Oxidation of chlorophene by ozonation: Kinetics, identification of by-products and reaction pathways

Chemical Engineering Journal

Volumn 230, Issue , 2013, Pages 447-455

  Benitez, F J ^a   Acero, J L ^a   Garcia Reyes, J F ^b   Real, F J ^a   Roldan, G ^a   Rodriguez, E ^a   Molina Diaz A ^b  

^a UNIVERSITY OF EXTREMADURA   (Spain)

^b UNIVERSITY OF JAÉN   (Spain)

Author keywords

Apparent rate constants; Chlorophene; Emerging contaminant; Identification of by products; Ozone; Reaction pathways

Indexed keywords

APPARENT RATE CONSTANT; CHLOROPHENE; DEGRADATION PATHWAYS; DEGREE OF DISSOCIATION; EMERGING CONTAMINANT; KINETIC EXPERIMENT; LIQUID CHROMATOGRAPHY/MASS SPECTROMETRY; REACTION PATHWAYS;

OZONIZATION; RATE CONSTANTS;

OZONE;

EID: 84880844640     PISSN: 13858947     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cej.2013.06.120     Document Type: Article

References (23)

1. Boehmer W., Ruedel H., Wenzel A., Schröeter-Kermani C. Retrospective monitoring of triclosan and methyl-triclosan in fish: results from the German Environmental Specimen Bank. Organohalogen. Comp. 2004, 66:1489-1494.
2. Zhang H., Huang C.H. Oxidative transformation of triclosan and chlorophene by manganese oxides. Environ. Sci. Technol. 2003, 37:2421-2430.
3. W.A. Arnold, K. McNeil, J.L. Packer, D.E. Latch, A.L. Boreen, Report of the USGS-WRRI 104G, National Grants Competition, 2003, 18.
4. He Z., Zhang A., Li Y., Song S., Liu Z., Chen J., Xu X. Chlorophene degradation by combined ultraviolet irradiation and ozonation. J. Environ. Sci. Health A: Tox. Hazard. Subst. Environ. Eng. 2011, 46:1-8.
5. 2+ system in the electro-Fenton degradation of the antimicrobial chlorophene. Appl. Catal. B: Environ. 2007, 72:382-394.
6. Benítez F.J., Acero J.L., Real F.J., Roldán G., Rodríguez E. Photolysis of model emerging contaminants in ultra-pure water: kinetics, by-products formation and degradation pathways. Water Res. 2013, 47:870-880.
7. Acero J.L., Benítez F.J., Real F.J., Roldán G., Rodríguez E. Chlorination and bromination kinetics of emerging contaminants in aqueous systems. Chem. Eng. J. 2013, 219:43-50.
8. Glaze W.H., Kang J.-W., Chapin D.H. Chemistry of water treatment processes involving ozone, hydrogen peroxide and ultraviolet radiation. Ozone: Sci. Eng. 1987, 9:335-352.
9. von Gunten U. Ozonation of drinking water. Part I. Oxidation kinetics and product formation. Water Res. 2003, 37:1443-1467.
10. Ikehata K., Nagashkar N.J., Gamal El-Din M. Degradation of aqueous pharmaceuticals by ozonation and advanced oxidation processes: a review. Ozone Sci. Eng. 2006, 28:353-414.
11. Esplugas S., Bila D.M., Krause L.G.T., Dezotti M. Ozonation and advanced oxidation technologies to remove endocrine disrupting chemicals (EDCs) and pharmaceuticals and personal care products (PPCPs) in water effluents. J. Hazard. Mater. 2007, 149:631-642.
12. Benítez F.J., Acero J.L., Real F.J., Roldán G. Ozonation of pharmaceutical compounds: rate constants and elimination in various water matrices. Chemosphere 2009, 77:53-59.
13. Staehelin J., Hoigne J. Decomposition of ozone in water in the presence of organic solutes acting as promoters and inhibitors of radical chain reactions. Environ. Sci. Technol. 1985, 19:1206-1213.
14. Gurol M., Nekouinaini S. Kinetic behavior of ozone in aqueous solutions of substituted phenols. Ind. Eng. Chem. Fund. 1984, 23:54-60.
15. De Laat J., Maouala-Makata P., Dore M. Rate constants for reactions of ozone and hydroxyl radicals with several phenyl-ureas and acetamides. Environ. Technol. 1996, 17:707-716.
16. Karpel Vel Leitner N., Roshani B. Kinetic of benzotriazole oxidation by ozone and hydroxyl radical. Water Res. 2010, 44:2058-2066.
17. Benitez F.J., Acero J.L., Real F.J., Garcia J. Kinetics of photodegradation and ozonation of pentachlorophenol. Chemosphere 2003, 51:651-662.
18. Hoigné J., Bader H. Rate constants of reactions of ozone with organic and inorganic compounds in water - II. Dissociating organic compounds. Water Res. 1983, 17:185-194.
19. Benner J., Salhi E., Ternes T., von Gunten U. Ozonation of reverse osmosis concentrate: kinetics and efficiency of beta blocker oxidation. Water Res. 2008, 42:3003-3012.
20. Abranko L., García-Reyes J.F., Molina-Díaz A. In-source fragmentation and accurate mass analysis of multiclass flavonoid conjugates by electrospray ionization time-of-flight mass spectrometry. J. Mass Spectrom. 2011, 46:478-488.
21. Zhang H., Huahuang C. Oxidative transformation of triclosan and chlorophene by manganese oxides. Environ. Sci. Technol. 2003, 37:2421-2430.
22. Satuf M.L., Brandi R.J., Cassano A.E., Alfano O.M. Photocatalytic degradation of 4-chlorophenol: a kinect study. Appl. Catal. B: Environ. 2008, 82:37-49.
23. Catrinescu C., Arsene D., Teodosiu C. Catalytic wet hydrogen peroxide oxidation of para-chlorophenol over Al/Fe pillared clays prepared from different host clays. Appl. Catal. B: Environ. 2011, 101:451-460.