Fully automated standard addition method for the quantification of 29 polar pesticide metabolites in different water bodies using LC-MS/MS

Analytical and Bioanalytical Chemistry

Volumn 405, Issue 19, 2013, Pages 6337-6351

  Kowal, Sebastian ^a,b   Balsaa, Peter ^a   Werres, Friedrich ^a   Schmidt, Torsten C ^a,b  

^a IWW WATER CENTRE   (Germany)

^b UNIVERSITY OF DUISBURG ESSEN   (Germany)

Author keywords

Automated standard addition method (SAM); Ion suppression; LC MS MS; Matrix effects; Non relevant metabolites; Pesticide metabolites

Indexed keywords

ION SUPPRESSION; LC-MS/MS; MATRIX EFFECTS; PESTICIDE METABOLITES; STANDARDADDITION METHOD (SAM);

AUTOMATION; CATCHMENTS; CHEMICAL ANALYSIS; COMPUTER ARCHITECTURE; DIRECT INJECTION; GROUNDWATER; LIQUID CHROMATOGRAPHY; MASS SPECTROMETRY; METABOLITES; PESTICIDES; SURFACE WATERS;

BIOMOLECULES;

PESTICIDE;

ARTICLE; AUTOMATION; CHEMICAL STRUCTURE; CHEMISTRY; EVALUATION; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; LIMIT OF DETECTION; METABOLISM; METHODOLOGY; TANDEM MASS SPECTROMETRY; WATER POLLUTANT;

AUTOMATION; CHROMATOGRAPHY, HIGH PRESSURE LIQUID; LIMIT OF DETECTION; MOLECULAR STRUCTURE; PESTICIDES; TANDEM MASS SPECTROMETRY; WATER POLLUTANTS, CHEMICAL;

EID: 84880135740     PISSN: 16182642     EISSN: 16182650     Source Type: Journal    
DOI: 10.1007/s00216-013-7028-5     Document Type: Article

References (44)

