Formation of trivalent zirconocene complexes from ansa-zirconocene-based olefin-polymerization precatalysts: An EPR- and NMR-spectroscopic study

Journal of the American Chemical Society

Volumn 135, Issue 29, 2013, Pages 10710-10719

  Lenton, Taylor N ^a   Bercaw, John E ^a   Panchenko, Valentina N ^b   Zakharov, Vladimir A ^b   Babushkin, Dmitrii E ^b   Soshnikov, Igor E ^b   Talsi, Evgenii P ^b   Brintzinger, Hans H ^c  

^a CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

^b BORESKOV INSTITUTE OF CATALYSIS   (Russian Federation)

^c UNIVERSITY OF KONSTANZ   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EPR SIGNALS; INTERCONVERSIONS; ISOBUTANES; METALLOCENE COMPLEXES; PRECATALYSTS; REACTION MECHANISM; TOLUENE SOLUTION; ZIRCONOCENE COMPLEXES;

CHLORINE COMPOUNDS; ORGANOMETALLICS; POSITIVE IONS; SPECTROSCOPIC ANALYSIS; ZIRCONIUM;

ZIRCONIUM COMPOUNDS;

ALKENE; AMALGAM; BUTANE; METAL COMPLEX; TOLUENE; ZIRCONOCENE;

ARTICLE; CATALYST; CHEMICAL STRUCTURE; COMPLEX FORMATION; CRYSTAL STRUCTURE; ELECTRON SPIN RESONANCE; POLYMERIZATION; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; REDUCTION;

EID: 84880842120     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja403170u     Document Type: Article

References (51)

