Effect of the polar modifiers on supercritical extraction efficiency for template removal from hexagonal mesoporous silica materials: Solubility parameter and polarity considerations

Separation and Purification Technology

Volumn 118, Issue , 2013, Pages 120-126

  Huang, Zhen ^a   Li, Jing Huan ^a   Li, Hui Shan ^b   Miao, Hui ^a   Kawi, S ^c   Goh, A H ^c  

^a TIANJIN UNIVERSITY OF COMMERCE   (China)

^b MILITARY TRANSPORTATION UNIVERSITY   (China)

^c NATIONAL UNIVERSITY OF SINGAPORE   (Singapore)

Author keywords

Hexagonal mesoporous materials; Modifier identity; Polarity; Solubility parameter; Supercritical CO2 extraction; Template removal

Indexed keywords

HEXAGONAL MESOPOROUS MATERIALS; MODIFIER IDENTITY; POLARITY; SOLUBILITY PARAMETERS; SUPERCRITICAL CO; TEMPLATE REMOVAL;

CARBON DIOXIDE; EFFICIENCY; EXTRACTION; MATERIALS; METHANOL; SOLUBILITY; SUPERCRITICAL FLUID EXTRACTION;

MESOPOROUS MATERIALS;

EID: 84880751401     PISSN: 13835866     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.seppur.2013.06.047     Document Type: Article

References (30)

1. R.M. Couto, T. Carvalho, L.A. Neves, R.M. Ruivo, P. Vidinha, A. Paiva, I.M. Coelhoso, S. Barreiros, and P.C. Simões Development of Ion-Jelly® Membranes Sep. Purif. Technol. 106 2013 22 31
2. K. Ghosh, H.J. Lehmler, S.E. Rankin, and B.L. Knutson Supercritical carbon dioxide swelling of fluorinated and hydrocarbon surfactant templates in mesoporous silica thin films J. Colloid Interface Sci. 367 2012 183 192
3. H. Rajaei, A. Amin, A. Golchehre, and F. Esmaeilzadeh Investigation on the effect of different supercritical fluid extraction process on the activation of the R-134 catalyst J. Supercrit. Fluids 67 2012 1 6
4. 2 Chem. Eng. J. 165 2010 974 979
5. J. Patarin Mild methods for removing organic templates from inorganic host materials Angew. Chem. Int. Ed. 43 2004 3878 3880 (Pubitemid 39268852)
6. 2 as a solvent J. Mater. Chem. 13 2003 1373 1377
7. L.-P. Chang, J.-H. Cheng, S.-L. Hsu, Y.-C. Fu, K.-L. Lin, C.-J. Shieh, X.-Q. Zhou, and C.-M.J. Chang Supercritical carbon dioxide anti-solvent purification of anti-oxidative compounds from Lycium barbarum fruits by using response surface methodology Sep. Purif. Technol. 100 2012 66 73
8. Y.-J. Cheng, C.-J. Shieh, Y.-C. Wang, S.-M. Lai, and C.-M.J. Chang Supercritical carbon dioxide extraction of omega-3 oil compounds from Ficus awkeotsang Makino achenes Sep. Purif. Technol. 98 2012 62 68
9. L.D. Kagliwal, S.C. Patil, A.S. Pol, R.S. Singhal, and V.B. Patravale Separation of bioactives from seabuckthorn seeds by supercritical carbon dioxide extraction methodology through solubility parameter approach Sep. Purif. Technol. 80 2011 533 540
10. M.G. Sajilata, M.V. Bule, P. Chavan, R.S. Singhal, and M.Y. Kamat Development of efficient supercritical carbon dioxide extraction methodology for zeaxanthin from dried biomass of Paracoccus zeaxanthinifaciens Sep. Purif. Technol. 71 2010 173 177
11. M.A. McHugh, and V.J. Krukonis Supercritical Fluid Extraction: Principles and Practice 1994 Butterworths Boston
12. J.H. Hildebrand, J.M. Prausnitz, and R.L. Scott Regular and Related Solutions: The Solubility of Gases, Liquids, and Solids 1970 Van Nostrand Reinhold New York
13. J.C. Giddings, M. Myers, J. King, Dense gas chromatography at pressures to 2000 atmospheres, J. Chromatogr. Sci. 7 (1969) 276-283.
14. Y. Marcus Are solubility parameters relevant to supercritical fluids? J. Supercrit. Fluids 38 2006 7 12 (Pubitemid 44093200)
15. H. Machida, M. Takesue, and Richard L. Smith Jr. Green chemical processes with supercritical fluids: Properties, materials, separations and energy J. Supercrit. Fluids 60 2011 2 15
16. Z. Huang, D.Y. Luan, S.C. Shen, K. Hidajat, and S. Kawi Supercritical fluid extraction of the organic template from synthesized porous materials: effect of pore size J. Supercrit. Fluids 35 2005 40 48 (Pubitemid 40891649)
17. S. Kawi, and M.W. Lai Supercritical fluid extraction of surfactant from Si-MCM-41 AIChE J. 48 2002 1572 1580 (Pubitemid 36173036)
18. S. Kawi, and A.H. Goh Supercritical fluid extraction of amine surfactant in hexagonal mesoporous silica (HMS) Stud. Surf. Sci. Catal. 129 2000 131 138
19. 2 extraction: Effects of temperature, pressure and flow rate Sep. Purif. Technol. 77 2011 112 119
20. 2: Experimental and modeling Chem. Eng. J. 166 2011 461 467
21. N. Alexandrou, M.J. Lawrence, and J. Pawliszyn Cleanup of complex organic mixtures using supercritical fluids and selective adsorbents Anal. Chem. 64 1992 301 311
22. T.M. Fahmy, M.E. Paulaitis, D.M. Johnston, and M.E.P. McNally Modifier effects in supercritical fluid extraction of solutes from clay, soil and plant materials Anal. Chem. 65 1993 1462 1469
23. J.J. Lagenfeld, S.B. Hawthrone, D.J. Miller, and J. Pawliszyn Role of modifiers for analytical-scale supercritical fluid extraction of environmental samples Anal. Chem. 66 1994 909 916
24. P.T. Tanev, and T.J. Pinnavaia Mesoporous silicas molecular sieves prepared by ionic and neutral surfactant templating: a comparison of physical properties Chem. Mater. 8 1996 2068 2079 (Pubitemid 126475395)
25. A.W. Francis Ternary systems of liquid carbon dioxide J. Phys. Chem. 58 1954 1099 1114
26. M. Ashraf-Khorassani, and L.T. Taylor Nitrous oxide versus carbon dioxide for supercritical fluid extraction and chromatography of amines Anal. Chem. 62 1990 1177 1180
27. D.R. Lide CRC Handbook of Chemistry and Physics 84th ed. 2004 CRC Press LLC Boca Raton
28. A.F.M. Barton CRC Handbook of Solubility Parameters and Other Cohesional Parameters second ed. 1991 CRC Press Boca Raton
29. 2O system J. Chem. Eng. Jpn. 19 1986 48 56
30. 2 extraction efficiencies of polycylclic aromatic hydrocarbons from environmental samples Anal. Chem. 57 1995 641 646