1. Wiebke T (2010) Übersicht nicht relevanter Grundwassermetaboliten von Pflanzenschutzmittel-Wirkstoffen. BVL - Bundesamt für Verbraucherschutz und Lebensmittelsicherheit 2010
2. Pflanzenschutzmittel - Stoffgruppen und Anwendung (2008) Bayerisches Landesamt für Umwelt. http://www.lfu.bayern.de/umweltwissen/doc/uw-51- pflanzenschutzmittel-stoffgruppen-anwendung.pdf
3. Chicharro M, Bermejo E, Sánchez A, Zapardiel A, Fernandez-Gutierrez A, Arraez D (2005) Multiresidue analysis of phenylurea herbicides in environmental waters by capillary electrophoresis using electrochemical detection. Anal Bioanal Chem 382(2):519-526
4. Pflanzenschutzmittel in der Umwelt (2008) http://www.lfu.bayern.de/ umweltwissen/doc/uw-52-pflanzenschutzmittel-umwelt.pdf
5. Schmidt CK, Brauch HJ (2008) N,N-dimethylsulfamide as precursor for N-nitrosodimethylamine (NDMA) formation upon ozonation and its fate during drinking water treatment. Environ Sci Technol 42(17):6340-6346
6. Gesundheitliche Orientierungswerte (GOW) für nicht relevante Metaboliten (nrM) von Wirkstoffen aus Pflanzenbehandlungs- und Schädlingsbekämpfungsmitteln (2009) http://www.umweltdaten.de/wasser/ themen/trinkwassertoxikologie/tabelle-gow-nrm.pdf
7. Gesundheitliche Orientierungswerte (GOW) für nicht relevante Metaboliten (nrM) von Wirkstoffen aus Pflanzenschutzmitteln (PSM) (2008) http://www.umweltdaten.de/wasser/themen/trinkwassertoxikologie/tabelle-gow-nrm. pdf
8. Dieter HH (2010) The relevance of "non-relevant metabolites" from plant protection products (PPPs) for drinking water: the German view. Regul Toxicol Pharmacol 56(2):121-125
9. Kowal S, Balsaa P, Werres F, Schmidt TC (2009) Determination of the polar pesticide degradation product N,N-dimethylsulfamide in aqueous matrices by UPLC-MS/MS. Anal Bioanal Chem 395(6):1787-1794
10. Kowal S, Balsaa P, Werres F, Schmidt TC (2012) Reduction of matrix effects and improvement of sensitivity during determination of two chloridazon degradation products in aqueous matrices by using UPLC-ESI-MS/MS. Anal Bioanal Chem 403(6):1707-1717
11. Polar pesticide-metabolites in drinking and mineral water (2008) Chemisches und Veterinäruntersuchungsamt. http://cvuas.untersuchungsamter- bw.de/pdf/EPRW08-watermetabolites.pdf
12. Freitas LG, Gotz CW, Ruff M, Singer HP, Muller SR (2004) Quantification of the new triketone herbicides, sulcotrione and mesotrione, and other important herbicides and metabolites, at the ng/l level in surface waters using liquid chromatography-tandem mass spectrometry. J Chromatogr A 1028(2):277-286
13. Kern S, Fenner K, Singer HP, Schwarzenbach RP, Hollender J (2009) Identification of transformation products of organic contaminants in natural waters by computer-aided prediction and high-resolution mass spectrometry. Environ Sci Technol 43(18):7039-7046
14. Niessen WMA (2006) Liquid chromatography-mass spectrometry, 3rd edn. Taylor & Francis, New York
15. Choi BK, Gusev AI, Hercules DM (1999) Postcolumn introduction of an internal standard for quantitative LC-MS analysis. Anal Chem 71(18):4107-4110
16. Choi BK, Hercules DM, Gusev AI (2001) LC-MS/MS signal suppression effects in the analysis of pesticides in complex environmental matrices. Anal Bioanal Chem 369(3-4):370-377
17. Ito S, Tsukada K (2002) Matrix effect and correction by standard addition in quantitative liquid chromatographic-mass spectrometric analysis of diarrhetic shellfish poisoning toxins. J Chromatogr A 943(1):39-46
18. Quintana JB, Reemtsma T (2004) Sensitive determination of acidic drugs and triclosan in surface and wastewater by ion-pair reverse-phase liquid chromatography/tandem mass spectrometry. Rapid Commun Mass Spectrom 18(7):765-774
19. Taylor PJ (2005) Matrix effects: the Achilles heel of quantitative high-performance liquid chromatography-electrospray-tandem mass spectrometry. Clin Biochem 38(4):328-334
20. Trufelli H, Palma P, Famiglini G, Cappiello A (2011) An overview of matrix effects in liquid chromatography-mass spectrometry. Mass Spectrom Rev 30(3):491-509
21. Hewavitharana AK (2011) Matrix matching in liquid chromatography-mass spectrometry with stable isotope labelled internal standards - is it necessary? J Chromatogr A 1218(2):359-361
22. Dams R, Huestis MA, Lambert WE, Murphy CM (2003) Matrix effect in bio-analysis of illicit drugs with LC-MS/MS: influence of ionization type, sample preparation, and biofluid. J Am Soc Mass Spectrom 14(11):1290-1294
