentration and determination of trace amounts of chromium(III) in water samples by flame atomic absorption spectrometry. Anal. Methods 2012, 4:1110-1116.
54. Wang Y.-K., Gao S.-T., Ma J.-J., Li J.-C. Application of graphene as a sorbent for simultaneous preconcentration and determination of trace amounts of cobalt and nickel in environmental water and vegetable samples. J. Chin. Chem. Soc. 2012, 59:1468-1477.
55. 2-graphene composite. Talanta 2011, 86:114-120.
56. Souza Silva E.A., Risticevic S., Pawliszyn J. Recent trends in SPME concerning sorbent materials, configurations and in vivo applications. Trends Anal. Chem. 2013, 43:24-36.
57. Mehdinia A., Aziz-Zanjani M.O. Recent advances in nanomaterials utilized in fiber coatings for solid-phase microextraction. Trends Anal. Chem. 2013, 42:205-215.
58. Chen J., Zou J., Zeng J., Song X., Ji J., Wang Y., Ha J., Chena X. Preparation and evaluation of graphene-coated solid-phase microextraction fiber. Anal. Chim. Acta 2010, 678:44-49.
59. Zhao G., Song S., Wang C., Wu Q., Wang Z. Solid-phase microextraction with a novel graphene-coated fiber coupled with high-performance liquid chromatography for the determination of some carbamates in water samples. Anal. Methods 2011, 3:2929-2935.
60. Wu Q., Feng C., Zhao G., Wang C., Wang Z. Graphene-coated fiber for solid-phase microextraction of triazine herbicides in water samples. J. Sep. Sci. 2012, 35:193-199.
61. Zhang H., Lee H.K. Plunger-in-needle solid-phase microextraction with graphene-based sol.gel coating as sorbent for determination of polybrominated diphenyl ethers. J. Chromatogr. A 2011, 1218:4509-4516.
62. Zhang S., Du Z., Li G. Graphene-supported zinc oxide solid-phase microextraction coating with enhanced selectivity and sensitivity for the determination of sulfur volatiles in Allium species. J. Chromatogr. A 2012, 1260:1-8.
63. Zou J., Song X., Ji J., Xu W., Chen J., Jiang Y., Wang Y., Chen X. Polypyrrole/graphene composite-coated fiber for the solid-phase microextraction of phenols. J. Sep. Sci. 2011, 34:2765-2772.
64. Ponnusamy V.K., Jen J.-F. A novel graphene nanosheets coated stainless steel fiber for microwave assisted headspace solid phase microextraction of organochlorine pesticides in aqueous samples followed by gas chromatography with electron capture detection. J. Chromatogr. A 2011, 1218:6861-6868.
65. Zhang H., Lee H.K. Simultaneous determination of ultraviolet filters in aqueous samples by plunger-in-needle solid-phase microextraction with graphene-based sol-gel coating as sorbent coupled with gas chromatography-mass spectrometry. Anal. Chim. Acta 2012, 742:67-73.
66. Xu L., Feng J., Li J., Liu X., Jiang Shengxiang Graphene oxide bonded fused-silica fiber for solid-phase microextraction-gas chromatography of polycyclic aromatic hydrocarbons in water. J. Sep. Sci. 2012, 35:93-100.
67. Xu L., Feng J., Liang X., Li J., Jiang S. C18 functionalized graphene oxide as a novel coating for solid-phase microextraction. J. Sep. Sci. 2012, 35:1531-1537.
68. Qu Q., Shen Y., Gu C., Gu Z., Gu Q., Wang C., Hu X. Capillary column coated with graphene oxide as stationary phase for gas chromatography. Anal. Chim. Acta 2012, 757:83-87.
69. Luo Y.-B., Yuan B.-F., Yu Q.-W., Feng Y.-Q. Substrateless graphene fiber: a sorbent for solid-phase microextraction. J. Chromatogr. A 2012, 1268:9-15.
70. Aguilar-Arteaga K., Rodriguez J.A., Barrado E. Magnetic solids in analytical chemistry: a review. Anal. Chim. Acta 2010, 674:157-165.
71. Chen L., Wang T., Tong J. Application of derivatized magnetic materials to the separation and the preconcentration of pollutants in water samples. Trends Anal. Chem. 2011, 30:1095-1108.
72. Li S., Niu Z., Zhong X., Yang H., Lei Y., Zhang F., Hu W., Dong Z., Jin J., Ma J. Fabrication of magnetic Ni nanoparticles functionalized water-soluble graphene sheets nanocomposites as sorbent for aromatic compounds removal. J. Hazard. Mater. 2012, 229-230:42-47.
73. Wu Q., Zhao G., Feng C., Wang C., Wang Z. Preparation of a graphene-based magnetic nanocomposite for the extraction of carbamate pesticides from environmental water samples. J. Chromatogr. A 2011, 1218:7936-7942.
74. Zhao G., Song S., Wang C., Wu Q., Wang Z. Determination of triazine herbicides in environmental water samples by high-performance liquid chromatography using graphene-coated magnetic nanoparticles as adsorbent. Anal. Chim. Acta 2011, 708:155-159.
75. Wang W., Li Y., Wu Q., Wang C., Zang X., Wang Z. Extraction of neonicotinoid insecticides from environmental water samples with magnetic graphene nanoparticles as adsorbent followed by determination with HPLC. Anal. Methods 2012, 4:766-772.
76. Wu Q., Liu M., Ma X., Wang W., Wang C., Zang X., Wang Z. Extraction of phthalate esters from water and beverages using a graphene-based magnetic nanocomposite prior to their determination by HPLC. Microchim. Acta 2012, 177:23-30.
77. Karamani A.A., Douvalis A.P., Stalikas C.D. Zero-valent iron/iron oxide oxyhydroxide/graphene as a magnetic sorbent for the enrichment of polychlorinated biphenyls, polyaromatic hydrocarbons and phthalates prior to gas chromatography-mass spectrometry. J. Chromatogr. A 2013, 1271:1-9.
78. Xue Y.H., Chen H., Yu D.S., Wang S.Y., Yardeni M., Dai Q.B., Guo M.M., Liu Y., Lu F., Qu J., Dai L.M. Oxidizing metal ions with graphene oxide: the in situ formation of magnetic nanoparticles on self-reduced graphene sheets for multifunctional applications. Chem. Commun. 2011, 47:11689-11691.
79. Liu Q., Shi J., Wang T., Guo F., Liu L., Jiang G. Hemimicelles/admicelles supported on magnetic graphene sheets for enhanced magnetic solid-phase extraction. J. Chromatogr. A 2012, 1257:1-8.
80. Luo Y.-B., Shi Z.-G., Gao Q., Feng Y.-Q. Magnetic retrieval of graphene: extraction of sulfonamide antibiotics from environmental water samples. J. Chromatogr. A 2011, 1218:1353-1358.