1. Resconi, L.; Cavallo, L.; Fait, A.; Piemontesi, F. Chem. Rev. 2000, 100, 1253-1345
2. Resconi, L.; Chadwick, J. C.; Cavallo, L. In Comprehensive Organometallic Chemistry III; Crabtree, R. H.; Mingos, D. M. P., Eds.; Elsevier: Oxford, 2007; Vol. 4, Bochmann, M., Vol. Ed.; Chapter 4.09, pp 1005-1166.
3. Chen, E. Y. X.; Marks, T. J. Chem. Rev. 2000, 100, 1391-1434
4. Bochmann, M. J. Organomet. Chem. 2004, 689, 3982-3998
5. Bochmann, M. Organometallics 2010, 29, 4711-4740
6. Huang, Y. H.; Yu, Q.; Zhu, S.; Rempel, G. L.; Li, L. J. Polym. Sci., Part A: Polym. Chem. 1999, 37, 1465-1472
7. Bryliakov, K. P.; Babushkin, D. E.; Talsi, E. P.; Voskoboynikov, A. Z.; Gritzo, H.; Schröder, L.; Damrau, H.-R. H.; Wieser, U.; Schaper, F.; Brintzinger, H. H. Organometallics 2005, 24, 894-904
8. Grassi, A.; Saccheo, S.; Zambelli, A.; Laschi, F. Macromolecules 1998, 31, 5588-5591
9. Chien, J. W. C.; Salajka, Z.; Dong, S. Macromolecules 1992, 25, 3199
10. Mahanthappa, M. K.; Waymouth, R. M. J. Am. Chem. Soc. 2001, 123, 12093-12094
11. Williams, E. F.; Murray, M. C.; Baird, M. C. Macromolecules 2000, 33, 261-268
12. Bryliakov, K. P.; Semikolenova, N. V.; Zakharov, V. A.; Talsi, E. P. J. Organomet. Chem. 2003, 683, 23-28
13. Napoli, M.; Grisi, F.; Longo, P. Macromolecules 2009, 42, 2516-2522
14. Cram, D.; Sartori, F.; Maldotti, A. Macromol. Chem. Phys. 1994, 195, 2817-2826
15. Lyakin, O. Y.; Bryliakov, K. P.; Panchenko, V. N.; Semikolenova, N. V.; Zakharov, V. A.; Talsi, E. P. Macromol. Chem. Phys. 2007, 208, 1168-1175
16. Review: Lancaster, S. J. In Comprehensive Organometallic Chemistry III; Crabtree, R. H.; Mingos, D. M. P., Eds.; Elsevier, Oxford, 2007, Vol. 4, Bochmann, M., Vol. Ed.; Chapter 4.07, p 741-757.
17. Babushkin, D. E.; Brintzinger, H. H. Chem.-Eur. J. 2007, 13, 5294-5299
18. Babushkin, D. E.; Panchenko, V. N.; Timofeeva, M. N.; Zakharov, V. A.; Brintzinger, H. H. Macromol. Chem. Phys. 2008, 209, 1210-1219
19. Baldwin, S. M.; Bercaw, J. E.; Brintzinger, H. H. J. Am. Chem. Soc. 2008, 130, 17423-17433
20. Kleinschmidt, R.; van der Leek, Y.; Reffke, M.; Fink, G. J. Mol. Catal. A: Chem. 1999, 148, 29-41
21. Bochmann, M.; Lancaster, S. J. Angew. Chem., Int. Ed. Engl. 1994, 33, 1634-1637
22. Baldwin, S. M.; Bercaw, J. E.; Brintzinger, H. H. J. Am. Chem. Soc. 2010, 132, 13969-13971
23. Baldwin, S. M.; Bercaw, J. E.; Henling, L. M.; Day, M. W.; Brintzinger, H. H. J. Am. Chem. Soc. 2011, 133, 1805-1813
24. Wailes, P. C.; Weigold, H. J. Organomet. Chem. 1971, 28, 91-95
25. Cuenca, T.; Royo, P. J. Organomet. Chem. 1985, 293, 61-67
26. Review: Connelly, N. G.; Geiger, W. E. Chem. Rev. 1996, 96, 877-910
27. Bryliakov, K. P.; Talsi, E. P.; Semikolenova, N. V.; Zakharov, V. A.; Brand, J.; Alonso-Moreno, C.; Bochmann, M. J. Organomet. Chem. 2007, 692, 859-868
28. Samuel, E.; Maillard, P.; Gianotti, C. J. Organomet. Chem. 1977, 142, 289-298
29. Hudson, A.; Lappert, M. F.; Pichon, R. J. Chem. Soc., Chem. Commun. 1983, 374
30. Bajgur, C. S.; Jones, S. B.; Petersen, J. L. Organometallics 1985, 4, 1929-1936
31. Dioumaev, V. K.; Harrod, J. F. Organometallics 1997, 16, 1452-1464
32. Choukroun, R.; Gervais, D. J. Chem. Soc., Chem. Commun. 1985, 224-225
33. Larsonneur, A.-M.; Choukroun, R.; Jaud, J. Organometallics 1993, 12, 3216-3224
34. Wehmschulte, R. J.; Power, P. P. Polyhedron 1999, 18, 1885-1888
35. III-H units. Brintzinger, H. H. J. Am. Chem. Soc. 1967, 89, 6871-6876
36. Lukens, W. W.; Matsunaga, P. T.; Andersen, R. A. Organometallics 1998, 17, 5240-5247
37. Henrici-Olive, G.; Olive, S. J. Organomet. Chem. 1970, 23, 155-157
38. Lappert, M. F.; Pickett, C. J.; Riley, P. I.; Yarrow, P. I. J. Chem. Soc., Dalton Trans. 1981, 805-813
39. Lappert, M. F.; Raston, C. L.; Skelton, B. W.; White, A. H. J. Chem. Soc., Dalton Trans. 1997, 2895-2902
40. Herrmann, W. A.; Rohrmann, J.; Herdtweck, E.; Spaleck, W.; Winter, A. Angew. Chem., Int. Ed. Engl. 1989, 28, 1511-1512
41. Pool, J. A.; Chirik, P. J. Can. J. Chem. 2005, 83, 286-295
42. Hitchcock, P. B.; Lappert, M. F.; Lawless, G. A.; Olivier, H.; Ryan, E. J. J. Chem. Soc., Chem Commun. 1992, 474-476
43. Gambarotta, S.; Chiang, M. Y. Organometallics 1987, 6, 897-899
44. Lauher, J. W.; Hoffmann, R. J. Am. Chem. Soc. 1976, 98, 1729-1742
45. McMahon, C. N; Francis, J. A.; Barron, A. R. J. Chem. Crystallogr. 1997, 27, 191-194
46. Lalama, M. S.; Kampf, J.; Dick, D. G; Oliver, J. P. Organometallics 1995, 14, 495-501
47. Asadi, A.; Avent, A. G.; Coles, M. P.; Eaborn, C.; Hitchcock, P. B.; Smith, J. D. J. Organomet. Chem. 2004, 689, 1238-1248
48. Chakraborty, D.; Chen, E. Y.-X. Inorg. Chem. Commun. 2002, 5, 698-701
49. 91Zr) = 12.3 G Dioumaev, V. K.; Harrod, J. F. Organometallics 1997, 16, 2798-2807
50. Urazowski, I. F.; Ponomaryev, V. I.; Nifant'ev, I. E.; Lemenovski, D. A. J. Organomet. Chem. 1989, 368, 287-294
51. Stoll, S.; Schweiger, A. J. Magn. Reson. 2006, 178, 42-55