23. Stüber M, Reemtsma T (2004) Evaluation of three calibration methods to compensate matrix effects in environmental analysis with LC-ESI-MS. Anal Bioanal Chem 378(4):910-916
24. Kang J, Hick LA, Price WE (2007) Using calibration approaches to compensate for remaining matrix effects in quantitative liquid chromatography/electrospray ionization multistage mass spectrometric analysis of phytoestrogens in aqueous environmental samples. Rapid Commun Mass Spectrom 21(24):4065-4072
25. Ismaiel OA, Halquist MS, Elmamly MY, Shalaby A, Thomas Karnes H (2008) Monitoring phospholipids for assessment of ion enhancement and ion suppression in ESI and APCI LC/MS/MS for chlorpheniramine in human plasma and the importance of multiple source matrix effect evaluations. J Chromatogr B Anal Technol Biomed Life Sci 875(2):333-343
26. Zhao X, Metcalfe CD (2008) Characterizing and compensating for matrix effects using atmospheric pressure chemical ionization liquid chromatography-tandem mass spectrometry: analysis of neutral pharmaceuticals in municipal wastewater. Anal Chem 80(6):2010-2017
27. Gosetti F, Mazzucco E, Zampieri D, Gennaro MC (2010) Signal suppression/enhancement in high-performance liquid chromatography tandem mass spectrometry. J Chromatogr A 1217(25):3929-3937
28. Niessen WMA, Manini P, Andreoli R (2006) Matrix effects in quantitative pesticide analysis using liquid chromatography-mass spectrometry. Mass Spectrom Rev 25(6):881-899
29. Haun J, Oeste K, Teutenberg T, Schmidt CK (2012) Long-term high-temperature and pH stability assessment of modern commercially available stationary phases by using retention factor analysis. J Chromatogr A 1263:99-107
30. Wyndham KD, Walter TH, Iraneta PC, Neue UD, McDonald PD, Morrison D, Baynham M (2004) A review of waters hybrid particle technology, part 2. Ethylene-bridged [BEH Technology] hybrids and their use in liquid chromatography
31. Srinivasan G, Müller K (2006) Influence of solvents on the conformational order of C18 alkyl modified silica gels. J Chromatogr A 1110(1-2):102-107
32. León-González ME, Pérez-Arribas LV, Polo Díez LM, Panis C, San Andrés MP (2001) Determination of triazine herbicides by capillary liquid chromatography with on-column focusing and temperature gradient. Anal Chim Acta 445(1):29-34
33. Ling BL, Baeyens W, Dewaele C (1992) Comparative study of "on-column focusing" applied to micro-LC and conventional LC. J Microcolumn Sep 4(1):17-22
34. Scheurer M, Brauch HJ, Lange FT (2009) Analysis and occurrence of seven artificial sweeteners in German waste water and surface water and in soil aquifer treatment (SAT). Anal Bioanal Chem 394(6):1585-1594
35. Reemtsma T, Alder L, Banasiak U (2013) A multimethod for the determination of 150 pesticide metabolites in surface water and groundwater using direct injection liquid chromatography-mass spectrometry. J Chromatogr A 1271(1):95-104
36. Van De Steene JC, Lambert WE (2008) Comparison of matrix effects in HPLC-MS/MS and UPLC-MS/MS analysis of nine basic pharmaceuticals in surface waters. J Am Soc Mass Spectrom 19(5):713-718
37. Zhu YH, Li GR, Duan YP, Chen SQ, Zhang C, Li YF (2008) Application of the standard addition method for the determination of acrylamide in heat-processed starchy foods by gas chromatography with electron capture detector. Food Chem 109(4):899-908
38. Conley JM, Symes SJ, Kindelberger SA, Richards SM (2008) Rapid liquid chromatography-tandem mass spectrometry method for the determination of a broad mixture of pharmaceuticals in surface water. J Chromatogr A 1185(2):206-215
39. Schadstoffinformationen (2006) http://www.enius.de/schadstoffe/ tolylfluanid.html.
40. Test 07/2012, Stille Mineralwässer: Mineralstoffe Mangelware (2012) http://www.test.de/shop/test-hefte/test-07-2012/?ft=download-2001
41. Predict properties viewer (2012) http://www.chemicalize.org/
42. Wiebke T (2008) Metaboliten von Pflanzenschutzmittel-Wirkstoffen im Sickerwasser von Lysimetern oder Feldversickerungsstudien. BVL - Bundesamt für Verbraucherschutz und Lebensmittelsicherheit 2008
43. Gesundheitliche Orientierungswerte (GOW) für nicht relevante Metaboliten (nrM) von Wirkstoffen aus Pflanzenschutzmitteln (PSM) (2008) Umweltbundesamt. http://www.umweltdaten.de/wasser/themen/trinkwassertoxikologie/ tabelle-gow-nrm.pdf
44. Peer review of the pesticide risk assessment of the active substances (2008) http://www.efsa.europa.eu/de/pesticides/pesticidesscdocs.htm