Kinetic modeling of mercury oxidation by chlorine over CeO 2-TiO2 catalysts

Fuel

Volumn 113, Issue , 2013, Pages 726-732

  Li, Hailong ^a,b,c   Wu, Chang Yu ^b,d   Li, Liqing ^a   Li, Ying ^e   Zhao, Yongchun ^c   Zhang, Junying ^c  

^a CENTRAL SOUTH UNIVERSITY   (China)

^b J Crayton Pruitt Family Department of Biomedical Engineering   (United States)

^c HUAZHONG UNIVERSITY OF SCIENCE AND TECHNOLOGY   (China)

^d NATIONAL CHENG KUNG UNIVERSITY   (Taiwan)

^e University of Wisconsin Milwaukee   (United States)

Author keywords

CeO2 TiO2; Coal combustion; Kinetic; Mercury oxidation; SO2

Indexed keywords

ADSORPTION EQUILIBRIA; COAL COMBUSTION FLUE GAS; HETEROGENEOUS OXIDATION; MERCURY OXIDATIONS; OXIDATION EFFICIENCY; SO2; TIO; WET FLUE GAS DESULFURIZATION;

ADSORPTION; CATALYSTS; CHLORINE; COAL COMBUSTION; FLUE GASES; KINETIC PARAMETERS; KINETIC THEORY; KINETICS; MERCURY (METAL); OXIDATION; RATE CONSTANTS; SULFUR DIOXIDE; TITANIUM DIOXIDE;

SELECTIVE CATALYTIC REDUCTION;

EID: 84880694085     PISSN: 00162361     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.fuel.2013.06.029     Document Type: Article

References (50)

