Selective α-metalation of THF by a cationic zirconium complex supported by an (NNNN)-type macrocyclic ligand

Chemistry - A European Journal

Volumn 19, Issue 29, 2013, Pages 9468-9471

  Kulinna, Heiko ^a   Spaniol, Thomas P ^a   Maron, Laurent ^b   Okuda, Jun ^a  

^a RWTH AACHEN UNIVERSITY   (Germany)

^b INSA   (France)

Author keywords

C H activation; density functional calculations; hydrides; silanes; zirconium

Indexed keywords

C-H ACTIVATION; C-H BOND; DFT CALCULATION; KINETIC MEASUREMENT; MACRO-CYCLIC LIGANDS; METALATIONS; ZIRCONIUM COMPLEXES;

ACTIVATION ANALYSIS; DENSITY FUNCTIONAL THEORY; HYDRIDES; SILANES; ZIRCONIUM;

ZIRCONIUM COMPOUNDS;

CATION; COORDINATION COMPOUND; FURAN DERIVATIVE; LIGAND; MACROCYCLIC COMPOUND; SILANE DERIVATIVE; TETRAHYDROFURAN; ZIRCONIUM;

ARTICLE; C H ACTIVATION; CHEMICAL STRUCTURE; CHEMISTRY; DENSITY FUNCTIONAL CALCULATIONS; HYDRIDES; QUANTUM THEORY;

C H ACTIVATION; DENSITY FUNCTIONAL CALCULATIONS; HYDRIDES; SILANES; ZIRCONIUM;

CATIONS; COORDINATION COMPLEXES; FURANS; LIGANDS; MACROCYCLIC COMPOUNDS; MOLECULAR STRUCTURE; QUANTUM THEORY; SILANES; ZIRCONIUM;

EID: 84879987508     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201301202     Document Type: Article

References (29)

1. R. E. Mulvey, V. L. Blair, W. Clegg, A. R. Kennedy, J. Klett, L. Russo, Nat. Chem. 2010, 2, 588-591
2. A. Maercker, Angew. Chem. 1987, 99, 1002-1019
3. Angew. Chem. Int. Ed. Engl. 1987, 26, 972-989.
4. A. R. Kennedy, J. Klett, R. E. Mulvey, D. S. Wright, Science 2009, 326, 706-708
5. E. Crosbie, P. García-Álvarez, A. R. Kennedy, J. Klett, R. E. Mulvey, S. D. Robertson, Angew. Chem. 2010, 122, 9578-9581
6. Angew. Chem. Int. Ed. 2010, 49, 9388-9391
7. R. E. Mulvey, Acc. Chem. Res. 2009, 42, 743-755.
8. R. B. Bates, L. M. Kroposki, D. E. Potter, J. Org. Chem. 1972, 37, 560-562.
9. H. Adams, N. A. Bailey, P. Cahill, D. Rogers, M. J. Winter, J. Chem. Soc. Dalton Trans. 1986, 2119-2126.
10. K. A. Miller, J. M. Bartolin, R. M. O'Neill, R. D. Sweeder, T. M. Owens, J. W. Kampf, M. M. B. Holl, N. J. Wells, J. Am. Chem. Soc. 2003, 125, 8986-8987.
11. J. Meiners, A. Friedrich, E. Herdtweck, S. Schneider, Organometallics 2009, 28, 6331-6338.
12. H. Kulinna, T. P. Spaniol, L. Maron, J. Okuda, Inorg. Chem. 2012, 51, 12462-12472.
13. F. H. Allen, A. J. Kirby, J. Am. Chem. Soc. 1984, 106, 6197-6200
14. M. A. Beno, H. Hope, M. M. Olmstead, P. P. Power, Organometallics 1985, 4, 2117-2121.
15. Y. Li, A. Turnas, J. T. Ciszewski, A. L. Odom, Inorg. Chem. 2002, 41, 6298-6306
16. R. F. Munhá, L. F. Veiros, M. T. Duarte, M. D. Fryzuk, A. M. Martins, Dalton Trans. 2009, 7494-7508
17. R. F. Munhá, S. Namorado, S. Barroso, M. T. Duarte, J. R. Ascenso, A. R. Dias, A. M. Martins, J. Organomet. Chem. 2006, 691, 3853-3861
18. M. E. G. Skinner, Y. Li, P. Mountford, Inorg. Chem. 2002, 41, 1110-1119
19. P. O'Connor, D. J. Berg, B. Twamley, Organometallics 2005, 24, 28-36.
20. C. Visser, A. Meetsma, B. Hessen, Organometallics 2002, 21, 1912-1918.
21. M. Gõmez-Gallego, M. A. Sierra, Chem. Rev. 2011, 111, 4857-4963.
22. C. Chatgilialoglu, Adv. Organomet. Chem. 1999, 44, 67-112
23. D. J. Parks, J. M. Blackwell, W. E. Piers, J. Org. Chem. 2000, 65, 3090-3098.
24. A. D. Sadow, T. D. Tilley, J. Am. Chem. Soc. 2003, 125, 9462-9475.
25. N. Barros, O. Eisenstein, L. Maron, Dalton Trans. 2010, 39, 10749-10756.
26. H. Gilman, C. L. Smith, J. Organomet. Chem. 1968, 14, 91-101.
27. L. Perrin, L. Maron, O. Eisenstein, J. Chem. Soc. Dalton Trans. 2002, 534-539
28. L. Perrin, L. Maron, O. Eisenstein, Faraday Discuss. 2003, 124, 25-39
29. E. A. Goldman, K. I. Goldberg, ACS Symp., Ser. 885, "Organometallic C-H Bond Activation" 2004, 116-135.