1. K. Schofield Mercury emission control from coal combustion systems: a modified air preheater solution Combust Flame 159 4 2012 1741 1747
2. J.Y. Zhang, C.G. Zheng, D.Y. Ren, C.L. Chou, J. Liu, and R.S. Zeng Distribution of potentially hazardous trace elements in coals from Shanxi Province, China Fuel 83 1 2004 129 135
3. Y.E. Yudovich, and M.P. Ketris Mercury in coal: a review: Part 1 Geochem Int J Coal Geol 62 3 2005 107 134
4. J.H. Pavlish, E.A. Sondreal, M.D. Mann, E.S. Olson, K.C. Galbreath, and D.L. Laudal Status review of mercury control options for coal-fired power plants Fuel Process Technol 82 2-3 2003 89 165
5. Y. Wu, S. Wang, D.G. Streets, J. Hao, M. Chan, and J. Jiang Trends in anthropogenic mercury emissions in China from 1995 to 2003 Environ Sci Technol 40 17 2006 5312 5318 (Pubitemid 44373092)
6. M.H. Keating, K.R. Mahaffey, R. Schoeny, G.E. Rice, O.R. Bullock, and R.B. Ambrose Mercury study report to congress volume I: executive summary 1997 Office of Air Quality Planning and Standards and Office of Research and Development Washington (DC)
7. E.J. Granite, H.W. Pennline, and R.A. Hargis Novel sorbents for mercury removal from flue gas Ind Eng Chem Res 39 4 2000 1020 1029 (Pubitemid 30210644)
8. Ministry of environmental protection of the People's Republic of China, Emission standard of air pollutants for thermal power plants. http://www.zhb.gov.cn/gkml/hbb/bgg/201109/W020120113518288046763.pdf. [accessed 06.05.12].
9. U.S. Environmental protection agency, Air toxics standards for utilities. http://www.epa.gov/airquality/powerplanttoxics/actions.html. [accessed on 06.05.12].
10. J.B. Milford, and A. Pienciak After the clean air mercury rule: prospects for reducing mercury emissions from coal-fired power plants Environ Sci Technol 43 8 2009 2669 2673
11. S. Niksa, and N. Fujiwara Estimating Hg emissions from coal-fired power stations in China Fuel 88 1 2009 214 217
12. Y. Zhuang, J.S. Thompson, C.J. Zygarlicke, and JH. Pavlish Development of a mercury transformation model in coal combustion flue gas Environ Sci Technol 38 21 2004 5803 5808 (Pubitemid 39447210)
13. K.C. Galbreath, and C.J. Zygarlicke Mercury speciation in coal combustion and gasification flue gases Environ Sci Technol 30 8 1996 2421 2426 (Pubitemid 26266287)
14. L. Zhang, Y. Zhuo, L. Chen, X. Xu, and C. Chen Mercury emissions from six coal-fired power plants in China Fuel Process Technol 89 11 2008 1033 1040
15. A.P. Jones, J.W. Hoffmann, D.N. Smith, T.J. Feeley, and JT. Murphy DOE/NETL's phase II mercury control technology field testing program: preliminary economic analysis of activated carbon injection Environ Sci Technol 41 4 2007 1365 1371
16. R. Strivastava Control of mercury emissions from coal fired electric utility boilers: an update 2010 U.S. Environmental Protection Agency Cincinnati (Ohio)
17. S.X. Wang, L. Zhang, G.H. Li, Y. Wu, J.M. Hao, and N. Pirrone Mercury emission and speciation of coal-fired power plants in China Atmos Chem Phys 10 3 2010 1183 1192
18. Y. Zhao, S. Wang, L. Duan, Y. Lei, P. Cao, and J. Hao Primary air pollutant emissions of coal-fired power plants in China: current status and future prediction Atmos Environ 42 36 2008 8442 8452
19. S. Pritchard Predictable SCR co-benefits for mercury control Power Eng 113 1 2009 42 45
20. A.A. Presto, and E.J. Granite Survey of catalysts for oxidation of mercury in flue gas Environ Sci Technol 40 18 2006 5601 5609 (Pubitemid 44413704)
21. S. He, J. Zhou, Y. Zhu, Z. Luo, M. Ni, and K. Cen Mercury oxidation over a vanadia-based selective catalytic reduction catalyst Energy Fuels 23 1 2009 253 259
22. x plants - bench scale investigations and speciation experiments Appl Catal B 79 3 2008 286 295
23. C.W. Lee, S.D. Serre, Y. Zhao, and S.J. Lee Mercury oxidation promoted by a selective catalytic reduction catalyst under simulated powder river basin coal combustion conditions J Air Waste Manage Assoc 58 4 2008 484 493 (Pubitemid 351594523)
24. 2 commercial SCR catalyst Ind Eng Chem Res 47 21 2008 8136 8141
25. Y. Cao, Z. Gao, J. Zhu, Q. Wang, Y. Huang, and C. Chiu Impacts of halogen additions on mercury oxidation, in a slipstream selective catalyst reduction (SCR), reactor when burning sub-bituminous coal Environ Sci Technol 42 1 2008 256 261
26. S. Eswaran, and H.G. Stenger Effect of halogens on mercury conversion in SCR catalysts Fuel Process Technol 89 11 2008 1153 1159
27. Y. Zhuang, J. Laumb, R. Liggett, M. Holmes, and J. Pavlish Impacts of acid gases on mercury oxidation across SCR catalyst Fuel Process Technol 88 10 2007 929 934 (Pubitemid 47211693)
28. S. Niksa, and N. Fujiwara A predictive mechanism for mercury oxidation on selective catalytic reduction catalysts under coal-derived flue gas J Air Waste Manage Assoc 55 12 2005 1866 1875 (Pubitemid 43035893)
29. 2-based catalysts in SCR process Appl Catal B 99 1-2 2010 272 278
30. x and elemental mercury from flue gas Energy Fuels 22 4 2008 2299 2306
31. 2 catalysts for catalytic oxidation of elemental mercury in low-rank coal combustion flue gas Environ Sci Technol 45 2011 7394 7400
32. 3 Catal Commun 11 5 2010 465 469
33. 3 J Hazard Mater 174 1-3 2010 734 739
34. 2 catalyst Catal Commun 9 6 2008 1453 1457
35. 2 catalysts by Raman and XPS techniques J Phys Chem B 107 22 2003 5162 5167
36. A.A. Presto, E.J. Granite, A. Karash, R.A. Hargis, W.J. O'Dowd, and H.W. Pennline A kinetic approach to the catalytic oxidation of mercury in flue gas Energy Fuels 20 5 2006 1941 1945 (Pubitemid 44541280)
37. C.L. Senior Oxidation of mercury across selective catalytic reduction catalysts in coal-fired power plants J Air Waste Manage Assoc 56 1 2006 23 31 (Pubitemid 43733616)
38. Y. Eom, S.H. Jeon, T.A. Ngo, J. Kim, and T.G. Lee Heterogeneous mercury reaction on a selective catalytic reduction (SCR) catalyst Catal Lett 121 3-4 2008 219 225
39. B. Zhao, Z. Zhang, J. Jin, and W.P. Pan Simulation of mercury capture by sorbent injection using a simplified model J Hazard Mater 170 2-3 2009 1179 1185
40. J. Ren, J. Zhou, Z. Luo, Y. Zhong, and X. Zhang Fixed bed experiments and mathematical modeling for adsorption of mercury vapor Proc CSEE 26 11 2006 1 6 (Pubitemid 44171297)
41. C. Hu Mercury emission from coal-fired power plants in China and stability adsorption mechanism of mercury on activated carbon 2007 Zhejiang University Hangzhou
42. 2 catalyst Catal Commun 9 14 2008 2441 2444
43. 5 J Catal 134 2 1992 479 491
44. 2 SCR catalysts Appl Catal B 10 4 1996 299 311 (Pubitemid 27013009)
45. Laudal DL, Thompson JS, Pavlish JH, Brickett L, Chu P, Srivastava RK, Lee CW, Kilgroe JD. Mercury speciation at power plants using SCR and SNCR control technologies. In: 3rd International air quality conference, Arlington, Virginia. September, 2002.
46. B.W. Vosteen, R. Kanefke, and H. Köser Bromine-enhanced mercury abatement from combustion flue gases-recent industrial applications and laboratory research Int J Electr Heat Gen 86 3 2006 70 75
47. Y. Cao, Q. Wang, C. Chen, B. Chen, M. Cohron, and Y.C. Tseng Investigation of mercury transformation by HBr addition in a slipstream facility with real flue gas atmospheres of bituminous coal and powder river basin coal Energy Fuels 21 5 2007 2719 2730 (Pubitemid 47602752)
48. 3 J Phys Chem C 113 11 2009 4426 4432
49. Y. Cao, B. Chen, J. Wu, H. Cui, J. Smith, and C.K. Chen Study of mercury oxidation by a selective catalytic reduction catalyst in a pilot-scale slipstream reactor at a utility boiler burning bituminous coal Energy Fuels 21 1 2007 145 156
50. A.A. Presto, and E.J. Granite Impact of sulfur oxides on mercury capture by activated carbon Environ Sci Technol 41 18 2007 6579 6584 (Pubitemid 47438003)